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Document 32013R0944

    Commission Regulation (EU) No 944/2013 of 2 October 2013 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures Text with EEA relevance

    IO L 261, 3.10.2013, p. 5–22 (BG, ES, CS, DA, DE, ET, EL, EN, FR, HR, IT, LV, LT, HU, MT, NL, PL, PT, RO, SK, SL, FI, SV)

    Legal status of the document In force

    ELI: http://data.europa.eu/eli/reg/2013/944/oj

    3.10.2013   

    EN

    Official Journal of the European Union

    L 261/5


    COMMISSION REGULATION (EU) No 944/2013

    of 2 October 2013

    amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures

    (Text with EEA relevance)

    THE EUROPEAN COMMISSION,

    Having regard to the Treaty on the Functioning of the European Union,

    Having regard to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (1), and in particular Article 37(5) and Article 53 thereof,

    Whereas:

    (1)

    In respect of precautionary statement P210 set out in table 6.2 Part 1 of Annex IV to Regulation (EC) No 1272/2008 the 5th revision of the Globally Harmonised System of Classification and Labelling of Chemicals (hereinafter ‘GHS’) of the United Nations has brought about changes which were not fully taken into account in Commission Regulation (EU) No 487/2013 (2). For reasons of consistency it is necessary to provide for full alignment between the GHS and Regulation (EC) No 1272/2008.

    (2)

    Part 3 of Annex VI to Regulation (EC) No 1272/2008 contains two lists of harmonised classification and labelling of hazardous substances. Table 3.1 lists the harmonised classification and labelling of hazardous substances based on the criteria set out in Parts 2 to 5 of Annex I to Regulation (EC) No 1272/2008. Table 3.2 lists the harmonised classification and labelling of hazardous substances based on the criteria set out in Annex VI to Council Directive 67/548/EEC of 27 June 1967 on the approximation of laws, regulations and administrative provisions relating to the classification, packaging and labelling of dangerous substances (3). Those two lists need to be amended to include updated classifications for substances already subject to those harmonised classifications and to include new harmonised classifications.

    (3)

    The Committee for Risk Assessment (RAC) of the European Chemicals Agency (ECHA) has issued opinions on proposals for harmonised classification and labelling of substances which had been submitted to ECHA pursuant to Article 37 of Regulation (EC) No 1272/2008. Based on those opinions, as well as on the comments received from the parties concerned, it is appropriate to amend Annex VI to Regulation (EC) No 1272/2008 in order to harmonise the classification and labelling of certain substances.

    (4)

    The harmonised classifications set out in Part 3 of Annex VI to Regulation (EC) No 1272/2008, as amended by this Regulation, should not apply immediately, as a certain period of time will be necessary to allow operators to adapt the labelling and packaging of substances and mixtures to the new classifications and to sell existing stocks. In addition, a certain period of time will be necessary to allow operators to comply with the registration obligations resulting from the new harmonised classifications for substances classified as carcinogenic, mutagenic or toxic to reproduction, categories 1A and 1B (Table 3.1) and categories 1 and 2 (Table 3.2), or as very toxic to aquatic organisms which may cause long term effects in the aquatic environment, in particular with those set out in Article 23 of Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (4).

    (5)

    With regard to the substance pitch, coal tar, high-temp. (EC Number: 266-028-2), an extended period of time will be necessary to allow operators to comply with the obligations resulting from the new harmonised classification for substances classified as very toxic to aquatic organisms which may cause long term effects in the aquatic environment, in particular with those set out in Article 3 and Annex III of Directive 2008/68/EC of the European Parliament and of the Council of 24 September 2008 on the inland transport of dangerous goods (5). Therefore, a longer transition time should be foreseen before the harmonised classification has to be applied.

    (6)

    With regard to the substance gallium arsenide (EC Number: 215-114-8), the RAC is in the process of adopting a new opinion for the hazard class ‘toxicity to reproduction’. Therefore, this hazard class should not be included in Annex VI to Regulation (EC) No 1272/2008 until that opinion is finalised.

    (7)

    With regard to the substance polyhexamethylene biguanide hydrochloride (CAS number 27083-27-8 or 32289-58-0), new scientific data has been made available for the hazard class ‘acute toxicity (inhalation)’, which suggests that the classification for this hazard class as recommended in the RAC opinion, which is based on older data, might not be appropriate. Therefore, this hazard class should not be included in Annex VI to Regulation (EC) No 1272/2008 until RAC has had the opportunity to deliver an opinion on the new information, while all other hazard classes covered by the earlier RAC opinion should be included.

    (8)

    In line with the transitional provisions of Regulation (EC) No 1272/2008 which allow the application of the new provisions at an earlier stage on a voluntary basis, suppliers should have the possibility of applying the harmonised classifications set out in Part 3 of Annex VI to Regulation (EC) No 1272/2008, as amended by this Regulation, and of adapting the labelling and packaging accordingly on a voluntary basis before the dates by which the harmonised classifications will become mandatory.

