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Commission Regulation (EU) 2018/669 of 16 April 2018 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixturesText with EEA relevance.

C/2018/2154
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OJ L 115, 4.5.2018, p. 1–755 (BG, ES, CS, DA, DE, ET, EL, EN, FR, HR, IT, LV, LT, HU, MT, NL, PL, PT, RO, SK, SL, FI, SV)

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4.5.2018   

EN

Official Journal of the European Union

L 115/1


COMMISSION REGULATION (EU) 2018/669

of 16 April 2018

amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures

(Text with EEA relevance)

THE EUROPEAN COMMISSION,

Having regard to the Treaty on the Functioning of the European Union,

Having regard to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (1), and in particular Article 53(1) thereof,

Whereas:

(1)

Tables 3.1 and 3.2 of Annex VI to Regulation (EC) No 1272/2008 contain the list of harmonised classification and labelling of hazardous substances but only in English for all language versions of that Regulation.

(2)

On 2 December 2008 (2) the Commission committed itself to ensure that the chemical names corresponding to the International Chemical Identifications in Tables 3.1 and 3.2 of Annex VI to Regulation (EC) No 1272/2008 are published in the same language as the language versions in which that Regulation has been published.

(3)

Table 3.1 of Annex VI to Regulation (EC) No 1272/2008 has been amended several times to reflect technical and scientific progress, by adding, deleting or modifying substances or their classification. To take account of those changes and to ensure that all the chemical names in Table 3.1 of Annex VI to Regulation (EC) No 1272/2008 are in the same language as the language versions in which that Regulation has been published, Table 3.1 needs to be replaced partially.

(4)

In view of the derogation (3) which applies to the translation into Irish of acts which are not adopted jointly by the European Parliament and the Council, the chemical names in Table 3.1 of Annex VI should not be translated into Irish.

(5)

Table 3.2 lists the harmonised classification and labelling of hazardous substances based on the criteria set out in Annex VI to Council Directive 67/548/EEC (4), which has been repealed with effect from 1 June 2015. As a consequence, Table 3.2 is to be deleted in accordance with Article 1(2) of Commission Regulation (EU) 2016/1179 (5) with effect from 1 June 2017. That table should therefore not be changed. As a result Table 3.1 has been renamed to Table 3 in accordance with Article 2(2) of Commission Regulation (EU) 2017/776 (6) with effect from 1 June 2017.

(6)

Suppliers should be given sufficient time to adapt the labelling and packaging of substances and mixtures to the new translation provisions and to sell existing stocks.

(7)

Suppliers should have the possibility of applying this Regulation before its date of application to ensure a high level of protection of human health and of the environment and to provide sufficient flexibility to suppliers.

(8)

The measures provided for in this Regulation are in accordance with the opinion of the Committee established under Article 133 of Regulation (EC) No 1907/2006 of the European Parliament and of the Council (7),

HAS ADOPTED THIS REGULATION:

Article 1

The entries set out in Annex VI to Regulation (EC) No 1272/2008 corresponding to the entries set out in the Annex to this Regulation are replaced by the entries set out in the Annex to this Regulation.

Article 2

This Regulation shall enter into force on the twentieth day following that of its publication in the Official Journal of the European Union.

It shall apply from 1 December 2019.

By way of derogation from the second subparagraph, substances and mixtures may before 1 December 2019 be classified, labelled and packaged in accordance with Regulation (EC) No 1272/2008, as amended by this Regulation.

This Regulation shall be binding in its entirety and directly applicable in all Member States.

Done at Brussels, 16 April 2018.

For the Commission

The President

Jean-Claude JUNCKER


(1)  OJ L 353, 31.12.2008, p. 1.

(2)  Corrigendum to the position of the European Parliament adopted at first reading on 3 September 2008 with a view to the adoption of Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 — P6_TA(2008)0392 (COM (2007)0355 — C6-0197/2007 — 2007/0121 (COD)).

(3)  Council Regulation (EU) No 1257/2010 of 20 December 2010 extending the temporary derogation measures from Regulation No 1 of 15 April 1958 determining the languages to be used by the European Economic Community and Regulation No 1 of 15 April 1958 determining the languages to be used by the European Atomic Energy Community introduced by Regulation (EC) No 920/2005 (OJ L 343, 29.12.2010, p. 5).

(4)  Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (OJ 196, 16.8.1967, p. 1).

(5)  Commission Regulation (EU) 2016/1179 of 19 July 2016 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (OJ L 195 de 20.7.2016, p. 11).

(6)  Commission Regulation (EU) 2017/776 of 4 May 2017 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures (OJ L 116, 5.5.2017, p. 1).

(7)  Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (OJ L 396, 30.12.2006, p. 1).


ANNEX

Index No

International Chemical Identification

EC No

CAS No

Classification

Labelling

Specific Conc. Limits, M-factors

Notes

Hazard Class and

Category Code(s)

Hazard statement Code(s)

Pictogram, Signal Word Code(s)

Hazard statement Code(s)

Suppl. Hazard statement Code(s)

(1)

(2)

(3)

(4)

(5)

(6)

(7)

(8)

(9)

(10)

(11)

001-001-00-9

hydrogen

215-605-7

1333-74-0

Flam. Gas 1

Press. Gas

H220

GHS02

GHS04

Dgr

H220

 

 

U

001-002-00-4

aluminium lithium hydride

240-877-9

16853-85-3

Water-react. 1

Skin Corr. 1A

H260

H314

GHS02

GHS05

Dgr

H260

H314

 

 

 

001-003-00-X

sodium hydride

231-587-3

7646-69-7

Water-react. 1

H260

GHS02

Dgr

H260

 

 

 

001-004-00-5

calcium hydride

232-189-2

7789-78-8

Water-react. 1

H260

GHS02

Dgr

H260

 

 

 

003-001-00-4

lithium

231-102-5

7439-93-2

Water-react. 1

Skin Corr. 1B

H260

H314

GHS02

GHS05

Dgr

H260

H314

EUH014

 

 

003-002-00-X

n-hexyllithium

404-950-0

21369-64-2

Water-react. 1

Pyr. Sol. 1

Skin Corr. 1A

H260

H250

H314

GHS02

GHS05

Dgr

H260

H250

H314

EUH014

 

 

003-003-00-5

(2-methylpropyl)lithium; isobutyllithium

440-620-2

920-36-5

Water-react. 1

Pyr. Liq. 1

Skin Corr. 1A

STOT SE 3

Aquatic Acute 1

Aquatic Chronic 1

H260

H250

H314

H336

H400

H410

GHS02

GHS05

GHS07

GHS09

Dgr

H260

H250

H314

H336

H410

EUH014

 

 

004-001-00-7

beryllium

231-150-7

7440-41-7

Carc. 1B

Acute Tox. 2 *

Acute Tox. 3 *

STOT RE 1

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Skin Sens. 1

H350i

H330

H301

H372 **

H319

H335

H315

H317

GHS06

GHS08

Dgr

H350i

H330

H301

H372 **

H319

H335

H315

H317

 

 

 

004-002-00-2

beryllium compounds with the exception of aluminium beryllium silicates, and with those specified elsewhere in this Annex

Carc. 1B

Acute Tox. 2 *

Acute Tox. 3 *

STOT RE 1

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Skin Sens. 1

Aquatic Chronic 2

H350i

H330

H301

H372 **

H319

H335

H315

H317

H411

GHS06

GHS08

GHS09

Dgr

H350i

H330

H301

H372 **

H319

H335

H315

H317

H411

 

 

A

004-003-00-8

beryllium oxide

215-133-1

1304-56-9

Carc. 1B

Acute Tox. 2 *

Acute Tox. 3 *

STOT RE 1

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Skin Sens. 1

H350i

H330

H301

H372 **

H319

H335

H315

H317

GHS06

GHS08

Dgr

H350i

H330

H301

H372 **

H319

H335

H315

H317

 

 

 

005-001-00-X

boron trifluoride

231-569-5

7637-07-2

Press. Gas

Acute Tox. 2 *

Skin Corr. 1A

H330

H314

GHS04

GHS06

GHS05

Dgr

H330

H314

EUH014

 

U

005-002-00-5

boron trichloride

233-658-4

10294-34-5

Press. Gas

Acute Tox. 2 *

Acute Tox. 2 *

Skin Corr. 1B

H330

H300

H314

GHS04

GHS06

GHS05

Dgr

H330

H300

H314

EUH014

 

U

005-003-00-0

boron tribromide

233-657-9

10294-33-4

Acute Tox. 2 *

Acute Tox. 2 *

Skin Corr. 1A

H330

H300

H314

GHS06

GHS05

Dgr

H330

H300

H314

EUH014

 

 

005-004-00-6

trialkylboranes, solid

Pyr. Sol. 1

Skin Corr. 1B

H250

H314

GHS02

GHS05

Dgr

H250

H314

 

 

A

005-004-01-3

trialkylboranes, liquid

Pyr. Liq. 1

Skin Corr. 1B

H250

H314

GHS02

GHS05

Dgr

H250

H314

 

 

A

005-005-00-1

trimethyl borate

204-468-9

121-43-7

Flam. Liq. 3

Acute Tox. 4 *

H226

H312

GHS02

GHS07

Wng

H226

H312

 

 

 

005-006-00-7

dibutyltin hydrogen borate

401-040-5

75113-37-0

Repr. 1B

Muta. 2

STOT RE 1

Acute Tox. 4 *

Acute Tox. 4 *

Eye Dam. 1

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H360FD

H341

H372**

H312

H302

H318

H317

H400

H410

GHS05

GHS08

GHS07

GHS09

Dgr

H360FD

H341

H372**

H312

H302

H318

H317

H410

 

 

 

005-007-00-2

boric acid; [1]

boric acid; [2]

233-139-2 [1]

234-343-4 [2]

10043-35-3 [1]

11113-50-1 [2]

Repr. 1B

H360FD

GHS08

Dgr

H360FD

 

Repr.1B;

H360FD: C ≥ 5,5  %

 

005-008-00-8

diboron trioxide;

boric oxide

215-125-8

1303-86-2

Repr. 1B

H360FD

GHS08

Dgr

H360FD

 

Repr.1B;

H360FD:C ≥ 3,1  %

 

005-009-00-3

tetrabutylammonium butyltriphenylborate

418-080-4

120307-06-4

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H317

H400

H410

GHS07

GHS09

Wng

H317

H410

 

 

 

005-010-00-9

N, N-dimethylanilinium tetrakis(pentafluorophenyl)borate

422-050-6

118612-00-3

Carc. 2

Acute Tox. 4 *

Skin Irrit. 2

Eye Dam. 1

H351

H302

H315

H318

GHS08

GHS05

GHS07

Dgr

H351

H302

H315

H318

 

 

 

005-011-00-4

disodium tetraborate, anhydrous; boric acid, disodium salt; [1]

tetraboron disodium heptaoxide, hydrate; [2]

orthoboric acid, sodium salt [3]

215-540-4 [1]

235-541-3 [2]

237-560-2 [3]

1330-43-4 [1]

12267-73-1 [2]

13840-56-7 [3]

Repr. 1B

H360FD

GHS08

Dgr

H360FD

 

Repr. 1B; H360FD: C ≥4,5  %

 

005-011-01-1

disodium tetraborate decahydrate;

borax decahydrate

215-540-4

1303-96-4

Repr. 1B

H360FD

GHS08

Dgr

H360FD

 

Repr.1B; H360FD: C ≥ 8,5  %

 

005-011-02-9

disodium tetraborate pentahydrate;

borax pentahydrate

215-540-4

12179-04-3

Repr. 1B

H360FD

GHS08

Dgr

H360FD

 

Repr.B; H360FD: C ≥ 6,5  %

 

005-012-00-X

diethyl{4-[1,5,5-tris(4-diethylaminophenyl)penta-2,4-dienylidene]cyclohexa-2,5-dienylidene}ammonium butyltriphenylborate

418-070-1

141714-54-7

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H317

H400

H410

GHS07

GHS09

Wng

H317

H410

 

 

 

005-013-00-5

diethylmethoxyborane

425-380-9

7397-46-8

Pyr. Liq. 1

Acute Tox. 4 *

Acute Tox. 4 *

Acute Tox. 4 *

STOT RE 2 *

Skin Corr. 1B

Skin Sens. 1

Aquatic Chronic 4

H250

H332

H312

H302

H373**

H314

H317

H413

GHS02

GHS05

GHS08

GHS07

Dgr

H250

H332

H312

H302

H373**

H314

H317

H413

 

 

 

005-014-00-0

4-formylphenylboronic acid

438-670-5

87199-17-5

Skin Sens. 1

H317

GHS07

Wng

H317

 

 

 

005-015-00-6

1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

414-380-4

140681-55-6

Acute Tox. 4 *

Eye Dam. 1

Skin Sens. 1

Aquatic Chronic 3

H302

H318

H317

H412

GHS05

GHS07

Dgr

H302

H318

H317

H412

 

 

 

005-016-00-1

tetrabutylammonium butyl tris-(4-tert-butylphenyl)borate

431-370-5

Aquatic Chronic 4

H413

H413

 

 

 

005-017-00-7

sodium perborate; [1]

sodium peroxometaborate; [2]

sodium peroxoborate;

[containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]

239-172-9 [1]

231-556-4 [2]

15120-21-5 [1]

7632-04-4 [2]

Ox. Sol. 2

Repr. 1B

Acute Tox. 4 *

STOT SE 3

Eye Dam. 1

H272

H360Df

H302

H335

H318

GHS03

GHS05

GHS08

GHS07

Dgr

H272

H360Df

H302

H335

H318

 

Repr.1B; H360Df: C ≥9 % Repr.1B; H360 D: 6,5  % ≤ C <9 % Eye Dam. 1; H318: C ≥ 22 % Eye Irrit. 2; H319: 14 % ≤ C < 22 %

 

005-017-01-4

sodium perborate; [1]

sodium peroxometaborate; [2]

sodium peroxoborate;

[containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]

239-172-9 [1] 231-556-4 [2]

15120-21-5 [1]

7632-04-4 [2]

Ox. Sol. 2

Repr. 1B

Acute Tox. 3 *

Acute Tox. 4 *

STOT SE 3

Eye Dam. 1

H272

H360Df

H331

H302

H335

H318

GHS03

GHS06

GHS05

GHS08

Dgr

H272

H360Df

H331

H302

H335

H318

 

Repr. 1B; H360Df: C ≥9 % Repr. 1B; H360D: 6,5  % ≤ C < 9 % Eye Dam. 1; H318: C ≥ 22 % Eye Irrit. 2; H319: 14 % ≤ C < 22 %

 

005-018-00-2

perboric acid (H3BO2(O2)), monosodium salt trihydrate; [1]

perboric acid, sodium salt, tetrahydrate; [2]

perboric acid (HBO(O2)), sodium salt, tetrahydrate; [3]

sodium peroxoborate hexahydrate; [containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]

239-172-9 [1]

234-390-0 [2]

231-556-4 [3]

13517-20-9 [1]

37244-98-7 [2]

10486-00-7 [3]

Repr. 1B

STOT SE 3

Eye Dam. 1

H360Df

H335

H318

GHS05

GHS08

GHS07

Dgr

H360Df

H335

H318

 

Repr. 1B;

H360Df: C ≥ 14 % Repr. 1B;

H360D: 10 % ≤ C < 14 % Eye Dam. 1; H318: C ≥ 36 % Eye Irrit. 2;

H319: 22 % ≤ C < 36 %

 

005-018-01-X

perboric acid (H3BO2(O2)), monosodium salt, trihydrate; [1]

perboric acid, sodium salt, tetrahydrate; [2]

perboric acid (HBO(O2)), sodium salt, tetrahydrate; [3]

sodium peroxoborate hexahydrate; [containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]

239-172-9 [1]

234-390-0 [2]

231-556-4 [3]

13517-20-9 [1]

37244-98-7 [2]

10486-00-7 [3]

Repr. 1B

Acute Tox. 4 *

STOT SE 3

Eye Dam. 1

H360Df

H332

H335

H318

GHS05

GHS08

GHS07

Dgr

H360Df

H332

H335

H318

 

Repr. 1B; H360

Df: C ≥ 14 % Repr. 1B; H360D: 10 % ≤ C < 14 % Eye Dam. 1; H318: C ≥ 36 % Eye Irrit. 2; H319: 22 % ≤ C < 36 %

 

005-019-00-8

perboric acid, sodium salt; [1]

perboric acid, sodium salt, monohydrate; [2]

perboric acid (HBO(O2)), sodium salt, monohydrate; [3]

sodium peroxoborate;

[containing < 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]

234-390-0 [1]

234-390-0 [2]

231-556-4 [3]

11138-47-9 [1]

12040-72-1 [2]

10332-33-9 [3]

Ox. Sol. 3

Repr. 1B

Acute Tox. 4 *

STOT SE 3

Eye Dam. 1

H272

H360Df

H302

H335

H318

GHS03

GHS05

GHS08

GHS07

Dgr

H272

H360Df

H302

H335

H318

 

Repr. 1B; H360Df: C ≥ 9 %

Repr. 1B; H360D: 6,5  % ≤ C < 9 %

Eye Dam. 1; H318: C ≥ 22 %

Eye Irrit. 2; H319: 14 % ≤ C < 22 %

 

005-019-01-5

perboric acid, sodium salt; [1]

perboric acid, sodium salt, monohydrate; [2]

perboric acid (HBO(O2)), sodium salt, monohydrate;[3]

sodium peroxoborate;

[containing ≥ 0,1 % (w/w) of particles with an aerodynamic diameter of below 50 μm]

234-390-0 [1]

234-390-0 [2]

231-556-4 [3]

11138-47-9 [1]

12040-72-1 [2]

10332-33-9 [3]

Ox. Sol. 3

Repr. 1B

Acute Tox. 3 *

Acute Tox. 4 *

STOT SE 3

Eye Dam. 1

H272

H360Df

H331

H302

H335

H318

GHS03

GHS06

GHS05

GHS08

Dgr

H272

H360Df

H331

H302

H335

H318

 

Repr. 1B; H360Df: C ≥

9 %

Repr. 1B; H360D: 6,5  %

≤ C < 9 %

Eye Dam. 1; H318: C ≥ 22 %

Eye Irrit. 2; H319: 14 % ≤ C < 22 %

 

006-001-00-2

carbon monoxide

211-128-3

630-08-0

Flam. Gas 1

Press. Gas

Repr. 1A

Acute Tox. 3 *

STOT RE 1

H220

H360D ***

H331

H372 **

GHS02

GHS04

GHS06

GHS08

Dgr

H220

H360D *** H331

H372 **

 

 

U

006-002-00-8

phosgene; carbonyl chloride

200-870-3

75-44-5

Press. Gas

Acute Tox. 2 *

Skin Corr. 1B

H330

H314

GHS04

GHS06

GHS05

Dgr

H330

H314

 

 

U

006-003-00-3

carbon disulphide

200-843-6

75-15-0

Flam. Liq. 2

Repr. 2

STOT RE 1

Eye Irrit. 2

Skin Irrit. 2

H225

H361fd

H372 **

H319

H315

GHS02

GHS08

GHS07

Dgr

H225

H361fd

H372 **

H319

H315

 

Repr. 2; H361fd: C ≥ 1 %

STOT RE 1; H372: C ≥ 1 %

STOT RE 2; H373: 0,2  %

≤ C < 1 %

 

006-004-00-9

calcium carbide

200-848-3

75-20-7

Water-react. 1

H260

GHS02

Dgr

H260

 

 

T

006-005-00-4

thiram (ISO);

tetramethylthiuram disulphide

205-286-2

137-26-8

Acute Tox. 4 *

Acute Tox. 4 *

STOT RE 2 *

Eye Irrit. 2

Skin Irrit. 2

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H332

H302

H373 **

H319

H315

H317

H400

H410

GHS08

GHS07

GHS09

Wng

H332

H302

H373 **

H319

H315

H317

H410

 

M = 10

 

006-006-00-X

hydrogen cyanide;

hydrocyanic acid

200-821-6

74-90-8

Flam. Liq. 1

Acute Tox. 2 * Aquatic Acute 1

Aquatic Chronic 1

H224

H330

H400

H410

GHS02

GHS06

GHS09

Dgr

H224

H330

H410

 

 

 

006-006-01-7

hydrogen cyanide … %;

hydrocyanic acid … %

200-821-6

74-90-8

Acute Tox. 2 *

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H330

H310

H300

H400

H410

GHS06

GHS09

Dgr

H330

H310

H300

H410

 

 

B

006-007-00-5

salts of hydrogen cyanide with the exception of complex cyanides such as ferrocyanides, ferricyanides and mercuric oxycyanide and those specified elsewhere in this Annex

Acute Tox. 2 *

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H330

H310

H300

H400

H410

GHS06

GHS09

Dgr

H330

H310

H300

H410

EUH032

 

A

006-008-00-0

antu (ISO);

1-(1-naphthyl)-2-thiourea

201-706-3

86-88-4

Acute Tox. 2 *

Carc. 2

H300

H351

GHS06

GHS08

Dgr

H300

H351

 

 

 

006-009-00-6

1-isopropyl-3-methylpyrazol-5-yl dimethylcarbamate;

isolan

204-318-2

119-38-0

Acute Tox. 1

Acute Tox. 2 *

H310

H300

GHS06

Dgr

H310

H300

 

 

 

006-010-00-1

5,5-dimethyl-3-oxocyclohex-1-enyl dimethylcarbamate 5,5-dimethyldihydroresorcinol dimethylcarbamate; dimetan

204-525-8

122-15-6

Acute Tox. 3 *

H301

GHS06

Dgr

H301

 

 

 

006-011-00-7

carbaryl (ISO);

1-naphthyl methylcarbamate

200-555-0

63-25-2

Carc. 2

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

H351

H332

H302

H400

GHS08

GHS07

GHS09

Wng

H351

H332

H302

H400

 

M=100

 

006-012-00-2

ziram (ISO);

zinc bis dimethyldithiocarbamate

205-288-3

137-30-4

Acute Tox. 2 *

Acute Tox. 4 *

STOT RE 2 *

STOT SE 3

Eye Dam. 1

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H302

H373 **

H335

H318

H317

H400

H410

GHS06

GHS08

GHS05

GHS09

Dgr

H330

H302

H373 **

H335

H318

H317

H410

 

M = 100

 

006-013-00-8

metam-sodium (ISO);

sodium methyldithiocarbamate

205-293-0

137-42-8

Acute Tox. 4 *

Skin Corr. 1B

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H314

H317

H400

H410

GHS05

GHS07

GHS09

Dgr

H302

H314

H317

H410

EUH031

 

 

006-014-00-3

nabam (ISO);

disodium ethylenebis(N, N'-dithiocarbamate)

205-547-0

142-59-6

Acute Tox. 4 *

STOT SE 3

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H335

H317

H410

GHS07

GHS09

Wng

H302

H335

H317

H410

 

 

 

006-015-00-9

diuron (ISO);

3-(3,4-dichlorophenyl)-1,1-dimethylurea

206-354-4

330-54-1

Carc. 2

Acute Tox. 4 *

STOT RE 2 *

Aquatic Acute 1

Aquatic Chronic 1

H351

H302

H373**

H400

H410

GHS08

GHS07

GHS09

Wng

H351

H302

H373** H410

 

M = 10

 

006-016-00-4

propoxur (ISO);

2-isopropyloxyphenyl N-methylcarbamate;

2-isopropoxyphenyl methylcarbamate

204-043-8

114-26-1

Acute Tox. 3 * Aquatic Acute 1

Aquatic Chronic 1

H301

H400

H410

GHS06

GHS09

Dgr

H301

H410

 

 

 

006-017-00-X

aldicarb (ISO);

2-methyl-2-(methylthio)propanal-O-(N-methylcarbamoyl)oxime

204-123-2

116-06-3

Acute Tox. 2 *

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H330

H300

H311

H400

H410

GHS06

GHS09

Dgr

H330

H300

H311

H410

 

 

 

006-018-00-5

aminocarb (ISO);

4-dimethylamino-3-tolyl methylcarbamate

217-990-7

2032-59-9

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H311

H301

H400

H410

GHS06

GHS09

Dgr

H311

H301

H410

 

 

 

006-019-00-0

di-allate (ISO);

S-(2,3-dichloroallyl)-N,N-diisopropylthiocarbamate

218-961-1

2303-16-4

Carc. 2

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H351

H302

H400

H410

GHS08

GHS07

GHS09

Wng

H351

H302

H410

 

 

 

006-020-00-6

barban (ISO);

4-chlorbut-2-ynyl N-(3-chlorophenyl)carbamate

202-930-4

101-27-9

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H317

H400

H410

GHS07

GHS09

Wng

H302

H317

H410

 

 

 

006-021-00-1

linuron (ISO);

3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea

206-356-5

330-55-2

Repr. 1B Carc. 2

Acute Tox. 4 *

STOT RE 2 *

Aquatic Acute 1

Aquatic Chronic 1

H360Df

H351

H302

H373 **

H400

H410

GHS08

GHS07

GHS09

Dgr

H360Df

H351

H302

H373 **

H410

 

 

 

006-022-00-7

decarbofuran (ISO);

2,3-dihydro-2-methylbenzofuran-7-yl methylcarbamate

1563-67-3

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

H331

H311

H301

GHS06

Dgr

H331

H311

H301

 

 

 

006-023-00-2

mercaptodimethur (ISO);

methiocarb (ISO);

3,5-dimethyl-4-methylthiophenyl N-methylcarbamate

217-991-2

2032-65-7

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H301

H400

H410

GHS06

GHS09

Dgr

H301

H410

 

 

 

006-024-00-8

proxan-sodium (ISO);

sodium O-isopropyldithiocarbonate

205-443-5

140-93-2

Acute Tox. 4 *

Skin Irrit. 2

Aquatic Chronic 2

H302

H315

H411

GHS07

GHS09

Wng

H302

H315

H411

 

 

 

006-025-00-3

allethrin;

(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate; bioallethrin;

(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate; [1]

S-bioallethrin; [3]

(S)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate; [2]

esbiothrin;

(RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl(1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate [3]

209-542-4 [1]

249-013-5 [2]-[3]

584-79-2 [1]

28434-00-6 [2]

84030-86-4 [3]

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H332

H302

H400

H410

GHS07

GHS09

Wng

H332

H302

H410

 

 

C

006-026-00-9

carbofuran (ISO);

2,3-dihydro-2,2-dimethylbenzofuran-7-yl N-methylcarbamate

216-353-0

1563-66-2

Acute Tox. 2 *

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H330

H300

H400

H410

GHS06

GHS09

Dgr

H330

H300

H410

 

 

 

006-028-00-X

dinobuton (ISO);

2-(1-methylpropyl)-4,6-dinitrophenyl isopropyl carbonate

213-546-1

973-21-7

Acute Tox. 3 * Aquatic Acute 1

Aquatic Chronic 1

H301

H400

H410

GHS06

GHS09

Dgr

H301

H410

 

 

 

006-029-00-5

dioxacarb (ISO);

2-(1,3-dioxolan-2-yl)phenyl N-methylcarbamate

230-253-4

6988-21-2

Acute Tox. 3 * Aquatic Chronic 2

H301

H411

GHS06

GHS09

Dgr

H301

H411

 

 

 

006-030-00-0

EPTC (ISO);

S-ethyl dipropylthiocarbamate

212-073-8

759-94-4

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

006-031-00-6

formetanate (ISO);

3-[(EZ)-dimethylaminomethyleneamino]phenyl methylcarbamate

244-879-0

22259-30-9

Acute Tox. 2 *

Acute Tox. 2 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H300

H317

H400

H410

GHS06

GHS09

Dgr

H330

H300

H317

H410

 

 

 

006-032-00-1

monolinuron (ISO);

3-(4-chlorophenyl)-1-methoxy-1-methylurea

217-129-5

1746-81-2

Acute Tox. 4 *

STOT RE 2 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H373 **

H400

H410

GHS08

GHS07

GHS09

Wng

H302

H373 **

H410

 

 

 

006-033-00-7

metoxuron (ISO);

3-(3-chloro-4-methoxyphenyl)-1,1-dimethylurea

243-433-2

19937-59-8

Aquatic Acute 1

Aquatic Chronic 1

H400

H410

GHS09

Wng

H410

 

 

 

006-034-00-2

pebulate (ISO);

N-butyl-N-ethyl-S-propylthiocarbamate

214-215-4

1114-71-2

Acute Tox. 4 *

Aquatic Chronic 2

H302

H411

GHS07

GHS09

Wng

H302

H411

 

 

 

006-036-00-3

benzthiazuron (ISO);

1-benzothiazol-2-yl-3-methylurea

217-685-9

1929-88-0

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

006-037-00-9

promecarb (ISO);

3-isopropyl-5-methylphenyl N-methylcarbamate

220-113-0

2631-37-0

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H301

H400

H410

GHS06

GHS09

Dgr

H301

H410

 

 

 

006-038-00-4

sulfallate (ISO);

2-chloroallyl N, N-dimethyldithiocarbamate

202-388-9

95-06-7

Carc. 1B

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H350

H302

H400

H410

GHS08

GHS07

GHS09

Dgr

H350

H302

H410

 

 

 

006-039-00-X

tri-allate (ISO);

S-2,3,3-trichloroallyl diisopropylthiocarbamate

218-962-7

2303-17-5

Acute Tox. 4 *

STOT RE 2 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H373 **

H317

H400

H410

GHS08

GHS07

GHS09

Wng

H302

H373 **

H317

H410

 

 

 

006-040-00-5

3-methylpyrazol-5-yl-dimethylcarbamate; monometilan

2532-43-6

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

H331

H311

H301

GHS06

Dgr

H331

H311

H301

 

 

 

006-041-00-0

dimethylcarbamoyl chloride

201-208-6

79-44-7

Carc. 1B

Acute Tox. 3 *

Acute Tox. 4 *

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

H350

H331

H302

H319

H335

H315

GHS06

GHS08

Dgr

H350

H331

H302

H319

H335

H315

 

Carc. 1B;

H350: C ≥ 0,001  %

 

006-042-00-6

monuron (ISO);

3-(4-chlorophenyl)-1,1-dimethylurea

205-766-1

150-68-5

Carc. 2

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H351

H302

H400

H410

GHS08

GHS07

GHS09

Wng

H351

H302

H410

 

 

 

006-043-00-1

3-(4-chlorophenyl)-1,1-dimethyluronium trichloroacetate;

monuron-TCA

140-41-0

Carc. 2

Eye Irrit. 2

Skin Irrit. 2

Aquatic Acute 1

Aquatic Chronic 1

H351

H319

H315

H400

H410

GHS08

GHS07

GHS09

Wng

H351

H319

H315

H410

 

 

 

006-044-00-7

isoproturon (ISO);

3-(4-isopropylphenyl)-1,1-dimethylurea

251-835-4

34123-59-6

Carc. 2

Aquatic Acute 1

Aquatic Chronic 1

H351

H400

H410

GHS08

GHS09

Wng

H351

H410

 

M = 10

 

006-045-00-2

methomyl (ISO);

1-(methylthio)ethylideneamino N-methylcarbamate

240-815-0

16752-77-5

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H400

H410

GHS06

GHS09

Dgr

H300

H410

 

M=100

 

006-047-00-3

bufencarb (ISO);

reaction mass of 3-(1-methylbutyl)phenyl N-methylcarbamate and 3-(1-ethylpropyl)phenyl N-methylcarbamate

8065-36-9

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H311

H301

H400

H410

GHS06

GHS09

Dgr

H311

H301

H410

 

 

 

006-048-00-9

ethiofencarb (ISO);

2-(ethylthiomethyl)phenyl N-methylcarbamate

249-981-9

29973-13-5

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

006-049-00-4

dixanthogen;

O, O-diethyl dithiobis(thioformate)

207-944-4

502-55-6

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

006-050-00-X

1,1-dimethyl-3-phenyluronium trichloroacetate;

fenuron-TCA

4482-55-7

Skin Irrit. 2

Aquatic Acute 1

Aquatic Chronic 1

H315

H400

H410

GHS07

GHS09

Wng

H315

H410

 

 

 

006-051-00-5

ferbam (ISO);

iron tris(dimethyldithiocarbamate)

238-484-2

14484-64-1

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Aquatic Acute 1

Aquatic Chronic 1

H319

H335

H315

H400

H410

GHS07

GHS09

Wng

H319

H335

H315

H410

 

 

 

006-052-00-0

formetanate hydrochloride;

3-(N, N-dimethylaminomethyleneamino)phenyl N-methylcarbamate

245-656-0

23422-53-9

Acute Tox. 2 *

Acute Tox. 2 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H300

H317

H400

H410

GHS06

GHS09

Dgr

H330

H300

H317

H410

 

 

 

006-053-00-6

isoprocarb (ISO);

2-isopropylphenyl N-methylcarbamate

220-114-6

2631-40-5

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

006-054-00-1

mexacarbate (ISO);

3,5-dimethyl-4-dimethylaminophenyl N-methylcarbamate

206-249-3

315-18-4

Acute Tox. 2 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H312

H400

H410

GHS06

GHS09

Dgr

H300

H312

H410

 

 

 

006-055-00-7

xylylcarb (ISO);

3,4-dimethylphenyl N-methylcarbamate;

3,4-xylyl methylcarbamate;

MPMC

219-364-9

2425-10-7

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

006-056-00-2

metolcarb (ISO);

m-tolyl methylcarbamate;

MTMC

214-446-0

1129-41-5

Acute Tox. 4 *

Aquatic Chronic 2

H302

H411

GHS07

GHS09

Wng

H302

H411

 

 

 

006-057-00-8

nitrapyrin (ISO);

2-chloro-6-trichloromethylpyridine

217-682-2

1929-82-4

Acute Tox. 4 *

Aquatic Chronic 2

H302

H411

GHS07

GHS09

Wng

H302

H411

 

 

 

006-058-00-3

noruron (ISO);

1,1-dimethyl-3-(perhydro-4,7-methanoinden-5-yl)urea

2163-79-3

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

006-059-00-9

oxamyl (ISO);

N',N'-dimethylcarbamoyl(methylthio)methylenamine N-methylcarbamate;

245-445-3

23135-22-0

Acute Tox. 2 *

Acute Tox. 2 *

Acute Tox. 4 *

Aquatic Chronic 2

H330

H300

H312

H411

GHS06

GHS09

Dgr

H330

H300

H312

H411

 

 

 

006-060-00-4

oxycarboxin (ISO);

2,3-dihydro-6-methyl-5-(N-phenylcarbamoyl)-1,4-oxothiine 4,4-dioxide

226-066-2

5259-88-1

Acute Tox. 4 *

Aquatic Chronic 3

H302

H412

GHS07

Wng

H302

H412

 

 

 

006-061-00-X

S-ethyl N-(dimethylaminopropyl)thiocarbamatehydrochloride;

prothiocarb hydrochloride

243-193-9

19622-19-6

Acute Tox. 4 *

Aquatic Chronic 2

H302

H411

GHS07

GHS09

Wng

H302

H411

 

 

 

006-062-00-5

methyl 3,4-dichlorophenylcarbanilate;

SWEP.

1918-18-9

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

006-063-00-0

thiobencarb (ISO);

S-4-chlorobenzyl diethylthiocarbamate

248-924-5

28249-77-6

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

006-064-00-6

thiofanox (ISO);

3,3-dimethyl-1-(methylthio)butanone-O-(N-methylcarbamoyl)oxime

254-346-4

39196-18-4

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

 

 

006-065-00-1

3-chloro-6-cyano-bicyclo(2,2,1)heptan-2-one-O-(N-methylcarbamoyl)oxime;

triamid

15271-41-7

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Chronic 2

H300

H311

H411

GHS06

GHS09

Dgr

H300

H311

H411

 

 

 

006-066-00-7

vernolate (ISO);

S-propyl dipropylthiocarbamate

217-681-7

1929-77-7

Acute Tox. 4 *

Aquatic Chronic 2

H302

H411

GHS07

GHS09

Wng

H302

H411

 

 

 

006-067-00-2

XMC;

3,5-xylyl methylcarbamate

2655-14-3

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

006-068-00-8

diazomethane

206-382-7

334-88-3

Carc. 1B

H350

GHS08

Dgr

H350

 

 

 

006-069-00-3

thiophanate-methyl (ISO);

1,2-di-(3-methoxycarbonyl-2-thioureido)benzene

245-740-7

23564-05-8

Muta. 2

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H341

H332

H317

H400

H410

GHS08

GHS07

GHS09

Wng

H341

H332

H317

H410

 

 

 

006-070-00-9

furmecyclox (ISO);

N-cyclohexyl-N-methoxy-2,5-dimethyl-3-furamide

262-302-0

60568-05-0

Carc. 2

Aquatic Acute 1

Aquatic Chronic 1

H351

H400

H410

GHS08

GHS09

Wng

H351

H410

 

 

 

006-071-00-4

cyclooct-4-en-1-yl methyl carbonate

401-620-8

87731-18-8

Skin Sens. 1

H317

GHS07

Wng

H317

 

 

 

006-072-00-X

prosulfocarb (ISO);

S-benzyl N, N-dipropylthiocarbamate

401-730-6

52888-80-9

Acute Tox. 4 *

Skin Sens. 1

Aquatic Chronic 2

H302

H317

H411

GHS07

GHS09

Wng

H302

H317

H411

 

 

 

006-073-00-5

3-(dimethylamino)propylurea

401-950-2

31506-43-1

Eye Dam. 1

H318

GHS05

Dgr

H318

 

 

 

006-074-00-0

2-(3-(prop-1-en-2-yl)phenyl)prop-2-yl isocyanate

402-440-2

2094-99-7

Acute Tox. 2 *

Skin Corr. 1B

STOT RE 2 *

Resp. Sens. 1

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H314

H373 **

H334

H317

H400

H410

GHS06

GHS08

GHS05

GHS09

Dgr

H330

H314

H373 **

H334

H317

H410

 

 

 

006-076-00-1

mancozeb (ISO);

manganese

ethylenebis(dithiocarbamate)

(polymeric) complex with zinc salt

8018-01-7

Repr. 2

Skin Sens. 1

Aquatic Acute 1

H361d***

H317

H400

GHS08

GHS07

GHS09

Wng

H361d***

H317

H400

 

M=10

 

006-077-00-7

maneb (ISO);

manganese

ethylenebis(dithiocarbamate)

(polymeric)

235-654-8

12427-38-2

Repr. 2

Acute Tox. 4 *

Eye Irrit. 2

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H361d***

H332

H319

H317

H400

H410

GHS08

GHS07

GHS09

Wng

H361d***

H332

H319

H317

H410

 

M=10

 

006-078-00-2

zineb (ISO);

zinc ethylenebis(dithiocarbamate) (polymeric)

235-180-1

12122-67-7

STOT SE 3

Skin Sens. 1

H335

H317

GHS07

Wng

H335

H317

 

 

 

006-079-00-8

disulfiram;

tetraethylthiuramdisulfide

202-607-8

97-77-8

Acute Tox. 4 *

STOT RE 2 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H373 **

H317

H400

H410

GHS08

GHS07

GHS09

Wng

H302

H373 **

H317

H410

 

 

 

006-080-00-3

tetramethylthiuram monosulphide

202-605-7

97-74-5

Acute Tox. 4 *

Skin Sens. 1

Aquatic Chronic 2

H302

H317

H411

GHS07

GHS09

Wng

H302

H317

H411

 

 

 

006-081-00-9

zinc bis(dibutyldithiocarbamate)

205-232-8

136-23-2

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H319

H335

H315

H317

H400

H410

GHS07

GHS09

Wng

H319

H335

H315

H317

H410

 

 

 

006-082-00-4

zinc bis(diethyldithiocarbamate)

238-270-9

14324-55-1

Acute Tox. 4 *

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H319

H335

H315

H317

H400

H410

GHS07

GHS09

Wng

H302

H319

H335

H315

H317

H410

 

 

 

006-083-00-X

butocarboxim (ISO);

3-(methylthio)-2-butanone O-[(methylamino)carbonyl]oxime

252-139-3

34681-10-2

Flam. Liq. 3

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

Eye Irrit. 2

Aquatic Acute 1

Aquatic Chronic 1

H226

H331

H311

H301

H319

H400

H410

GHS02

GHS06

GHS09

Dgr

H226

H331

H311

H301

H319

H410

 

 

 

006-084-00-5

carbosulfan (ISO);

2,3-dihydro-2,2-dimethyl-7-benzofuryl [(dibutylamino)thio]methylcarbamate

259-565-9

55285-14-8

Acute Tox. 2 *

Acute Tox. 3 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H301

H317

H400

H410

GHS06

GHS09

Dgr

H330

H301

H317

H410

 

 

 

006-085-00-0

fenobucarb (ISO);

2-butylphenyl methylcarbamate

223-188-8

3766-81-2

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

006-086-00-6

fenoxycarb (ISO);

ethyl [2-(4-phenoxyphenoxy)ethyl]carbamate

276-696-7

72490-01-8

Carc. 2

Aquatic Acute 1

Aquatic Chronic 1

H351

H400

H410

GHS08

GHS09

Wng

H351

H410

 

M = 1

M = 10 000

 

006-087-00-1

furathiocarb (ISO);

2,3-dihydro-2,2-dimethyl-7-benzofuryl 2,4-dimethyl-6-oxa-5-oxo-3-thia-2,4-diazadecanoate

265-974-3

65907-30-4

Acute Tox. 2 *

Acute Tox. 3 *

STOT RE 2 *

Eye Irrit. 2

Skin Irrit. 2

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H301

H373**

H319

H315

H317

H400

H410

GHS06

GHS08

GHS09

Dgr

H330

H301

H373**

H319

H315

H317

H410

 

M = 100

 

006-088-00-7

benfuracarb (ISO);

ethyl N-[2,3-dihydro-2,2-dimethylbenzofuran-7-yloxycarbonyl(methyl)aminothio]-N-isopropyl-β-alaninate

82560-54-1

Repr. 2

Acute Tox. 3 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H361f***

H331

H302

H400

H410

GHS06

GHS08

GHS09

Dgr

H361f***

H331

H302

H410

 

 

 

006-090-00-8

2-(3-iodoprop-2-yn-1-yloxy)ethyl phenylcarbamate

408-010-0

88558-41-2

Acute Tox. 4 *

Eye Dam. 1

Aquatic Chronic 3

H332

H318

H412

GHS05

GHS07

Dgr

H332

H318

H412

 

 

 

006-091-00-3

propineb (ISO);

polymeric zinc propylenebis(dithiocarbamate)

9016-72-2

Acute Tox. 4 *

STOT RE 2 *

Skin Sens. 1

Aquatic Acute 1

H332

H373**

H317

H400

GHS08

GHS07

GHS09

Wng

H332

H373**

H317

H400

 

 

 

006-092-00-9

tert-butyl (1S)-N-[1-((2S)-2-oxiranyl)-2-phenylethyl]carbamate

425-420-5

98737-29-2

Aquatic Acute 1

Aquatic Chronic 1

H400

H410

GHS09

Wng

H410

 

 

 

006-093-00-4

2,2'-dithio di(ethylammonium)-bis(dibenzyldithiocarbamate)

427-180-7

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H317

H400

H410

GHS07

GHS09

Wng

H302

H317

H410

 

 

 

006-094-00-X

O-isobutyl-N-ethoxy carbonylthiocarbamate

434-350-4

103122-66-3

Flam. Liq. 3

Carc. 1B

Muta. 1B

Acute Tox. 4 *

STOT RE 2 *

Skin Sens. 1

Aquatic Chronic 2

H226

H350

H340

H302

H373**

H317

H411

GHS02

GHS08

GHS07

GHS09

Dgr

H226

H350

H340

H302

H373**

H317

H411

 

 

 

006-095-00-5

fosetyl-aluminium (ISO);

aluminium triethyl triphosphonate

254-320-2

39148-24-8

Eye Dam. 1

H318

GHS05

Dgr

H318

 

 

 

006-096-00-0

chlorpropham (ISO);

isopropyl 3-chlorocarbanilate

202-925-7

101-21-3

Carc. 2

STOT RE 2 *

Aquatic Chronic 2

H351

H373**

H411

GHS08

GHS09

Wng

H351

H373**

H411

 

 

 

006-097-00-6

1-phenyl-3-(p-toluenesulfonyl)urea

424-620-1

13909-63-2

Acute Tox. 4 *

STOT RE 2 *

Aquatic Chronic 3

H302

H373**

H412

GHS08

GHS07

Wng

H302

H373**

H412

 

 

 

006-098-00-1

tert-butyl (1R,5S)-3-azabicyclo[3.1.0]hex-6-ylcarbamate

429-170-8

134575-17-0

Acute Tox. 4 *

STOT RE 2 *

Eye Dam. 1

Skin Sens. 1

H302

H373**

H318

H317

GHS05

GHS08

GHS07

Dgr

H302

H373**

H318

H317

 

 

 

006-099-00-7

N-(p-toluenesulfonyl)-N'-(3-(p-toluenesulfonyloxy)phenyl)urea;

3-][(4-methylphenyl)sulfonyl]carbamoyl}amino)phenyl4-methylbenzenesulfonate

520-2

232938-43-1

Aquatic Chronic 2

H411

GHS09

H411

 

 

 

006-101-00-6

reaction mass of: N, N''-(methylenedi-4,1-phenylene)bis[N'-phenylurea];

N-(4-[[4-[[(phenylamino)carbonyl]amino]phenylmethyl]phenyl]-N'-cyclohexylurea;

N, N''-(methylenedi-4,1-phenylene)bis[N'-cyclohexylurea]

423-070-8

Aquatic Chronic 4

H413

H413

 

 

 

006-102-00-1

O-hexyl-N-ethoxycarbonylthiocarbamate

432-750-3

Carc. 1B

Muta. 1B

Acute Tox. 4 *

STOT RE 2 *

Skin Sens. 1

Aquatic Chronic 2

H350

H340

H302

H373**

H317

H411

GHS08

GHS07

GHS09

Dgr

H350

H340

H302

H373**

H317

H411

 

 

 

006-103-00-7

N, N''-(methylenedi-4,1-phenylene)bis[N'-octyl]urea

445-760-8

Eye Dam. 1

Resp. Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H318

H334

H400

H410

GHS05

GHS08

GHS09

Dgr

H318

H334

H410

 

M=100

 

007-001-00-5

ammonia, anhydrous

231-635-3

7664-41-7

Flam. Gas 2

Press. Gas

Acute Tox. 3 *

Skin Corr. 1B

Aquatic Acute 1

H221

H331

H314

H400

GHS04

GHS06

GHS05

GHS09

Dgr

H221

H331

H314

H400

 

 

U

007-001-01-2

ammonia ….%

215-647-6

1336-21-6

Skin Corr. 1B

Aquatic Acute 1

H314

H400

GHS05

GHS09

Dgr

H314

H400

 

STOT SE 3; H335: C ≥ 5 %

B

007-002-00-0

nitrogen dioxide; [1]

dinitrogen tetraoxide [2]

233-272-6 [1]

234-126-4 [2]

10102-44-0 [1]

10544-72-6 [2]

Press. Gas

Ox. Gas 1

Acute Tox. 2 *

Skin Corr. 1B

H270

H330

H314

GHS04

GHS03

GHS06

GHS05

Dgr

H270

H330

H314

 

*

STOT SE 3; H335: C ≥0,5  %

5

007-003-00-6

chlormequat chloride (ISO);

2-chloroethyltrimethylammonium chloride

213-666-4

999-81-5

Acute Tox. 4 *

Acute Tox. 4 *

H312

H302

GHS07

Wng

H312

H302

 

 

 

007-006-00-2

ethyl nitrite

203-722-6

109-95-5

Flam. Gas 1

Press. Gas

Acute Tox. 4 *

Acute Tox. 4 *

Acute Tox. 4 *

H220

H332

H312

H302

GHS02

GHS04

GHS07

Dgr

H220

H332

H312

H302

 

 

U

007-007-00-8

ethyl nitrate

210-903-3

625-58-1

Unst. Expl.

H200

GHS01

Dgr

H200

 

 

 

007-008-00-3

hydrazine

206-114-9

302-01-2

Flam. Liq. 3

Carc. 1B

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

Skin Corr. 1B

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H226

H350

H331

H311

H301

H314

H317

H400

H410

GHS02

GHS06

GHS08

GHS05

GHS09

Dgr

H226

H350

H331

H311

H301

H314

H317

H410

 

Skin Corr. 1B; H314: C ≥ 10 % Skin Irrit. 2; H315: 3 % ≤ C < 10 %

Eye Irrit. 2; H319: 3 % ≤ C < 10 %

 

007-009-00-9

dicyclohexylammonium nitrite

221-515-9

3129-91-7

Acute Tox. 4 *

Acute Tox. 4 *

H332

H302

GHS07

Wng

H332

H302

 

*

 

007-010-00-4

sodium nitrite

231-555-9

7632-00-0

Ox. Sol. 3

Acute Tox. 3 *

Aquatic Acute 1

H272

H301

H400

GHS03

GHS06

GHS09

Dgr

H272

H301

H400

 

*

 

007-011-00-X

potassium nitrite

231-832-4

7758-09-0

Ox. Sol. 2

Acute Tox. 3 *

Aquatic Acute 1

H272

H301

H400

GHS03

GHS06

GHS09

Dgr

H272

H301

H400

 

*

 

007-012-00-5

N,N-dimethylhydrazine

200-316-0

57-14-7

Flam. Liq. 2

Carc. 1B

Acute Tox. 3 *

Acute Tox. 3 *

Skin Corr. 1B

Aquatic Chronic 2

H225

H350

H331

H301

H314

H411

GHS02

GHS06

GHS08

GHS05

GHS09

Dgr

H225

H350

H331

H301

H314

H411

 

 

 

007-013-00-0

1,2-dimethylhydrazine

540-73-8

Carc. 1B

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Chronic 2

H350

H331

H311

H301

H411

GHS06

GHS08

GHS09

Dgr

H350

H331

H311

H301

H411

 

Carc. 1B; H350: C ≥ 0,01  %

 

007-014-00-6

salts of hydrazine

Carc. 1B

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H350

H331

H311

H301

H317

H400

H410

GHS06

GHS08

GHS09

Dgr

H350

H331

H311

H301

H317

H410

 

 

A

007-015-00-1

O-ethylhydroxylamine

402-030-3

624-86-2

Flam. Liq. 2

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

STOT RE 1

Eye Irrit. 2

Skin Sens. 1

Aquatic Acute 1

H225

H331

H311

H301

H372 **

H319

H317

H400

GHS02

GHS06

GHS08

GHS09

Dgr

H225

H331

H311

H301

H372 **

H319

H317

H400

 

 

 

007-016-00-7

butyl nitrite

208-862-1

544-16-1

Flam. Liq. 2

Acute Tox. 3 *

Acute Tox. 3 *

H225

H331

H301

GHS02

GHS06

Dgr

H225

H331

H301

 

 

 

007-017-00-2

isobutyl nitrite

208-819-7

542-56-3

Flam. Liq. 2

Carc. 1B

Muta. 2

Acute Tox. 4 *

Acute Tox. 4 *

H225

H350

H341

H332

H302

GHS02

GHS08

GHS07

Dgr

H225

H350

H341

H332

H302

 

 

 

007-018-00-8

sec-butyl nitrite

213-104-8

924-43-6

Flam. Liq. 2

Acute Tox. 4 *

Acute Tox. 4 *

H225

H332

H302

GHS02

GHS07

Dgr

H225

H332

H302

 

 

 

007-019-00-3

tert-butyl nitrite

208-757-0

540-80-7

Flam. Liq. 2

Acute Tox. 4 *

Acute Tox. 4 *

H225

H332

H302

GHS02

GHS07

Dgr

H225

H332

H302

 

 

 

007-020-00-9

pentyl nitrite; [1]

‘amyl nitrite’, mixed isomers [2]

207-332-7 [1]

203-770-8 [2]

463-04-7 [1]

110-46-3 [2]

Flam. Liq. 2

Acute Tox. 4 *

Acute Tox. 4 *

H225

H332

H302

GHS02

GHS07

Dgr

H225

H332

H302

 

 

 

007-021-00-4

hydrazobenzene;

1,2-diphenylhydrazine

204-563-5

122-66-7

Carc. 1B

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H350

H302

H400

H410

GHS08

GHS07

GHS09

Dgr

H350

H302

H410

 

 

 

007-022-00-X

hydrazine bis(3-carboxy-4-hydroxybenzensulfonate)

405-030-1

Carc. 1B

Acute Tox. 4 *

Skin Corr. 1B

Skin Sens. 1

Aquatic Chronic 3

H350

H302

H314

H317

H412

GHS08

GHS05

GHS07

Dgr

H350

H302

H314

H317

H412

 

 

 

007-023-00-5

sodium 3,5-bis(3-(2,4-di-tert-pentylphenoxy)propylcarbamoyl)benzenesulfonate

405-510-0

Skin Irrit. 2

Skin Sens. 1

H315

H317

GHS07

Wng

H315

H317

 

 

 

007-024-00-0

2-(decylthio)ethylammonium chloride

405-640-8

36362-09-1

STOT RE 2 *

Skin Irrit. 2

Eye Dam. 1

Aquatic Acute 1

Aquatic Chronic 1

H373 **

H315

H318

H400

H410

GHS08

GHS05

GHS09

Dgr

H373 **

H315

H318

H410

 

 

 

007-025-00-6

(4-hydrazinophenyl)-N-methylmethanesulfonamide hydrochloride

406-090-1

81880-96-8

Muta. 2

Acute Tox. 3 *

STOT RE 1

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H341

H301

H372 **

H317

H400

H410

GHS06

GHS08

GHS09

Dgr

H341

H301

H372 **

H317

H410

 

 

 

007-026-00-1

oxo-((2,2,6,6-tetramethylpiperidin-4-yl)amino)carbonylacetohydrazide

413-230-5

122035-71-6

Eye Dam. 1

Skin Sens. 1

H318

H317

GHS05

GHS07

Dgr

H318

H317

 

 

 

007-027-00-7

1,6-bis(3,3-bis((1-methylpentylidenimino)propyl)ureido)hexane

420-190-2

771478-66-1

Acute Tox. 4 *

Acute Tox. 4 *

STOT RE 2 *

Skin Corr. 1B

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H312

H302

H373 **

H314

H317

H400

H410

GHS08

GHS05

GHS07

GHS09

Dgr

H312

H302

H373 **

H314

H317

H410

 

 

 

007-028-00-2

hydroxylammonium nitrate

236-691-2

13465-08-2

Expl. 1.1 ****

Carc. 2

Acute Tox. 3 *

Acute Tox. 4 *

STOT RE 2 *

Eye Irrit. 2

Skin Irrit. 2

Skin Sens. 1

Aquatic Acute 1

H201

H351

H311

H302

H373**

H319

H315

H317

H400

GHS01

GHS06

GHS08

GHS09

Dgr

H201

H351

H311

H302

H373**

H319

H315

H317

H400

 

 

 

007-029-00-8

diethyldimethylammonium hydroxide

419-400-5

95500-19-9

Acute Tox. 4 *

Acute Tox. 4 *

Skin Corr. 1A

H312

H302

H314

GHS05

GHS07

Dgr

H312

H302

H314

 

 

 

008-001-00-8

oxygen

231-956-9

7782-44-7

Ox. Gas 1

Press. Gas

H270

GHS03

GHS04

Dgr

H270

 

 

U

008-003-00-9

hydrogen peroxide solution… %

231-765-0

7722-84-1

Ox. Liq. 1

Acute Tox. 4 *

Acute Tox. 4 *

Skin Corr. 1A

H271

H332

H302

H314

GHS03

GHS05

GHS07

Dgr

H271

H332

H302

H314

 

Ox. Liq. 1; H271: C ≥70 %****

Ox. Liq. 2; H272: 50 % ≤ C < 70 % ****

*

Skin Corr. 1A; H314: C ≥ 70 % Skin Corr. 1B; H314: 50 % ≤ C < 70 %

Skin Irrit. 2; H315: 35 % ≤ C < 50 %

Eye Dam. 1; H318: 8 % ≤ C < 50 %

Eye Irrit. 2; H319: 5 % ≤ C< 8 % STOT SE 3; H335; C ≥ 35 %

B

009-001-00-0

fluorine

231-954-8

7782-41-4

Press. Gas

Ox. Gas 1

Acute Tox. 2 *

Skin Corr. 1A

H270

H330

H314

GHS04

GHS03

GHS06

GHS05

Dgr

H270

H330

H314

 

 

 

009-002-00-6

hydrogen fluoride

231-634-8

7664-39-3

Acute Tox. 2 *

Acute Tox. 1

Acute Tox. 2 *

Skin Corr. 1A

H330

H310

H300

H314

GHS06

GHS05

Dgr

H330

H310

H300

H314

 

 

 

009-003-00-1

hydrofluoric acid … %

231-634-8

7664-39-3

Acute Tox. 2 *

Acute Tox. 1

Acute Tox. 2 *

Skin Corr. 1A

H330

H310

H300

H314

GHS06

GHS05

Dgr

H330

H310

H300

H314

 

Skin Corr. 1A; H314: C ≥ 7 % Skin Corr. 1B; H314: 1 % ≤ C< 7 % Eye Irrit. 2; H319: 0,1  % ≤C < 1 %

B

009-004-00-7

sodium fluoride

231-667-8

7681-49-4

Acute Tox. 3 *

Eye Irrit. 2

Skin Irrit. 2

H301

H319

H315

GHS06

Dgr

H301

H319

H315

EUH032

 

 

009-005-00-2

potassium fluoride

232-151-5

7789-23-3

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

H331

H311

H301

GHS06

Dgr

H331

H311

H301

 

 

 

009-006-00-8

ammonium fluoride

235-185-9

12125-01-8

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

H331

H311

H301

GHS06

Dgr

H331

H311

H301

 

 

 

009-007-00-3

sodium bifluoride;

sodium hydrogen difluoride

215-608-3

1333-83-1

Acute Tox. 3 *

Skin Corr. 1B

H301

H314

GHS06

GHS05

Dgr

H301

H314

 

*Skin Corr. 1B; H314: C ≥ 1 % Skin Irrit. 2; H315: 0,1  % ≤ C < % Eye Irrit. 2;

H319: 0,1  % ≤

C < 1 %

 

009-008-00-9

potassium bifluoride;

potassium hydrogen difluoride

232-156-2

7789-29-9

Acute Tox. 3 *

Skin Corr. 1B

H301

H314

GHS06

GHS05

Dgr

H301

H314

 

*

Skin Corr. 1B; H314: C ≥ 1 %

Skin Irrit. 2; H315: 0,1  % ≤ C < 1 %

Eye Irrit. 2; H319: 0,1  % ≤ C < 1 %

 

009-009-00-4

ammonium bifluoride;

ammonium hydrogen difluoride

215-676-4

1341-49-7

Acute Tox. 3 *

Skin Corr. 1B

H301

H314

GHS06

GHS05

Dgr

H301

H314

 

*

Skin Corr. 1B; H314: C ≥ 1 % Skin Irrit.2; H315: 0,1  % ≤ C < 1 %

Eye Irrit. 2; H319: 0,1  % ≤ C < 1 %

 

009-010-00-X

fluoroboric acid … %

240-898-3

16872-11-0

Skin Corr. 1B

H314

GHS05

Dgr

H314

 

Skin Corr. 1B; H314: C ≥ 25 % Skin Irrit. 2; H315: 10 % ≤ C < 25 %

Eye Irrit. 2; H319: 10 % ≤

C < 25 %

B

009-011-00-5

fluorosilicic acid … %

241-034-8

16961-83-4

Skin Corr. 1B

H314

GHS05

Dgr

H314

 

 

B

009-012-00-0

alkali fluorosilicates(Na); [1]

alkali fluorosilicates(K); [2]

alkali fluorosilicates(NH4) [3]

240-934-8 [1]

240-896-2 [2]

240-968-3 [3]

16893-85-9 [1]

16871-90-2 [2]

16919-19-0 [3]

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

H331

H311

H301

GHS06

Dgr

H331

H311

H301

 

*

A

009-013-00-6

fluorosilicates, with the exception of those specified elsewhere in this Annex

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

*

A

009-014-00-1

lead hexafluorosilicate

247-278-1

25808-74-6

Repr. 1A

Acute Tox. 4 *

Acute Tox. 4 *

STOT RE 2 *

Aquatic Acute 1

Aquatic Chronic 1

H360Df

H332

H302

H373 **

H400

H410

GHS08

GHS07

GHS09

Dgr

H360Df

H332

H302

H373 **

H410

 

 

1

009-015-00-7

sulphuryl difluoride

220-281-5

2699-79-8

Press. Gas

Acute Tox. 3 *

STOT RE 2 *

Aquatic Acute 1

H331

H373 **

H400

GHS04

GHS06

GHS08

GHS09

Dgr

H331

H373 **

H400

 

 

U

009-016-00-2

trisodium hexafluoroaluminate [1]

trisodium hexafluoroaluminate(cryolite) [2]

237-410-6 [1]

239-148-8 [2]

13775-53-6 [1]

15096-52-3 [2]

STOT RE 1

Acute Tox. 4

Aquatic Chronic 2

H372

H332

H411

GHS07

GHS08

GHS09

Dgr

H372

H332

H411

 

 

 

009-017-00-8

potassium mu-fluoro-bis(triethylaluminium)

400-040-2

12091-08-6

Flam. Sol. 1

Water-react. 1

Skin Corr. 1A

Acute Tox. 4 *

H228

H270

H314

H332

GHS02

GHS05

GHS07

Dgr

H228

H270

H314

H332

EUH014

 

T

009-018-00-3

magnesium hexafluorosilicate

241-022-2

16949-65-8

Acute Tox. 3 *

H301

GHS06

Dgr

H301

 

*

 

011-001-00-0

sodium

231-132-9

7440-23-5

Water-react. 1

Skin Corr. 1B

H260

H314

GHS02

GHS05

Dgr

H260

H314

EUH014

 

 

011-002-00-6

sodium hydroxide;

caustic soda

215-185-5

1310-73-2

Skin Corr. 1A

H314

GHS05

Dgr

H314

 

Skin Corr. 1A; H314: C ≥ 5 % Skin Corr. 1B; H314 2 % ≤ C < 5 % Skin Irrit. 2; H315: 0,5  % ≤ C < 2 % Eye Irrit.2; H319: 0,5  % ≤ C < 2 %

 

011-003-00-1

sodium peroxide

215-209-4

1313-60-6

Ox. Sol. 1

Skin Corr. 1A

H271

H314

GHS03

GHS05

Dgr

H271

H314

 

 

 

011-004-00-7

sodium azide

247-852-1

26628-22-8

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H400

H410

GHS06

GHS09

Dgr

H300

H400

H410

EUH032

 

 

011-005-00-2

sodium carbonate

207-838-8

497-19-8

Eye Irrit. 2

H319

GHS07

Wng

H319

 

 

 

011-006-00-8

sodium cyanate

213-030-6

917-61-3

Acute Tox. 4 *

Aquatic Chronic 3

H302

H412

GHS07

Wng

H302

H412

 

 

 

011-007-00-3

propoxycarbazone-sodium

181274-15-7

Aquatic Acute 1

Aquatic Chronic 1

H400

H410

GHS09

Wng

H410

 

M = 10

 

012-001-00-3

magnesium powder (pyrophoric)

231-104-6

7439-95-4

Water-react. 1

Pyr. Sol. 1

H260

H250

GHS02

Dgr

H260

H250

 

 

T

012-002-00-9

magnesium, powder or turnings

231-104-6

Flam. Sol. 1

Water-react. 2

Self-heat. 1

H228

H261

H252

GHS02

Dgr

H228

H261

H252

 

 

T

012-003-00-4

magnesium alkyls

Pyr. Liq. 1

Water-react. 1

Skin Corr. 1B

H250

H260

H314

GHS02

GHS05

Dgr

H250

H260

H314

EUH014

 

A

012-004-00-X

aluminium-magnesium-carbonate-hydroxide-perchlorate-hydrate

422-150-1

Aquatic Acute 1

Aquatic Chronic 1

H400

H410

GHS09

Wng

H410

 

 

 

013-001-00-6

aluminium powder (pyrophoric)

231-072-3

7429-90-5

Water-react. 2

Pyr. Sol. 1

H261

H250

GHS02

Dgr

H261

H250

 

 

T

013-002-00-1

aluminium powder (stabilised)

231-072-3

7429-90-5

Water-react. 2

Flam. Sol. 1

H261

H228

GHS02

Dgr

H261

H228

 

 

T

013-003-00-7

aluminium chloride, anhydrous

231-208-1

7446-70-0

Skin Corr. 1B

H314

GHS05

Dgr

H314

 

 

 

013-004-00-2

aluminium alkyls

Pyr. Liq. 1

Water-react. 1

Skin Corr. 1B

H250

H260

H314

GHS02

GHS05

Dgr

H250

H260

H314

EUH014

 

A

013-005-00-8

diethyl(ethyldimethylsilanolato) aluminium

401-160-8

55426-95-4

Water-react. 1

Pyr. Liq. 1

Skin Corr. 1A

H260

H250

H314

GHS02

GHS05

Dgr

H260

H250

H314

EUH014

 

 

013-006-00-3

(ethyl-3-oxobutanoato-O'1,O'3)(2-dimethylaminoethanolato)(1-methoxypropan-2-olato)aluminium(III), dimerised

402-370-2

Flam. Liq. 3

Eye Dam. 1

H226

H318

GHS02

GHS05

Dgr

H226

H318

 

 

 

013-007-00-9

poly(oxo(2-butoxyethyl-3-oxobutanoato-O'1,O'3)aluminium)

403-430-0

Eye Dam. 1

H318

GHS05

Dgr

H318

 

 

 

013-008-00-4

di-n-octylaluminium iodide

408-190-0

7585-14-0

Pyr. Liq. 1

Skin Corr. 1B

Aquatic Acute 1

Aquatic Chronic 1

H250

H314

H400

H410

GHS02

GHS05

GHS09

Dgr

H250

H314

H410

EUH014

 

 

013-009-00-X

sodium (n-butyl)x(ethyl)y-1,5-dihydro)aluminate x = 0,5 y =1,5

418-720-2

Flam. Sol. 1

Water-react. 1

Pyr. Sol. 1

Acute Tox. 4 *

Skin Corr. 1A

H228

H260

H250

H332

H314

GHS02

GHS05

GHS07

Dgr

H228

H260

H250

H332

H314

EUH014

 

T

013-010-00-5

hydroxy aluminium bis(2,4,8,10-tetra-tert-butyl-6-hydroxy-12H-dibenzo[d, g][1.3.2]dioxaphosphocin-6-oxide)

430-650-4

151841-65-5

Aquatic Chronic 2

H411

GHS09

H411

 

 

 

014-001-00-9

trichlorosilane

233-042-5

10025-78-2

Flam. Liq. 1

Pyr. Liq. 1

Acute Tox. 4 *

Acute Tox. 4 *

Skin Corr. 1A

H224

H250

H332

H302

H314

GHS02

GHS05

GHS07

Dgr

H224

H250

H332

H302

H314

EUH014

EUH029

*

STOT SE 3; H335: C ≥ 1 %

T

014-002-00-4

silicon tetrachloride

233-054-0

10026-04-7

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

H319

H335

H315

GHS07

Wng

H319

H335

H315

EUH014

 

 

014-003-00-X

dimethyldichlorosilane

200-901-0

75-78-5

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

H225

H319

H335

H315

GHS02

GHS07

Dgr

H225

H319

H335

H315

 

 

 

014-004-00-5

trichloro(methyl)silane; methyltrichlorosilane

200-902-6

75-79-6

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

H225

H319

H335

H315

GHS02

GHS07

Dgr

H225

H319

H335

H315

EUH014

Skin Irrit.2; H315: C ≥ 1 % Eye Irrit. 2; H319: C ≥ 1 % STOT SE 3; H335: C ≥ 1 %

 

014-005-00-0

tetraethyl silicate;

ethyl silicate

201-083-8

78-10-4

Flam. Liq. 3

Acute Tox. 4 *

Eye Irrit. 2

STOT SE 3

H226

H332

H319

H335

GHS02

GHS07

Wng

H226

H332

H319

H335

 

 

 

014-006-00-6

bis(4-fluorophenyl)-methyl-(1,2,4-triazol-4-ylmethyl)silane hydrochloride

401-380-4

Eye Irrit. 2

Aquatic Chronic 2

H319

H411

GHS07

GHS09

Wng

H319

H411

 

 

 

014-007-00-1

triethoxyisobutylsilane

402-810-3

17980-47-1

Skin Irrit. 2

H315

GHS07

Wng

H315

 

 

 

014-008-00-7

(chloromethyl)bis(4-fluorophenyl)methylsilane

401-200-4

85491-26-5

Aquatic Chronic 2

H411

GHS09

H411

 

 

 

014-009-00-2

isobutylisopropyldimethoxysilane

402-580-4

111439-76-0

Flam. Liq. 3

Acute Tox. 4 *

Skin Irrit. 2

H226

H332

H315

GHS02

GHS07

Wng

H226

H332

H315

 

 

 

014-010-00-8

disodium metasilicate

229-912-9

6834-92-0

Skin Corr. 1B

STOT SE 3

H314

H335

GHS05

GHS07

Dgr

H314

H335

 

 

 

014-011-00-3

cyclohexyldimethoxymethylsilane

402-140-1

17865-32-6

Skin Irrit. 2

Aquatic Chronic 2

H315

H411

GHS07

GHS09

Wng

H315

H411

 

 

 

014-012-00-9

bis(3-(trimethoxysilyl)propyl)amine

403-480-3

Eye Dam. 1

Aquatic Chronic 2

H318

H411

GHS05

GHS09

Dgr

H318

H411

 

 

 

014-013-00-4

α-hydroxypoly(methyl-(3-(2,2,6,6-tetramethylpiperidin-4-yloxy)propyl)siloxane)

404-920-7

Acute Tox. 4 *

Acute Tox. 4 *

Skin Corr. 1B

Aquatic Chronic 2

H312

H302

H314

H411

GHS05

GHS07

GHS09

Dgr

H312

H302

H314

H411

 

 

 

014-014-00-X

etacelasil (ISO);

6-(2-chloroethyl)-6-(2-methoxyethoxy)-2,5,7,10-tetraoxa-6-silaundecane

253-704-7

37894-46-5

Repr. 1B

Acute Tox. 4 *

STOT RE 2 *

H360D *** H302

H373 **

GHS08

GHS07

Dgr

H360D *** H302

H373 **

 

 

 

014-015-00-5

α-trimethylsilanyl-ω-trimethylsiloxypoly[oxy(methyl-3-(2-(2-methoxypropoxy)propoxy)propylsilanediyl]-co-oxy(dimethylsilane))

406-420-4

69430-40-6

Aquatic Chronic 4

H413

H413

 

 

 

014-016-00-0

reaction mass of: 1,3-dihex-5-en-1-yl-1,1,3,3-tetramethyldisiloxane;

1,3-dihex-n-en-1-yl-1,1,3,3-tetramethyldisiloxane

406-490-6

Aquatic Chronic 2

H411

GHS09

H411

 

 

 

014-017-00-6

flusilazole (ISO);

bis(4-fluorophenyl)(methyl)(1H-1,2,4-triazol-1-ylmethyl)silane

85509-19-9

Carc. 2

Repr. 1B

Acute Tox. 4 *

Aquatic Chronic 2

H351

H360D *** H302

H411

GHS08

GHS07

GHS09

Dgr

H351

H360D *** H302

H411

 

 

 

014-018-00-1

octamethylcyclotetrasiloxane

209-136-7

556-67-2

Repr. 2

Aquatic Chronic 4

H361f *** H413

GHS08

Wng

H361f *** H413

 

 

 

014-019-00-7

reaction mass of: 4-[[bis-(4-fluorophenyl)methylsilyl]methyl]-4H-1,2,4-triazole;

1-[[bis-(4-fluorophenyl)methylsilyl]methyl]-1H-1,2,4-triazole

403-250-2

Carc. 2

Repr. 1B

Acute Tox. 4 *

Aquatic Chronic 2

H351

H360D *** H302

H411

GHS08

GHS07

GHS09

Dgr

H351

H360D *** H302

H411

 

 

 

014-020-00-2

bis(1,1-dimethyl-2-propynyloxy)dimethylsilane

414-960-7

53863-99-3

Acute Tox. 4 *

H332

GHS07

Wng

H332

 

 

 

014-021-00-8

tris(isopropenyloxy)phenyl silane

411-340-8

52301-18-5

Aquatic Acute 1

Aquatic Chronic 1

H400

H410

GHS09

Wng

H400

H410

 

 

 

014-022-00-3

reaction product of: (2-hydroxy-4-(3-propenoxy)benzophenone and triethoxysilane) with (hydrolysis product of silica and methyltrimethoxysilane)

401-530-9

Flam. Sol. 1

STOT SE 1

Acute Tox. 4 *

Acute Tox. 4 *

Acute Tox. 4 *

H228

H370 **

H332

H312

H302

GHS02

GHS08

GHS07

Dgr

H228

H370 **

H332

H312

H302

 

 

T

014-023-00-9

α, ω-dihydroxypoly(hex-5-en-1-ylmethylsiloxane)hoxysilane with (hydrolysis product of silica and methyltrimethoxysilane)iazole

408-160-7

125613-45-8

Aquatic Chronic 2

H411

GHS09

H411

 

 

 

014-024-00-4

1-((3-(3-chloro-4-fluorophenyl)propyl)dimethylsilanyl)-4-ethoxybenzene

412-620-2

121626-74-2

Aquatic Chronic 2

H411

GHS09

H411

 

 

 

014-025-00-X

4-[3-(diethoxymethylsilylpropoxy)-2,2,6,6-tetramethyl]piperidine

411-400-3

102089-33-8

Acute Tox. 4 *

STOT RE 2 *

Skin Irrit. 2

Eye Dam. 1

Aquatic Chronic 3

H302

H373 **

H315

H318

H412

GHS08

GHS05

GHS07

Dgr

H302

H373 **

H315

H318

H412

 

 

 

014-026-00-5

dichloro-(3-(3-chloro-4-fluorophenyl)propyl)methylsilane

407-180-3

770722-36-6

Skin Corr. 1A

H314

GHS05

Dgr

H314

 

 

 

014-027-00-0

chloro(3-(3-chloro-4-fluorophenyl)propyl)dimethylsilane

410-270-5

770722-46-8

Skin Corr. 1A

H314

GHS05

Dgr

H314

 

 

 

014-028-00-6

α-[3-(1-oxoprop-2-enyl)l-1-oxypropyl]dimethoxysilyloxy-ω-[3(1-oxoprop-2-enyl)-1-oxypropyl]dimethoxysilyl poly(dimethylsiloxane)

415-290-8

193159-06-7

Skin Sens. 1

H317

GHS07

Wng

H317

 

 

 

014-029-00-1

O, O'-(ethenylmethylsilylene)di[(4-methylpentan-2-one)oxime]

421-870-1

156145-66-3

Repr. 2

Acute Tox. 4 *

STOT RE 2 *

H361f *** H302

H373 **

GHS08

GHS07

Wng

H361f *** H302

H373 **

 

 

 

014-030-00-7

[(dimethylsilylene)bis((1,2,3,3a,7a-η)-1H-inden-1-ylidene)dimethyl]hafnium

422-060-0

137390-08-0

Acute Tox. 2 *

H300

GHS06

Dgr

H300

 

 

 

014-031-00-2

bis(1-methylethyl)-dimethoxysilane

421-540-7

18230-61-0

Flam. Liq. 3

Skin Irrit. 2

Skin Sens. 1

Aquatic Chronic 3

H226

H315

H317

H412

GHS02

GHS07

Wng

H226

H315

H317

H412

 

 

 

014-032-00-8

dicyclopentyldimethoxysilane

404-370-8

126990-35-0

Skin Irrit. 2

Eye Dam. 1

Aquatic Acute 1

Aquatic Chronic 1

H315

H318

H400

H410

GHS05

GHS09

Dgr

H315

H318

H410

 

 

 

014-033-00-3

2-methyl-3-(trimethoxysilyl)propyl-2-propenoate hydrolysis product with silica

419-030-4

125804-20-8

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3

H225

H319

H336

GHS02

GHS07

Dgr

H225

H319

H336

 

 

 

014-034-00-9

3-hexylheptamethyltrisiloxane

428-700-5

1873-90-1

Acute Tox. 4 *

Aquatic Chronic 4

H332

H413

GHS07

Wng

H332

H413

 

 

 

014-035-00-4

2-(3,4-epoxycyclohexyl)ethyltriethoxy silane

425-050-4

10217-34-2

Skin Sens. 1

Aquatic Chronic 3

H317

H412

GHS07

Wng

H317

H412

 

 

 

014-036-00-X

(4-ethoxyphenyl)(3-(4-fluoro-3-phenoxyphenyl)propyl)dimethylsilane

405-020-7

105024-66-6

Repr. 1B

Aquatic Acute 1

Aquatic Chronic 1

H360F*** H400

H410

GHS08

GHS09

Dgr

H360F*** H410

 

M=1000

 

014-037-00-5

2-butanone-O, O',O''-(phenylsilylidyne)trioxime

433-360-6

34036-80-1

STOT RE 2 *

Skin Sens. 1

Aquatic Chronic 3

H373**

H317

H412

GHS08

GHS07

Wng

H373**

H317

H412

 

 

 

014-038-00-0

S-(3-(triethoxysilyl)propyl)octanethioate

436-690-9

220727-26-4

Skin Sens. 1

H317

GHS07

Wng

H317

 

 

 

014-039-00-6

(2,3-dimethylbut-2-yl)-trimethoxysilane

439-360-2

142877-45-0

Skin Irrit. 2

Eye Dam. 1

Aquatic Chronic 3

H315

H318

H412

GHS05

Dgr

H315

H318

H412

 

 

 

014-041-00-7

N, N-bis(trimethylsilyl)aminopropylmethyldiethoxysilane

445-890-5

201290-01-9

Acute Tox. 4 *

Skin Sens. 1

H302

H317

GHS07

Wng

H302

H317

 

 

 

014-042-00-2

reaction mass of: O,O',O'',O'''-silanetetrayl tetrakis(4-methyl-2-pentanone oxime) (3 stereoisomers)

423-010-0

Eye Dam. 1

H318

GHS05

Dgr

H318

 

 

 

014-043-00-8

reaction product of amorphous silica (50-85 %), butyl (1-methylpropyl) magnesium (3-15 %), tetraethyl orthosilicate (5-15 %) and titanium tetrachloride (5-20 %)

432-200-2

STOT SE 3

Skin Irrit. 2

Eye Dam. 1

Aquatic Chronic 3

H335

H315

H318

H412

GHS05

GHS07

Dgr

H335

H315

H318

H412

 

 

 

014-044-00-3

3-[(4'-acetoxy-3'-methoxyphenyl) propyl]trimethoxysilane

433-050-0

Aquatic Chronic 2

H411

GHS09

H411

 

 

 

014-045-00-9

magnesium sodium fluoride silicate

442-650-1

STOT RE 2 *

H373**

GHS08

Wng

H373**

 

 

 

015-001-00-1

white phosphorus

231-768-7

12185-10-3

Pyr. Sol. 1

Acute Tox. 2 *

Acute Tox. 2 *

Skin Corr. 1A

Aquatic Acute 1

H250

H330

H300

H314

H400

GHS02

GHS06

GHS05

GHS09

Dgr

H250

H330

H300

H314

H400

 

 

 

015-002-00-7

red phosphorus

231-768-7

7723-14-0

Flam. Sol. 1

Aquatic Chronic 3

H228

H412

GHS02

Dgr

H228

H412

 

 

 

015-004-00-8

aluminium phosphide

244-088-0

20859-73-8

Water-react. 1

Acute Tox. 2

Acute Tox. 3

Acute Tox. 1

Aquatic Acute 1

H260

H300

H311

H330

H400

GHS02

GHS06

GHS09

Dgr

H260

H300

H311

H330

H400

EUH029

EUH032

M = 100

 

015-005-00-3

magnesium phosphide;

trimagnesium diphosphide

235-023-7

12057-74-8

Water-react. 1

Acute Tox. 2

Acute Tox. 3

Acute Tox. 1

Aquatic Acute 1

H260

H300

H311

H330

H400

GHS02

GHS06

GHS09

Dgr

H260

H300

H311

H330

H400

EUH029

EUH032

M = 100

 

015-006-00-9

trizinc diphosphide;

zinc phosphide

215-244-5

1314-84-7

Water-react. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H260

H300

H400

H410

GHS02

GHS06

GHS09

Dgr

H260

H300

H410

EUH029

EUH032

M=100

T

015-007-00-4

phosphorus trichloride

231-749-3

7719-12-2

Acute Tox. 2 *

Acute Tox. 2 *

STOT RE 2 *

Skin Corr. 1A

H330

H300

H373 **

H314

GHS06

GHS08

GHS05

Dgr

H330

H300

H373 **

H314

EUH014

EUH029

 

 

015-008-00-X

phosphorus pentachloride

233-060-3

10026-13-8

Acute Tox. 2 *

Acute Tox. 4 *

STOT RE 2 *

Skin Corr. 1B

H330

H302

H373 **

H314

GHS06

GHS08

GHS05

Dgr

H330

H302

H373 **

H314

EUH014

EUH029

 

 

015-009-00-5

phosphoryl trichloride

233-046-7

10025-87-3

Acute Tox. 2 *

STOT RE 1

Acute Tox. 4 *

Skin Corr. 1A

H330

H372 **

H302

H314

GHS06

GHS08

GHS05

Dgr

H330

H372 **

H302

H314

EUH014

EUH029

 

 

015-010-00-0

phosphorus pentoxide

215-236-1

1314-56-3

Skin Corr. 1A

H314

GHS05

Dgr

H314

 

 

 

015-011-00-6

phosphoric acid . %, orthophosphoric acid . %

231-633-2

7664-38-2

Skin Corr. 1B

H314

GHS05

Dgr

H314

 

Skin Corr. 1B; H314: C ≥ 25 % Skin Irrit. 2; H315: 10 % ≤ C < 25 % Eye Irrit. 2; H319: 10 % ≤ C < 25 %

B

015-012-00-1

tetraphosphorus trisulphide;

phosphorus sesquisulphid

215-245-0

1314-85-8

Flam. Sol. 2

Water-react. 1

Acute Tox. 4 *

Aquatic Acute 1

H228

H260

H302

H400

GHS02

GHS07

GHS09

Dgr

H228

H260

H302

H400

 

 

T

015-013-00-7

triethyl phosphate

201-114-5

78-40-0

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

015-014-00-2

tributyl phosphate

204-800-2

126-73-8

Carc. 2

Acute Tox. 4 *

Skin Irrit. 2

H351

H302

H315

GHS08

GHS07

Wng

H351

H302

H315

 

 

 

015-015-00-8

tricresyl phosphate (o-o-o-, o-o-m-, o-o-p-, o-m-m-, o-m-p-, o-p-p-); tritolyl phosphate (o-o-o-, o-o-m-, o-o-p-, o-m-m-, o-m-p-, o-p-p-);

201-103-5

78-30-8

STOT SE 1

Aquatic Chronic 2

H370 **

H411

GHS08

GHS09

Dgr

H370 **

H411

 

STOT SE 1; H370: C ≥ 1 % STOT SE 2; H371: 0,2  % ≤ C < 1 %

C

015-016-00-3

tricresyl phosphate (m-m-m-, m-m-p-, m-p-p-, p-p-p-);

tritolyl phosphate (m-m-m-, m-m-p-, m-p-p-, p-p-p-);

201-105-6

78-32-0

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Chronic 2

H312

H302

H411

GHS07

GHS09

Wng

H312

H302

H411

 

*

C

015-019-00-X

dichlorvos (ISO);

2,2-dichlorovinyl dimethyl phosphate

200-547-7

62-73-7

Acute Tox. 2 *

Acute Tox. 3 *

Acute Tox. 3 *

Skin Sens. 1

Aquatic Acute 1

H330

H311

H301

H317

H400

GHS06

GHS09

Dgr

H330

H311

H301

H317

H400

 

M=1000

 

015-020-00-5

mevinphos (ISO);

2-methoxycarbonyl-1-methylvinyl dimethyl phosphate

232-095-1

7786-34-7

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

M = 10000

 

015-021-00-0

trichlorfon (ISO);

dimethyl 2,2,2-trichloro-1-hydroxyethylphosphonate

200-149-3

52-68-6

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H317

H400

H410

GHS07

GHS09

Wng

H302

H317

H400

H410

 

M = 1000

 

015-022-00-6

phosphamidon (ISO);

2-chloro-2-diethylcarbamoyl-1-methylvinyl dimethyl phosphate

236-116-5

13171-21-6

Muta. 2

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H341

H300

H311

H400

H410

GHS06

GHS08

GHS09

Dgr

H341

H300

H311

H410

 

 

 

015-023-00-1

pyrazoxon;

diethyl 3-methylpyrazol-5-yl phosphate

108-34-9

Acute Tox. 2 *

Acute Tox. 1

Acute Tox. 2 *

H330

H310

H300

GHS06

Dgr

H330

H310

H300

 

 

 

015-024-00-7

triamiphos (ISO);

5-amino-3-phenyl-1,2,4-triazol-1-yl-N, N,N',N'-tetramethylphosphonic diamide

1031-47-6

Acute Tox. 1

Acute Tox. 2 *

H310

H300

GHS06

Dgr

H310

H300

 

 

 

015-025-00-2

TEPP (ISO);

tetraethyl pyrophosphate

203-495-3

107-49-3

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

H310

H300

H400

GHS06

GHS09

Dgr

H310

H300

H400

 

 

 

015-026-00-8

schradan (ISO); octamethylpyrophosphoramide

205-801-0

152-16-9

Acute Tox. 1

Acute Tox. 2 *

H310

H300

GHS06

Dgr

H310

H300

 

 

 

015-027-00-3

sulfotep (ISO);

O, O,O, O-tetraethyl dithiopyrophosphate

222-995-2

3689-24-5

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

M = 1000

 

015-028-00-9

demeton-O (ISO);

O,O-diethyl-O-2-ethylthioethyl phosphorothioate

206-053-8

298-03-3

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

H310

H300

H400

GHS06

GHS09

Dgr

H310

H300

H400

 

 

 

015-029-00-4

demeton-S (ISO);

diethyl-S-2-ethylthioethyl phosphorothioate

204-801-8

126-75-0

Acute Tox. 1

Acute Tox. 2 *

H310

H300

GHS06

Dgr

H310

H300

 

 

 

015-030-00-X

demeton-O-methyl (ISO);

O-2-ethylthioethyl O,O-dimethyl phosphorothioate

212-758-1

867-27-6

Acute Tox. 3 *

H301

GHS06

Dgr

H301

 

 

 

015-031-00-5

demeton-S-methyl (ISO);

S-2-ethylthioethyl dimethyl phosphorothioate

213-052-6

919-86-8

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Chronic 2

H311

H301

H411

GHS06

GHS09

Dgr

H311

H301

H411

 

 

 

015-032-00-0

prothoate (ISO);

O,O-diethyl isopropylcarbamoylmethyl phosphorodithioate

218-893-2

2275-18-5

Acute Tox. 1

Acute Tox. 2 *

Aquatic Chronic 3

H310

H300

H412

GHS06

Dgr

H310

H300

H412

 

 

 

015-033-00-6

phorate (ISO);

O,O-diethyl ethylthiomethyl phosphorodithioate

206-052-2

298-02-2

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

M = 1000

 

015-034-00-1

parathion (ISO);

O,O-diethyl O-4-nitrophenyl phosphorothioate

200-271-7

56-38-2

Acute Tox. 2 *

Acute Tox. 2 *

Acute Tox. 3 *

STOT RE 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H300

H311

H372 **

H400

H410

GHS06

GHS08

GHS09

Dgr

H330

H300

H311

H372 **

H410

 

M = 100

 

015-035-00-7

parathion — methyl (ISO);

O,O-dimethyl O-4-nitrophenyl phosphorothioate

206-050-1

298-00-0

Flam. Liq. 3

Acute Tox. 2 *

Acute Tox. 2 *

Acute Tox. 3 *

STOT RE 2 *

Aquatic Acute 1

Aquatic Chronic 1

H226

H330

H300

H311

H373 **

H400

H410

GHS02

GHS06

GHS08

GHS09

Dgr

H226

H330

H300

H311

H373 **

H410

 

M = 100

 

015-036-00-2

O-ethyl O-4-nitrophenyl phenylphosphonothioate;

EPN

218-276-8

2104-64-5

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

 

 

015-037-00-8

phenkapton (ISO);

S-(2,5-dichlorophenylthiomethyl) O, O-diethyl phosphorodithioate

218-892-7

2275-14-1

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H331

H311

H301

H400

H410

GHS06

GHS09

Dgr

H331

H311

H301

H410

 

 

 

015-038-00-3

coumaphos (ISO);

O-3-chloro-4-methylcoumarin-7-yl O,O-diethyl phosphorothioate

200-285-3

56-72-4

Acute Tox. 2 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H312

H400

H410

GHS06

GHS09

Dgr

H300

H312

H410

 

 

 

015-039-00-9

azinphos-methyl (ISO);

O,O-dimethyl-4-oxobenzotriazin-3-ylmethyl phosphorodithioate

201-676-1

86-50-0

Acute Tox. 2 *

Acute Tox. 2 *

Acute Tox. 3 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H300

H311

H317

H400

H410

GHS06

GHS09

Dgr

H330

H300

H311

H317

H410

 

 

 

015-040-00-4

diazinon (ISO);

O,O-diethyl O-2-isopropyl-6-methylpyrimidin-4-yl phosphorothioate

206-373-8

333-41-5

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H400

H410

 

 

 

015-041-00-X

malathion (ISO);

1,2-bis(ethoxycarbonyl)ethyl O, O-dimethyl phosphorodithioate;

[containing ≤ 0,03 % isomalathion]

204-497-7

121-75-5

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H317

H400

H410

GHS07

GHS09

Wng

H302

H317

H410

 

M=1000

 

015-042-00-5

chlorthion O-(3-chloro-4-nitrophenyl) O, O-dimethyl phosphorothioate

207-902-5

500-28-7

Acute Tox. 4 *

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H332

H312

H302

H400

H410

GHS07

GHS09

Wng

H332

H312

H302

H410

 

M = 100

 

015-043-00-0

phosnichlor (ISO);

O-4-chloro-3-nitrophenyl O, O-dimethyl phosphorothioate

5826-76-6

Acute Tox. 4 *

Acute Tox. 4 *

Acute Tox. 4 *

H332

H312

H302

GHS07

Wng

H332

H312

H302

 

 

 

015-044-00-6

carbophenothion (ISO);

4-chlorophenylthiomethyl O, O-diethyl phosphorodithioate

212-324-1

786-19-6

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H311

H301

H400

H410

GHS06

GHS09

Dgr

H311

H301

H410

 

 

 

015-045-00-1

mecarbam (ISO);

N-ethoxycarbonyl-N-methylcarbamoylmethyl O, O-diethyl phosphorodithioate

219-993-9

2595-54-2

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H311

H301

H400

H410

GHS06

GHS09

Dgr

H311

H301

H400

H410

 

 

 

015-046-00-7

oxydemeton-methyl;

S-2-(ethylsulphinyl)ethyl O,O-dimethyl phosphorothioate

206-110-7

301-12-2

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

H311

H301

H400

GHS06

GHS09

Dgr

H311

H301

H400

 

 

 

015-047-00-2

ethion (ISO);

O, O,O',O'-tetraethyl S, S'-methylenedi (phosphorodithioate);

diethion

209-242-3

563-12-2

Acute Tox. 3 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H301

H312

H400

H410

GHS06

GHS09

Dgr

H301

H312

H410

 

M = 10000

 

015-048-00-8

fenthion (ISO);

O, O-dimethyl-O-(4-methylthion-m-tolyl) phosphorothioate

200-231-9

55-38-9

Muta. 2

Acute Tox. 3 *

Acute Tox. 4 *

Acute Tox. 4 *

STOT RE 1

Aquatic Acute 1

Aquatic Chronic 1

H341

H331

H312

H302

H372**

H400

H410

GHS06

GHS08

GHS09

Dgr

H341

H331

H312

H302

H372** H410

 

M=100

 

015-049-00-3

endothion (ISO);

S-5-methoxy-4-oxopyran-2-ylmethyl dimethyl phosphorothioate

220-472-3

2778-04-3

Acute Tox. 3 *

Acute Tox. 3 *

H311

H301

GHS06

Dgr

H311

H301

 

 

 

015-050-00-9

thiometon (ISO);

S-2-ethylthioethyl O,O-dimethyl phosphorodithioate

211-362-6

640-15-3

Acute Tox. 3 *

Acute Tox. 4 *

H301

H312

GHS06

Dgr

H301

H312

 

 

 

015-051-00-4

dimethoate (ISO);

O, O-dimethyl methylcarbamoylmethyl phosphorodithioate

200-480-3

60-51-5

Acute Tox. 4 *

Acute Tox. 4 *

H312

H302

GHS07

Wng

H312

H302

 

 

 

015-052-00-X

fenchlorphos (ISO);

O, O-dimethyl O-2,4,5-trichlorophenyl phosphorothioate

206-082-6

299-84-3

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H312

H302

H400

H410

GHS07

GHS09

Wng

H312

H302

H410

 

 

 

015-053-00-5

menazon (ISO);

S-[(4,6-diamino-1,3,5-triazin-2-yl)methyl] O, O-dimethyl phosphorodithioate

201-123-4

78-57-9

Acute Tox. 4 *

Aquatic Chronic 3

H302

H412

GHS07

Wng

H302

H412

 

 

 

015-054-00-0

fenitrothion (ISO);

O, O-dimethyl O-4-nitro-m-tolyl phosphorothioate

204-524-2

122-14-5

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

015-055-00-6

naled (ISO);

1,2-dibromo-2,2-dichloroethyl dimethyl phosphate

206-098-3

300-76-5

Acute Tox. 4 *

Acute Tox. 4 *

Eye Irrit. 2

Skin Irrit. 2

Aquatic Acute 1

H312

H302

H319

H315

H400

GHS07

GHS09

Wng

H312

H302

H319

H315

H400

 

M = 1000

 

015-056-00-1

azinphos-ethyl (ISO);

O,O-diethyl 4-oxobenzotriazin-3-ylmethyl phosphorodithioate

220-147-6

2642-71-9

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H311

H400

H410

GHS06

GHS09

Dgr

H300

H311

H410

 

M=100

 

015-057-00-7

formothion (ISO);

N-formyl-N-methylcarbamoylmethyl O, O-dimethyl phosphorodithioate

219-818-6

2540-82-1

Acute Tox. 4 *

Acute Tox. 4 *

H312

H302

GHS07

Wng

H312

H302

 

 

 

015-058-00-2

morphothion (ISO);

O, O-dimethyl-S-(morpholinocarbonylmethyl) phosphorodithioate

205-628-0

144-41-2

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H331

H311

H301

H400

H410

GHS06

GHS09

Dgr

H331

H311

H301

H410

 

 

 

015-059-00-8

vamidothion (ISO);

O,O-dimethyl S-2-(1-methylcarbamoylethylthio) ethyl phosphorothioate

218-894-8

2275-23-2

Acute Tox. 3 *

Acute Tox. 4 *

Aquatic Acute 1

H301

H312

H400

GHS06

GHS09

Dgr

H301

H312

H400

 

 

 

015-060-00-3

disulfoton (ISO);

O,O-diethyl 2-ethylthioethyl phosphorodithioate

206-054-3

298-04-4

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

 

 

015-061-00-9

dimefox (ISO); tetramethylphosphorodiamidic fluoride

204-076-8

115-26-4

Acute Tox. 1

Acute Tox. 2 *

H310

H300

GHS06

Dgr

H310

H300

 

 

 

015-062-00-4

mipafox (ISO);

N,N'-di-isopropylphosphorodiamidic fluoride

206-742-3

371-86-8

STOT SE 1

H370 **

GHS08

Dgr

H370 **

 

 

 

015-063-00-X

dioxathion (ISO);

1,4-dioxan-2,3-diyl-O,O,O',O'-tetraethyl di(phosphorodithioate)

201-107-7

78-34-2

Acute Tox. 2 *

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H330

H300

H311

H400

H410

GHS06

GHS09

Dgr

H330

H300

H311

H410

 

M = 1000

 

015-064-00-5

bromophos-ethyl (ISO);

O-4-bromo-2,5-dichlorophenyl

O,O-diethyl phosphorothioate

225-399-0

4824-78-6

Acute Tox. 3 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H301

H312

H400

H410

GHS06

GHS09

Dgr

H301

H312

H410

 

 

 

015-065-00-0

S-[2-(ethylsulphinyl)ethyl] O,O-dimethyl phosphorodithioate

2703-37-9

Acute Tox. 2 *

Acute Tox. 1

Acute Tox. 2 *

Aquatic Chronic 2

H330

H310

H300

H411

GHS06

GHS09

Dgr

H330

H310

H300

H411

 

 

 

015-066-00-6

omethoate (ISO);

O, O-dimethyl S-methylcarbamoylmethyl phosphorothioate

214-197-8

1113-02-6

Acute Tox. 3 *

Acute Tox. 4 *

Aquatic Acute 1

H301

H312

H400

GHS06

GHS09

Dgr

H301

H312

H400

 

 

 

015-067-00-1

phosalone (ISO);

S-(6-chloro-2-oxobenzoxazolin-3-ylmethyl) O, O-diethyl phosphorodithioate

218-996-2

2310-17-0

Acute Tox. 3 *

Acute Tox. 4 *

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H301

H332

H312

H317

H400

H410

GHS06

GHS09

Dgr

H301

H332

H312

H317

H410

 

M=1000

 

015-068-00-7

dichlofenthion (ISO);

O—2,4-dichlorophenyl O,O-diethyl phosphorothioate

202-564-5

97-17-6

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H400

H410

 

 

 

015-069-00-2

methidathion (ISO);

2,3-dihydro-5-methoxy-2-oxo-1,3,4-thiadiazol-3-ylmethyl-O,O-dimethylphosphorodithioate

213-449-4

950-37-8

Acute Tox. 2 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H312

H400

H410

GHS06

GHS09

Dgr

H300

H312

H410

 

 

 

015-070-00-8

cyanthoate (ISO);

S-(N-(1-cyano-1-methylethyl)carbamoylmethyl) O,O-diethyl phosphorothioate

223-099-4

3734-95-0

Acute Tox. 2 *

Acute Tox. 3 *

H300

H311

GHS06

Dgr

H300

H311

 

 

 

015-071-00-3

chlorfenvinphos (ISO);

2-chloro-1-(2,4 dichlorophenyl)vinyl diethyl phosphate

207-432-0

470-90-6

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H311

H400

H410

GHS06

GHS09

Dgr

H300

H311

H410

 

 

 

015-072-00-9

monocrotophos (ISO);

dimethyl-1-methyl-2-(methylcarbamoyl)vinyl phosphate

230-042-7

6923-22-4

Muta. 2

Acute Tox. 2 *

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H341

H330

H300

H311

H400

H410

GHS06

GHS08

GHS09

Dgr

H341

H330

H300

H311

H410

 

 

 

015-073-00-4

dicrotophos (ISO);

(Z)-2-dimethylcarbamoyl-1-methylvinyl dimethyl phosphate

205-494-3

141-66-2

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H311

H400

H410

GHS06

GHS09

Dgr

H300

H311

H410

 

 

 

015-074-00-X

crufomate (ISO);

4-tert-butyl-2-chlorophenyl methyl methylphosphoramidate

206-083-1

299-86-5

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H312

H302

H400

H410

GHS07

GHS09

Wng

H312

H302

H410

 

 

 

015-075-00-5

S-[2-(isopropylsulphinyl)ethyl] O,O-dimethyl phosphorothioate

2635-50-9

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

H331

H311

H301

GHS06

Dgr

H331

H311

H301

 

 

 

015-076-00-0

potasan;

O, O-diethyl O-(4-methylcoumarin-7-yl) phosphorothioate

299-45-6

Acute Tox. 2 *

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H330

H310

H300

H400

H410

GHS06

GHS09

Dgr

H330

H310

H300

H410

 

M = 1000

 

015-077-00-6

2,2-dichlorovinyl 2-ethylsulphinylethyl methyl phosphate

7076-53-1

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 3 *

H331

H311

H301

GHS06

Dgr

H331

H311

H301

 

 

 

015-078-00-1

demeton-S-methylsulphon(ISO);

S-2-ethylsulphonylethyl dimethyl phosphorothioate

241-109-5

17040-19-6

Acute Tox. 3 *

Acute Tox. 4 *

Aquatic Chronic 2

H301

H312

H411

GHS06

GHS09

Dgr

H301

H312

H411

 

 

 

015-079-00-7

acephate (ISO);

O, S-dimethyl acetylphosphoramidothioate

250-241-2

30560-19-1

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

015-080-00-2

amidithion (ISO);

2-methoxyethylcarbamoylmethyl O,O-dimethyl phosphorodithioate

919-76-6

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

015-081-00-8

O,O,O',O'-tetrapropyl dithiopyrophosphate

221-817-0

3244-90-4

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H312

H302

H400

H410

GHS07

GHS09

Wng

H312

H302

H410

 

 

 

015-082-00-3

azothoate (ISO);

O-4-(4-chlorophenylazo)phenyl O,O-dimethyl phosphorothioate

227-419-3

5834-96-8

Acute Tox. 4 *

Acute Tox. 4 *

H332

H302

GHS07

Wng

H332

H302

 

 

 

015-083-00-9

bensulide (ISO);

O, O-diisopropyl 2-phenylsulphonylaminoethyl phosphorodithioate

212-010-4

741-58-2

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

015-084-00-4

chlorpyrifos (ISO);

O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate

220-864-4

2921-88-2

Acute Tox. 3 * Aquatic Acute 1

Aquatic Chronic 1

H301

H400

H410

GHS06

GHS09

Dgr

H301

H400

H410

 

M = 10000

 

015-085-00-X

chlorphonium chloride (ISO);

tributyl (2,4-dichlorobenzyl) phosphonium chloride

204-105-4

115-78-6

Acute Tox. 3 *

Acute Tox. 4 *

Eye Irrit. 2

Skin Irrit. 2

H301

H312

H319

H315

GHS06

Dgr

H301

H312

H319

H315

 

 

 

015-086-00-5

coumithoate (ISO);

O,O-diethyl O-7,8,9,10-tetrahydro-6-oxo-benzo(c)chromen-3-yl phosphorothioate

572-48-5

Acute Tox. 3 *

H301

GHS06

Dgr

H301

 

 

 

015-087-00-0

cyanophos (ISO);

O-4-cyanophenyl O,O-dimethyl phosphorothioate

220-130-3

2636-26-2

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H312

H302

H400

H410

GHS07

GHS09

Wng

H312

H302

H410

 

 

 

015-088-00-6

dialifos (ISO);

2-chloro-1-phthalimidoethyl O,O-diethyl phosphorodithioate

233-689-3

10311-84-9

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H311

H400

H410

GHS06

GHS09

Dgr

H300

H311

H400

H410

 

 

 

015-089-00-1

ethoate-methyl (ISO); ethylcarbamoylmethyl O,O-dimethyl phosphorodithioate

204-121-1

116-01-8

Acute Tox. 4 *

Acute Tox. 4 *

H312

H302

GHS07

Wng

H312

H302

 

 

 

015-090-00-7

fensulfothion (ISO);

O,O-diethyl O-4-methylsulfinylphenyl phosphorothioate

204-114-3

115-90-2

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

 

 

015-091-00-2

fonofos (ISO);

O-ethyl phenyl ethylphosphonodithioate

213-408-0

944-22-9

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

 

 

015-092-00-8

phosacetim (ISO);

O,O-bis(4-chlorophenyl) N-acetimidoylphosphoramidothioate

223-874-7

4104-14-7

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

 

 

015-093-00-3

leptophos (ISO);

O-4-bromo-2,5-dichlorophenyl O-methyl phenylphosphorothioate

244-472-8

21609-90-5

Acute Tox. 3 *

STOT SE 1

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H301

H370 **

H312

H400

H410

GHS06

GHS08

GHS09

Dgr

H301

H370 **

H312

H410

 

 

 

015-094-00-9

mephosfolan (ISO);

diethyl 4-methyl-1,3-dithiolan-2-ylidenephosphoramidate

213-447-3

950-10-7

Acute Tox. 1

Acute Tox. 2 *

Aquatic Chronic 2

H310

H300

H411

GHS06

GHS09

Dgr

H310

H300

H411

 

 

 

015-095-00-4

methamidophos (ISO);

O,S-dimethyl phosphoramidothioate

233-606-0

10265-92-6

Acute Tox. 2 *

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

H330

H300

H311

H400

GHS06

GHS09

Dgr

H330

H300

H311

H400

 

 

 

015-096-00-X

oxydisulfoton (ISO);

O, O-diethyl S-2-ethylsulphinylethyl phosphorodithioate

219-679-1

2497-07-6

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H311

H400

H410

GHS06

GHS09

Dgr

H300

H311

H410

 

M = 10

 

015-097-00-5

phenthoate (ISO);

ethyl 2-(dimethoxyphosphinothioylthio)-2-phenylacetate

219-997-0

2597-03-7

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H312

H302

H400

H410

GHS07

GHS09

Wng

H312

H302

H410

 

M = 100

 

015-098-00-0

trichloronate (ISO);

O-ethyl O-2,4,5-trichlorophenyl ethylphosphonothioate

206-326-1

327-98-0

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H311

H400

H410

GHS06

GHS09

Dgr

H300

H311

H410

 

 

 

015-099-00-6

pirimiphos-ethyl (ISO);

O, O-diethyl O-2-diethylamino-6-methylpyrimidin-4-yl phosphorothioate

245-704-0

23505-41-1

Acute Tox. 3 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H301

H312

H400

H410

GHS06

GHS09

Dgr

H301

H312

H410

 

 

 

015-100-00-X

phoxim (ISO);

α-(diethoxyphosphinothioylimino) phenylacetonitrile

238-887-3

14816-18-3

Repr. 2

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H361f*** H302

H317

H400

H410

GHS08

GHS07

GHS09

Wng

H361f*** H302

H317

H410

 

M=1000

 

015-101-00-5

phosmet (ISO);

O, O-dimethyl phthalimidomethyl S-phosphorodithioate

211-987-4

732-11-6

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H312

H302

H400

H410

GHS07

GHS09

Wng

H312

H302

H410

 

M = 100

 

015-102-00-0

tris(2-chloroethyl)phosphate

204-118-5

115-96-8

Carc. 2

Repr. 1B

Acute Tox. 4 *

Aquatic Chronic 2

H351

H360F*** H302

H411

GHS08

GHS07

GHS09

Dgr

H351

H360F*** H302

H411

 

 

 

015-103-00-6

phosphorus tribromide

232-178-2

7789-60-8

Skin Corr. 1B

STOT SE 3

H314

H335

GHS05

GHS07

Dgr

H314

H335

EUH014

 

 

015-104-00-1

diphosphorus pentasulphide;

phosphorus pentasulphide

215-242-4

1314-80-3

Flam. Sol. 1

Water-react. 1

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

H228

H260

H332

H302

H400

GHS02

GHS07

GHS09

Dgr

H228

H260

H332

H302

H400

EUH029

 

T

015-105-00-7

triphenyl phosphite

202-908-4

101-02-0

Eye Irrit. 2

Skin Irrit. 2

Aquatic Acute 1

Aquatic Chronic 1

H319

H315

H400

H410

GHS07

GHS09

Wng

H319

H315

H410

 

Skin Irrit. 2; H315: C ≥ 5 % Eye Irrit. 2; H319: C ≥ 5 %

 

015-106-00-2

hexamethylphosphoric triamide; hexamethylphosphoramide

211-653-8

680-31-9

Carc. 1B

Muta. 1B

H350

H340

GHS08

Dgr

H350

H340

 

Carc. 1B;

H350: C ≥ 0,01  %

 

015-107-00-8

ethoprophos (ISO);

ethyl-S,S-dipropyl phosphorodithioate

236-152-1

13194-48-4

Acute Tox. 2 *

Acute Tox. 1

Acute Tox. 3 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H310

H301

H317

H400

H410

GHS06

GHS09

Dgr

H330

H310

H301

H317

H410

 

 

 

015-108-00-3

bromophos (ISO);

O-4-bromo-2,5-dichlorophenyl O,O-dimethyl phosphorothioate

218-277-3

2104-96-3

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

M = 100

 

015-109-00-9

crotoxyphos (ISO);

1-phenylethyl 3-(dimethoxyphosphinyloxy) isocrotonate

231-720-5

7700-17-6

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H311

H301

H400

H410

GHS06

GHS09

Dgr

H311

H301

H410

 

M = 10

 

015-110-00-4

cyanofenphos (ISO);

O-4-cyanophenyl O-ethyl phenylphosphonothioate

13067-93-1

Acute Tox. 3 *

STOT SE 1

Acute Tox. 4 *

Eye Irrit. 2

Aquatic Chronic 2

H301

H370 **

H312

H319

H411

GHS06

GHS08

GHS09

Dgr

H301

H370 **

H312

H319

H411

 

 

 

015-111-00-X

phosfolan (ISO);

diethyl 1,3-dithiolan-2-ylidenephosphoramidate

213-423-2

947-02-4

Acute Tox. 1

Acute Tox. 2 *

H310

H300

GHS06

Dgr

H310

H300

 

 

 

015-112-00-5

thionazin (ISO);

O,O-diethyl O-pyrazin-2-yl phosphorothioate;

206-049-6

297-97-2

Acute Tox. 1

Acute Tox. 2 *

H310

H300

GHS06

Dgr

H310

H300

 

 

 

015-113-00-0

tolclofos-methyl (ISO);

O-(2,6-dichloro-p-tolyl)-O,O-dimethyl thiophosphate

260-515-3

57018-04-9

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H317

H400

H410

GHS07

GHS09

Wng

H317

H410

 

 

 

015-114-00-6

chlormephos (ISO);

S-chloromethyl O,O-diethyl phosphorodithioate

246-538-1

24934-91-6

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

M = 10

 

015-115-00-1

chlorthiophos (ISO);

[isomeric reaction mass in which O-2,5-dichlorophenyl-4-methylthiophenyl O, O-diethyl phosphorothioate predominates]

244-663-6

21923-23-9

Acute Tox. 2 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H300

H311

H400

H410

GHS06

GHS09

Dgr

H300

H311

H410

 

M = 1000

 

015-116-00-7

demephion-O (ISO);

O, O-dimethyl O-2-methylthioethyl phosphorothioate

211-666-9

682-80-4

Acute Tox. 2 *

Acute Tox. 3 *

H300

H311

GHS06

Dgr

H300

H311

 

 

 

015-117-00-2

demephion-S (ISO);

O, O-dimethyl S-2-methylthioethyl phosphorothioate

219-971-9

2587-90-8

Acute Tox. 2 *

Acute Tox. 3 *

H300

H311

GHS06

Dgr

H300

H311

 

 

 

015-118-00-8

demeton

8065-48-3

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

H310

H300

H400

GHS06

GHS09

Dgr

H310

H300

H400

 

 

 

015-119-00-3

dimethyl 4-(methylthio)phenyl phosphate

3254-63-5

Acute Tox. 1

Acute Tox. 2 *

H310

H300

GHS06

Dgr

H310

H300

 

 

 

015-120-00-9

ditalimfos (ISO);

O, O-diethyl phthalimidophosphonothioate

225-875-8

5131-24-8

Skin Irrit. 2

Skin Sens. 1

H315

H317

GHS07

Wng

H315

H317

 

 

 

015-121-00-4

edifenphos (ISO);

O-ethyl S, S-diphenyl phosphorodithioate

241-178-1

17109-49-8

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H331

H301

H312

H317

H400

H410

GHS06

GHS09

Dgr

H331

H301

H312

H317

H410

 

 

 

015-122-00-X

etrimfos (ISO);

O-6-ethoxy-2-ethylpyrimidin-4-yl O, O-dimethylphosphorothioate

253-855-9

38260-54-7

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

M = 10

 

015-123-00-5

fenamiphos (ISO);

ethyl-4-methylthio-m-tolyl isopropyl phosphoramidate

244-848-1

22224-92-6

Acute Tox. 2

Acute Tox. 2

Acute Tox. 2

Eye Irrit. 2

Aquatic Acute 1

Aquatic Chronic 1

H300

H310

H330

H319

H400

H410

GHS06

GHS09

Dgr

H300

H310

H330

H319

H410

 

M = 100

M = 100

 

015-124-00-0

fosthietan (ISO);

diethyl 1,3-dithietan-2-ylidenephosphoramidate

244-437-7

21548-32-3

Acute Tox. 1

Acute Tox. 2 *

H310

H300

GHS06

Dgr

H310

H300

 

 

 

015-125-00-6

glyphosine (ISO);

N,N-bis(phosphonomethyl)glycine

219-468-4

2439-99-8

Eye Dam. 1

H318

GHS05

Dgr

H318

 

 

 

015-126-00-1

heptenophos (ISO);

7-chlorobicyclo(3.2.0)hepta-2,6-dien-6-yl dimethyl phosphate

245-737-0

23560-59-0

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H301

H400

H410

GHS06

GHS09

Dgr

H301

H410

 

M = 100

 

015-127-00-7

iprobenfos(ISO);

S-benzyl diisopropyl phosphorothioate

247-449-0

26087-47-8

Acute Tox. 4 *

Aquatic Chronic 2

H302

H411

GHS07

GHS09

Wng

H302

H411

 

 

 

015-128-00-2

IPSP;

S-ethylsulphinylmethyl O,O-diisopropylphosphorodithioate

5827-05-4

Acute Tox. 1

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H301

H400

H410

GHS06

GHS09

Dgr

H310

H301

H410

 

M = 100

 

015-129-00-8

isofenphos (ISO);

O-ethyl O-2-isopropoxycarbonylphenyl-isopropylphosphoramidothioate

246-814-1

25311-71-1

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H311

H301

H400

H410

GHS06

GHS09

Dgr

H311

H301

H410

 

M = 100

 

015-130-00-3

isothioate (ISO);

S-2-isopropylthioethyl O,O-dimethyl phosphorodithioate;

36614-38-7

Acute Tox. 3 *

Acute Tox. 3 *

H311

H301

GHS06

Dgr

H311

H301

 

 

 

015-131-00-9

isoxathion (ISO);

O,O-diethyl O-5-phenylisoxazol-3-ylphosphorothioate

242-624-8

18854-01-8

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H311

H301

H400

H410

GHS06

GHS09

Dgr

H311

H301

H410

 

 

 

015-132-00-4

S-(chlorophenylthiomethyl) O,O-dimethylphosphorodithioate; methylcarbophenothione

953-17-3

Acute Tox. 3 *

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H311

H301

H400

H410

GHS06

GHS09

Dgr

H311

H301

H410

 

M = 1000

 

015-133-00-X

piperophos (ISO);

S-2-methylpiperidinocarbonylmethyl-O, O-dipropyl phosphorodithioate

24151-93-7

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

M = 10

 

015-134-00-5

pirimiphos-methyl (ISO);

O-(2-diethylamino-6-methylpyrimidin-4-yl) O, O-dimethyl phosphorothioate

249-528-5

29232-93-7

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

015-135-00-0

profenofos (ISO)O-(4-bromo-2-chlorophenyl) O-ethyl S-propyl phosphorothioate;

255-255-2

41198-08-7

Acute Tox. 4 *

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H332

H312

H302

H400

H410

GHS07

GHS09

Wng

H332

H312

H302

H410

 

M = 1000

 

015-136-00-6

trans-isopropyl-3-[[(ethylamino)methoxyfosfinothioyl]oxy]crotonate;

isopropyl 3-[[(ethylamino)methoxyphosphinothioyl]oxy]isocrotonate; propetamphos (ISO)

250-517-2

31218-83-4

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H301

H400

H410

GHS06

GHS09

Dgr

H301

H410

 

M = 100

 

015-137-00-1

pyrazophos (ISO);

O, O-diethyl O-(6-ethoxycarbonyl-5-methylpyrazolo[2,3-a]pyrimidin-2-yl) phosphorothioate

236-656-1

13457-18-6

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H332

H302

H400

H410

GHS07

GHS09

Wng

H332

H302

H410

 

 

 

015-138-00-7

quinalphos (ISO);

O, O-diethyl-O-quinoxalin-2-yl phosphorothioate

237-031-6

13593-03-8

Acute Tox. 3 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H301

H312

H400

H410

GHS06

GHS09

Dgr

H301

H312

H410

 

M = 1000

 

015-139-00-2

terbufos (ISO);

S-tert-butylthiomethyl O, O-diethylphosphorodithioate;

235-963-8

13071-79-9

Acute Tox. 1

Acute Tox. 2 *

Aquatic Acute 1

Aquatic Chronic 1

H310

H300

H400

H410

GHS06

GHS09

Dgr

H310

H300

H410

 

M = 1000

 

015-140-00-8

triazophos (ISO);

O, O-diethyl-O-1-phenyl-1H-1,2,4-triazol-3-yl phosphorothioate

245-986-5

24017-47-8

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H331

H301

H312

H400

H410

GHS06

GHS09

Dgr

H331

H301

H312

H410

 

M=100

 

015-141-00-3

ethylenediammonium O, O-bis(octyl) phosphorodithioate, mixed isomers

400-520-1

Skin Corr. 1B

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H314

H302

H400

H410

GHS05

GHS07

GHS09

Dgr

H314

H302

H410

 

 

 

015-142-00-9

butyl (dialkyloxy(dibutoxyphosphoryloxy))titanium (trialkyloxy)titanium phosphate

401-100-0

Flam. Liq. 2

Eye Irrit. 2

Aquatic Chronic 2

H225

H319

H411

GHS02

GHS07

GHS09

Dgr

H225

H319

H411

 

 

T

015-143-00-4

reaction mass of 2-chloroethyl chloropropyl 2-chloroethylphosphonate, reaction mass of isomers and 2-chloroethyl chloropropyl 2-chloropropylphosphonate, reaction mass of isomers

401-740-0

Acute Tox. 4 *

H302

GHS07

Wng

H302

 

 

 

015-144-00-X

reaction mass of pentyl methylphosphinate and 2-methylbutyl methylphosphinate

402-090-0

87025-52-3

Skin Corr. 1B

H314

GHS05

Dgr

H314

 

 

 

015-145-00-5

reaction mass of copper(I) O, O-diisopropyl phosphorodithioate and copper(I) O-isopropyl O-(4-methylpent-2-yl) phosphorodithioate and copper(I) O, O-bis(4-methylpent-2-yl) phosphorodithioate

401-520-4

Aquatic Acute 1

Aquatic Chronic 1

H400

H410

GHS09

Wng

H410

 

 

 

015-146-00-0

S-(tricyclo(5.2.1.0 2,6)deca-3-en-8(or 9)-yl O-(isopropyl or isobutyl or 2-ethylhexyl) O-(isopropyl or isobutyl or 2-ethylhexyl) phosphorodithioate

401-850-9

Aquatic Acute 1

Aquatic Chronic 1

H400

H410

GHS09

Wng

H410

 

 

 

015-147-00-6

reaction mass of C12-14-tert-alkylammonium diphenyl phosphorothioate and dinonyl sulphide (or disulphide)

400-930-0

Skin Irrit. 2

Eye Dam. 1

Skin Sens. 1

Aquatic Chronic 2

H315

H318

H317

H411

GHS05

GHS07

GHS09

Dgr

H315

H318

H317

H411

 

 

 

015-148-00-1

2-(diphosphonomethyl)succinic acid

403-070-4

51395-42-7

Skin Corr. 1B

Skin Sens. 1

H314

H317

GHS05

GHS07

Dgr

H314

H317

 

 

 

015-149-00-7

reaction mass of: hexyldioctylphosphineoxide; dihexyloctylphosphineoxide; trioctylphosphineoxide

403-470-9

Skin Corr. 1B

Aquatic Acute 1

Aquatic Chronic 1

H314

H400

H410

GHS05

GHS09

Dgr

H314

H410

 

 

 

015-150-00-2

(2-(1,3-dioxolan-2-yl)ethyl)triphenylphosphonium bromide

404-940-6

86608-70-0

Acute Tox. 4 *

Eye Dam. 1

STOT RE 2 *

Aquatic Chronic 3

H302

H318

H373 **

H412

GHS08

GHS05

GHS07

Dgr

H302

H318

H373 **

H412

 

 

 

015-151-00-8

tris(isopropyl/tert-butylphenyl)phosphate

405-010-2

Aquatic Chronic 2

H411

GHS09

H411

 

 

 

015-152-00-3

dioxabenzofos (ISO);

2-methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulphide

223-292-3

3811-49-2

Acute Tox. 3 *

Acute Tox. 3 *

STOT SE 1

Aquatic Chronic 2

H311

H301

H370 **

H411

GHS06

GHS08

GHS09

Dgr

H311

H301

H370 **

H411

 

 

 

015-153-00-9

isazofos (ISO);

O-(5-chloro-1-isopropyl-1,2,4-triazol-3-yl) O, O-diethyl phosphorothioate

255-863-8

42509-80-8

Acute Tox. 2 *

Acute Tox. 3 *

Acute Tox. 3 *

STOT RE 2 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H330

H311

H301

H373 **

H317

H400

H410

GHS06

GHS08

GHS09

Dgr

H330

H311

H301

H373 **

H317

H410

 

 

 

015-154-00-4

ethephon;

2-chloroethylphosphonic acid

240-718-3

16672-87-0

Acute Tox. 3

Acute Tox. 4

Acute Tox. 4

Skin Corr. 1C

Aquatic Chronic 2

H311

H332

H302

H314

H411

GHS06

GHS05

GHS09

Dgr

H311

H332

H302

H314

H411

EUH071

 

 

015-155-00-X

glufosinate ammonium (ISO); ammonium 2-amino-4-(hydroxymethylphosphinyl)butyrate

278-636-5

77182-82-2

Repr. 1B

Acute Tox. 4 *

Acute Tox. 4 *

Acute Tox. 4 *

STOT RE 2 *

H360Fd

H332

H312

H302

H373**

GHS08

GHS07

Dgr

H360Fd

H332

H312

H302

H373**

 

 

 

015-156-00-5

methyl 3-[(dimethoxyphosphinothioyl)oxy]methacrylate; [1]

methacrifos (ISO);

methyl (E)-3-[(dimethoxyphosphinothioyl)oxy]methacrylate [2]

250-366-9 [1]-[2]

30864-28-9 [1]

62610-77-9 [2]

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H317

H400

H410

GHS07

GHS09

Wng

H302

H317

H410

 

 

 

015-157-00-0

phosphonic acid; [1]

phosphorous acid [2]

237-066-7 [1]

233-663-1 [2]

13598-36-2 [1]

10294-56-1 [2]

Acute Tox. 4 *

Skin Corr. 1A

H302

H314

GHS05

GHS07

Dgr

H302

H314

 

 

 

015-158-00-6

(η-cyclopentadienyl)(η-cumenyl)iron(1+)hexafluorophosphate(1-)

402-340-9

32760-80-8

Aquatic Chronic 3

H412

H412

 

 

 

015-159-00-1

hydroxyphosphonoacetic acid

405-710-8

23783-26-8

Acute Tox. 4 *

STOT RE 2 *

Skin Corr. 1B

Skin Sens. 1

H302

H373 **

H314

H317

GHS08

GHS05

GHS07

Dgr

H302

H373 **

H314

H317

 

 

 

015-160-00-7

vanadyl pyrophosphate

406-260-5

58834-75-6

Eye Irrit. 2

Skin Sens. 1

Aquatic Chronic 3

H319

H317

H412

GHS07

Wng

H319

H317

H412

 

 

 

015-161-00-2

divanadyl pyrophosphate

407-130-0

65232-89-5

Acute Tox. 4 *

Eye Dam. 1

Skin Sens. 1

Aquatic Chronic 2

H302

H318

H317

H411

GHS05

GHS07

GHS09

Dgr

H302

H318

H317

H411

 

 

 

015-162-00-8

vanadium(IV) oxide hydrogen phosphate hemihydrate, lithium, zinc, molybdenum, iron and chlorine-doped

407-350-7

Acute Tox. 4 *

STOT RE 2 *

Eye Dam. 1

Aquatic Chronic 2

H332

H373 **

H318

H411

GHS08

GHS05

GHS07

GHS09

Dgr

H332

H373 **

H318

H411

 

 

 

015-163-00-3

bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosphinoxide

412-010-6

145052-34-2

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H317

H400

H410

GHS07

GHS09

Wng

H317

H410

 

 

 

015-164-00-9

calcium P, P'-(1-hydroxyethylene)bis(hydrogen phosphonate)dihydrate

400-480-5

36669-85-9

Aquatic Chronic 3

H412

H412

 

 

 

015-165-00-4

reaction mass of: thiobis(4,1-phenylene)-S, S,S',S'-tetraphenyldisulfonium bishexafluorophosphate; diphenyl(4-phenylthiophenyl)sulfonium hexafluorophosphate

404-986-7

Eye Dam. 1

Aquatic Acute 1

Aquatic Chronic 1

H318

H400

H410

GHS05

GHS09

Dgr

H318

H410

 

 

 

015-166-00-X

3,9-bis(2,6-di-tert-butyl-4-methylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane

410-290-4

80693-00-1

Aquatic Chronic 4

H413

H413

 

 

 

015-167-00-5

3-(hydroxyphenylphosphinyl)propanoic acid

411-200-6

14657-64-8

Eye Dam. 1

H318

GHS05

Dgr

H318

 

 

 

015-168-00-0

fosthiazate (ISO);

(RS)-S-sec-butyl-O-ethyl-2-oxo-1,3-thiazolidin-3-ylphosphonothioate

98886-44-3

Acute Tox. 3 *

Acute Tox. 3 *

Acute Tox. 4 *

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H331

H301

H312

H317

H400

H410

GHS06

GHS09

Dgr

H331

H301

H312

H317

H410

EUH070

 

 

015-169-00-6

tributyltetradecylphosphonium tetrafluoroborate

413-520-1

Acute Tox. 4 *

STOT RE 2 *

Skin Corr. 1B

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H302

H373 **

H314

H317

H400

H410

GHS08

GHS05

GHS07

GHS09

Dgr

H302

H373 ** H314

H317

H410

 

 

 

015-170-00-1

reaction mass of: di-(1-octane-N, N,N-trimethylammonium) octylphosphate; 1-octane-N, N,N-trimethylammonium di-octylphosphate; 1-octane-N, N,N-trimethylammonium octylphosphate

407-490-9

Acute Tox. 4 *

Acute Tox. 4 *

Skin Corr. 1B

H312

H302

H314

GHS05

GHS07

Dgr

H312

H302

H314

 

 

 

015-171-00-7

O, O,O-tris(2(or 4)-C 9-10-isoalkylphenyl) phosphorothioate

406-940-1

Aquatic Chronic 2

H411

GHS09

H411

 

 

 

015-172-00-2

reaction mass of: bis(isotridecylammonium)mono(di-(4-methylpent-2-yloxy)thiophosphorothionylisopropyl)phosphate;

isotridecylammonium bis(di-(4-methylpent-2-yloxy)thiophosphorothionylisopropyl)phosphate

406-240-6

Flam. Liq. 3

Skin Corr. 1B

Aquatic Chronic 2

H226

H314

H411

GHS02

GHS05

GHS09

Dgr

H226

H314

H411

 

 

 

015-173-00-8

methyl [2-(1,1-dimethylethyl)-6-methoxypyrimidin-4-yl]ethylphosphonothioate

414-080-3

117291-73-3

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

015-174-00-3

1-chloro-N,N-diethyl-1,1-diphenyl-1-(phenylmethyl)phosphoramine

411-370-1

82857-68-9

Acute Tox. 3 *

Eye Dam. 1

Aquatic Chronic 2

H301

H318

H411

GHS06

GHS05

GHS09

Dgr

H301

H318

H411

 

 

 

015-175-00-9

tert-butyl (triphenylphosphoranylidene) acetate

412-880-7

35000-38-5

Acute Tox. 3 *

STOT RE 2 *

Eye Irrit. 2

Skin Sens. 1

Aquatic Chronic 2

H301

H373 **

H319

H317

H411

GHS06

GHS08

GHS09

Dgr

H301

H373 ** H319

H317

H411

 

 

 

015-176-00-4

P, P,P',P'-tetrakis-(o-methoxyphenyl)propane-1,3-diphosphine

413-430-2

116163-96-3

Aquatic Acute 1

Aquatic Chronic 1

H400

H410

GHS09

Wng

H410

 

 

 

015-177-00-X

((4-phenylbutyl)hydroxyphosphoryl)acetic acid

412-170-7

83623-61-4

STOT RE 2 *

Eye Dam. 1

Skin Sens. 1

H373 **

H318

H317

GHS08

GHS05

Dgr

H373 ** H318

H317

 

 

 

015-178-00-5

(R)-α-phenylethylammonium(-)-(1R, 2S)-(1,2-epoxypropyl)phosphonate monohydrate

418-570-8

25383-07-7

Repr. 2

Aquatic Chronic 2

H361f *** H411

GHS08

GHS09

Wng

H361f *** H411

 

 

 

015-179-00-0

UVCB condensation product of: tetrakis-hydroxymethylphosphonium chloride, urea and distilled hydrogenated C16-18 tallow alkylamine

422-720-8

166242-53-1

Carc. 2

Acute Tox. 4 *

STOT RE 2 *

Skin Corr. 1B

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H351

H302

H373 **

H314

H317

H400

H410

GHS08

GHS05

GHS07

GHS09

Dgr

H351

H302

H373 ** H314

H317

H410

 

 

 

015-180-00-6

[R-(R*,S*)]-[[2-methyl-1-(1-oxopropoxy)propoxy]-(4-phenylbutyl)phosphinyl] acetic acid, (-)-cinchonidine (1:1) salt

415-820-8

137590-32-0

Eye Dam. 1

Skin Sens. 1

Aquatic Chronic 3

H318

H317

H412

GHS05

GHS07

Dgr

H318

H317

H412

 

 

 

015-181-00-1

phosphine

232-260-8

7803-51-2

Flam. Gas 1

Press. Gas

Acute Tox. 2 *

Skin Corr. 1B

Aquatic Acute 1

H220

H330

H314

H400

GHS02

GHS04

GHS06

GHS05

GHS09

Dgr

H220

H330

H314

H400

 

 

U

015-182-00-7

tetrapropan-2-yl (dichloromethanediyl)bis(phosphonate)

430-630-5

10596-22-2

Acute Tox. 4 *

Eye Irrit. 2

Skin Sens. 1

H302

H319

H317

GHS07

Wng

H302

H319

H317

 

 

 

015-183-00-2

(1-hydroxydodecylidene)diphosphonic acid

425-230-2

16610-63-2

Skin Corr. 1B

Aquatic Acute 1

Aquatic Chronic 1

H314

H400

H410

GHS05

GHS09

Dgr

H314

H410

 

 

 

015-184-00-8

salts of glyphosate, with the exception of those specified elsewhere in this Annex

Aquatic Chronic 2

H411

GHS09

H411

 

 

A

015-186-00-9

chlorpyrifos-methyl (ISO) O, O-dimethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate

227-011-5

5598-13-0

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H317

H400

H410

GHS07

GHS09

Wng

H317

H410

 

M = 10000

 

015-187-00-4

reaction mass of: tetrasodium(((2-hydroxyethyl)imino)bis(methylene))bisphosphonate, N-oxide;

trisodium ((tetrahydro-2-hydroxy-4H-1,4,2-oxazaphosphorin-4-yl)-methyl)phosphonate, N-oxide, P-oxide

417-540-1

Eye Dam. 1

Aquatic Chronic 2

H318

H411

GHS05

GHS09

Dgr

H318

H411

 

 

 

015-189-00-5

phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide

423-340-5

162881-26-7

Skin Sens. 1

Aquatic Chronic 4

H317

H413

GHS07

Wng

H317

H413

 

 

 

015-190-00-0

bis(2,4-dicumylphenyl)neopentyl diphosphite;

3,9-bis[2,4-bis(1-methyl-1-phenylethyl)phenoxy]-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane

421-920-2

154862-43-8

Aquatic Chronic 4

H413

H413

 

 

 

015-191-00-6

dodecyldiphenyl phosphate

431-760-5

27460-02-2

Skin Irrit. 2

Aquatic Chronic 3

H315

H412

GHS07

Wng

H315

H412

 

 

 

015-192-00-1

tetrakis(2,6-dimethylphenyl)-m-phenylene biphosphate

432-770-2

139189-30-3

Skin Sens. 1

H317

GHS07

Wng

H317

 

 

 

015-193-00-7

triphenyl(phenylmethyl)phosphonium 1,1,2,2,3,3,4,4,4-nonafluoro-N-methyl-1-butanesulfonamide (1:1)

442-960-7

332350-93-3

Acute Tox. 3 *

Eye Dam. 1

Aquatic Acute 1

Aquatic Chronic 1

H301

H318

H400

H410

GHS05

GHS06

GHS09

Dgr

H301

H318

H410

 

 

 

015-194-00-2

tetrabutyl-phosphonium nonafluoro-butane-1-sulfonate

444-440-5

220689-12-3

Acute Tox. 4 *

Aquatic Chronic 3

H302

H412

GHS07

Wng

H302

H412

 

 

 

015-195-00-8

reaction mass of: potassium o-toluenephosphonate;

potassium m-toluenephosphonate; potassium p-toluenephosphonate

433-860-4

Eye Irrit. 2

Skin Sens. 1

Aquatic Chronic 3

H319

H317

H412

GHS07

Wng

H319

H317

H412

 

 

 

015-196-00-3

reaction mass of: dimethyl (2-(hydroxymethylcarbamoyl)ethyl)phosphonate;

diethyl (2-(hydroxymethylcarbamoyl)ethyl)phosphonate;

methyl ethyl (2-(hydroxymethylcarbamoyl)ethyl)phosphonate

435-960-3

Carc. 1B

Muta. 1B

Skin Sens. 1

H350

H340

H317

GHS08

GHS07

Dgr

H350

H340

H317

 

 

 

015-197-00-9

bis(2,4,4-trimethylpentyl)dithiophosphonic acid

420-160-9

107667-02-7

Flam. Liq. 3

Acute Tox. 3 *

Acute Tox. 4 *

Skin Corr. 1B

Aquatic Chronic 2

H226

H331

H302

H314

H411

GHS02

GHS06

GHS05

GHS09

Dgr

H226

H331

H302

H314

H411

 

 

 

015-198-00-4

(4-phenylbutyl)phosphinic acid

420-450-5

86552-32-1

Carc. 2

Eye Dam. 1

H351

H318

GHS05

GHS08

Dgr

H351

H318

 

 

 

015-199-00-X

tris[2-chloro-1-chloromethyl)ethyl] phosphate

237-159-2

13674-87-8

Carc. 2

H351

GSH08

Wng

H351

 

 

 

015-200-00-3

indium phosphide

244-959-5

22398-80-7

Carc. 1B Repr. 2

STOT RE 1

H350

H361f

H372 (lungs)

GHS08

Dgr

H350

H361f

H372 (lungs)

 

STOT RE 1; H372: C ≥0,1  % Carc 1B;

H350: C

≥0,01  % STOT RE 2;

H373: 0,01  % ≤

C < 0,1  %

 

015-201-00-9

trixylyl phosphate

246-677-8

25155-23-1

Repr. 1B

H360F

GHS08

Dgr

H360F

 

 

 

015-202-00-4

tris(nonylphenyl) phosphite

247-759-6

26523-78-4

Skin Sens. 1

Aquatic Acute 1

Aquatic Chronic 1

H317

H400

H410

GHS07

GHS09

Wng

H317

H410

 

 

 

015-203-00-X

diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide

278-355-8

75980-60-8

Repr. 2

H361f (causing atrophy of the testes)

GHS08

Wng

H361f (causing atrophy of the testes)

 

 

 

016-001-00-4

hydrogen sulphide

231-977-3

7783-06-4

Flam. Gas 1

Press. Gas

Acute Tox. 2 *

Aquatic Acute 1

H220

H330

H400

GHS02

GHS04

GHS06

GHS09

Dgr

H220

H330

H400

 

 

U

016-002-00-X

barium sulphide

244-214-4

21109-95-5

Acute Tox. 4 *

Acute Tox. 4 *

Aquatic Acute 1

H332

H302

H400

GHS07

GHS09

Wng

H332

H302

H400

EUH031

 

 

016-003-00-5

barium polysulphides

256-814-3

50864-67-0

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Aquatic Acute 1

H319

H335

H315

H400

GHS07

GHS09

Wng

H319

H335

H315

H400

EUH031

 

 

016-004-00-0

calcium sulphide

243-873-5

20548-54-3

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Aquatic Acute 1

H319

H335

H315

H400

GHS07

GHS09

Wng

H319

H335

H315

H400

EUH031

 

 

016-005-00-6

calcium polysulphides

215-709-2

1344-81-6

Eye Irrit. 2

STOT SE 3

Skin Irrit. 2

Aquatic Acute 1

H319

H335

H315

H400

GHS07

GHS09

Wng

H319

H335

H315

H400

EUH031

 

 

016-006-00-1

dipotassium sulphide;

potassium sulphide

215-197-0

1312-73-8

Skin Corr. 1B

Aquatic Acute 1

H314

H400

GHS05

GHS09

Dgr

H314

H400

EUH031

 

 

016-007-00-7

potassium polysulphides

253-390-1

37199-66-9

Skin Corr. 1B

Aquatic Acute 1

H314

H400

GHS05

GHS09

Dgr

H314

H400

EUH031

 

 

016-008-00-2

ammonium polysulphides

232-989-1

9080-17-5

Skin Corr. 1B

Aquatic Acute 1

H314

H400

GHS05

GHS09

Dgr

H314

H400

EUH031

EUH031: C ≥1 %

 

016-009-00-8

disodium sulfide;

sodium sulfide

215-211-5

1313-82-2

Acute Tox. 3 *

Acute Tox. 4 *

Skin Corr. 1B

Aquatic Acute 1

H311

H302

H314

H400

GHS06

GHS05

GHS09

Dgr

H311

H302

H314

H400

 

 

 

016-010-00-3

sodium polysulphides

215-686-9

1344-08-7

Acute Tox. 3 *

Skin Corr. 1B

Aquatic Acute 1

H301

H314

H400

GHS06

GHS05

GHS09

Dgr

H301

H314

H400

EUH031

 

 

016-011-00-9

sulphur dioxide

231-195-2

7446-09-5

Press. Gas

Acute Tox. 3 *

Skin Corr. 1B

H331

H314

GHS04

GHS06

GHS05

Dgr

H331

H314

 

*

U5

016-012-00-4

disulphur dichloride;

sulfur monochloride

233-036-2

10025-67-9

Acute Tox. 3 *

Acute Tox. 4 *

Skin Corr. 1A

Aquatic Acute 1

H301

H332

H314

H400

GHS06

GHS05

GHS09

Dgr

H301

H332

H314

H400

EUH014

EUH029

STOT SE 3; H335: C ≥ 1 %

 

016-013-00-X

sulphur dichloride

234-129-0

10545-99-0

Skin Corr. 1B

STOT SE 3

Aquatic Acute 1

H314

H335

H400

GHS05

GHS07

GHS09

Dgr

H314

H335

H400

EUH014

STOT SE 3; H335: C ≥ 5 %

 

016-014-00-5

sulphur tetrachloride

13451-08-6

Skin Corr. 1B

Aquatic Acute 1

H314

H400

GHS05

GHS09

Dgr

H314

H400

EUH014

STOT SE 3; H335: C ≥ 5 %

 

016-015-00-0

thionyl dichloride;

thionyl chloride

231-748-8

7719-09-7

Acute Tox. 4 *

Acute Tox. 4 *

Skin Corr. 1A

H332

H302

H314

GHS05

GHS07

Dgr

H332

H302

H314

EUH014

EUH029

STOT SE 3; H335: C ≥ 1 %

 

016-016-00-6

sulphuryl chloride

232-245-6

7791-25-5

Skin Corr. 1B

STOT SE 3

H314

H335

GHS05

GHS07

Dgr

H314

H335

EUH014

 

 

016-017-00-1

chlorosulphonic acid

232-234-6

7790-94-5

Skin Corr. 1A

STOT SE 3

H314

H335

GHS05

GHS07

Dgr

H314

H335

EUH014

 

 

016-018-00-7

fluorosulphonic acid

232-149-4

7789-21-1

Acute Tox. 4 *

Skin Corr. 1A

H332

H314

GHS05

GHS07

Dgr

H332

H314

 

 

 

016-019-00-2

oleum … % SO3

Skin Corr. 1A

STOT SE 3

H314

H335

GHS05

GHS07

Dgr

H314

H335

EUH014

 

B

016-020-00-8

sulphuric acid … %

231-639-5

7664-93-9

Skin Corr. 1A

H314

GHS05

Dgr

H314

 

Skin Corr. 1A; H314: C ≥ 15 % Skin Irrit. 2; H315: 5 % ≤ C

< 15 %

Eye Irrit. 2; H319: 5 % ≤ C

< 15 %

B

016-021-00-3

methanethiol;

methyl mercaptan

200-822-1

74-93-1

Flam. Gas. 1

Press. Gas

Acute Tox. 3 *

Aquatic Acute 1

Aquatic Chronic 1

H220

H331

H400

H410

GHS02

GHS04

GHS06

GHS09

Dgr

H220

H331

H410

 

 

U

016-022-00-9

ethanethiol;

ethyl mercaptan

200-837-3

75-08-1

Flam. Liq. 2

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H225

H332

H400

H410

GHS02

GHS07

GHS09

Dgr

H225

H332

H410

 

 

 

016-023-00-4

dimethyl sulphate

201-058-1

77-78-1

Carc. 1B

Muta. 2

Acute Tox. 2 *

Acute Tox. 3 *

Skin Corr. 1B

Skin Sens. 1

H350

H341

H330

H301

H314

H317

GHS06

GHS08

GHS05

Dgr

H350

H341

H330

H301

H314

H317

 

Carc. 1B; H350: C ≥ 0,01  % Muta. 2 H341: C ≥ 0,01  % STOT SE 3; H335: C ≥ 5 %

 

016-024-00-X

dimexano(ISO); bis(methoxythiocarbonyl) disulphide

215-993-8

1468-37-7

Acute Tox. 4 *

Aquatic Acute 1

Aquatic Chronic 1

H302

H400

H410

GHS07

GHS09

Wng

H302

H410

 

 

 

016-025-00-5

disul (ISO);

2-(2,4-dichlorophenoxy)ethyl hydrogensulphate;

2,4-DES

205-259-5

149-26-8

Acute Tox. 4 *

Skin Irrit. 2

Eye Dam. 1

H302

H315

H318

GHS05

GHS07

Dgr

H302

H315

H318

 

 

 

016-026-00-0

sulphamidic acid;

sulphamic acid;

sulfamic acid

226-218-8

5329-14-6

Eye Irrit. 2

Skin Irrit. 2

Aquatic Chronic 3

H319

H315

H412

GHS07

Wng

H319

H315

H412

 

 

 

016-027-00-6

diethyl sulphate

200-589-6

64-67-5

Carc. 1B

Muta. 1B

Acute Tox. 4 *

Acute Tox. 4 *

Acute Tox. 4 *

Skin Corr. 1B

H350

H340

H332

H312

H302

H314

GHS05

GHS08

GHS07

Dgr

H350

H340

H332

H312

H302

H314

 

 

 

016-028-00-1

sodium dithionite;