    (9)

    The measures provided for in this Regulation are in accordance with the opinion of the Committee established under Article 133 of Regulation (EC) No 1907/2006,

    HAS ADOPTED THIS REGULATION:

    Article 1

    Regulation (EC) No 1272/2008 is amended as follows:

    (1)

    Annex IV is amended in accordance with the Annex I to this Regulation;

    (2)

    Part 3 of Annex VI is amended as follows:

    (a)

    Table 3.1 is amended as follows:

    (i)

    The entries set out in Annex VI to Regulation (EC) No 1272/2008 corresponding to the entries set out in Annex II to this Regulation are replaced by the entries set out in Annex II to this Regulation;

    (ii)

    The entries set out in Annex III to this Regulation are inserted in accordance with the order of the entries set out in Table 3.1.

    (b)

    Table 3.2 is amended as follows:

    (i)

    The entries set out in Annex VI to Regulation (EC) No 1272/2008 corresponding to the entries set out in Annex IV to this Regulation are replaced by the entries set out in in Annex IV to this Regulation;

    (ii)

    The entries set out in Annex V to this Regulation are inserted in accordance with the order of the entries set out in Table 3.2.

    Article 2

    1.   By way of derogation from Article 3(2) substances and mixtures may, before 1 December 2014 and 1 June 2015 respectively, be classified, labelled and packaged in accordance with Regulation (EC) No 1272/2008 as amended by this Regulation.

    2.   By way of derogation from Article 3(2), substances classified, labelled and packaged in accordance with Regulation (EC) No 1272/2008 and placed on the market before 1 December 2014, shall not be required to be relabelled and repackaged in accordance with Regulation (EC) No 1272/2008 as amended by this Regulation until 1 December 2016.

    3.   By way of derogation from Article 3(2) mixtures classified, labelled and packaged in accordance with Directive 1999/45/EC of the European Parliament and of the Council (6) or Regulation (EC) No 1272/2008 and placed on the market before 1 June 2015, shall not be required to be relabelled and repackaged in accordance with Regulation (EC) No 1272/2008 as amended by this Regulation until 1 June 2017.

    4.   By way of derogation from Article 3(3) the harmonised classifications set out in Part 3 of Annex VI to Regulation (EC) No 1272/2008, as amended by this Regulation, may be applied before the dates referred to in Article 3(3).

    Article 3

    1.   This Regulation shall enter into force on the twentieth day following that of its publication in the Official Journal of the European Union.

    2.   Article 1(1) shall apply in respect of substances from 1 December 2014 and in respect of mixtures from 1 June 2015.

    3.   Article 1(2) shall apply from 1 January 2015 for all entries except for the entry pitch, coal tar, high-temp. (EC Number 266-028-2), for which Article 1 shall apply from 1 April 2016.

    This Regulation shall be binding in its entirety and directly applicable in all Member States.

    Done at Brussels, 2 October 2013.

    For the Commission

    The President

    José Manuel BARROSO


    (1)   OJ L 353, 31.12.2008, p. 1.

    (2)   OJ L 149, 1.6.2013, p. 1.

    (3)   OJ 196, 16.8.1967, p. 1.

    (4)   OJ L 396, 30.12.2006, p. 1.

    (5)   OJ L 260, 30.9.2008, p. 13.

    (6)   OJ L 200, 30.7.1999, p. 1.


    ANNEX I

    In Part 1, Table 6.2 of Annex IV to Regulation (EC) No 1272/2008, Code P210 is replaced by the following:

    ‘P210

    Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

    Explosives (section 2.1)

    Divisions 1.1, 1.2, 1.3, 1.4, 1.5

     

    Flammable gases (section 2.2)

    1, 2

    Aerosols (section 2.3)

    1, 2, 3

    Flammable liquids (section 2.6)

    1, 2, 3

    Flammable solids (section 2.7)

    1, 2

    Self-reactive substances and mixtures (section 2.8)

    Types A, B, C, D, E, F

    Pyrophoric liquids (section 2.9)

    1

    Pyrophoric solids (section 2.10)

    1

    Oxidising liquids (section 2.13)

    1, 2, 3

    Oxidising solids (section 2.14)

    1, 2, 3

    Organic peroxides (section 2.15)

    Types A, B, C, D, E, F’


    ANNEX II

    Index No

    International Chemical Identification

    EC No

    CAS No

    Classification

    Labelling

    Specific Conc. Limits,

    M — Factors

    Notes

    Hazard Class and Category Code(s)

    Hazard statement Code(s)

    Pictogram, Signal Word Code(s)

    Hazard statement Code(s)

    Suppl. Hazard statement Code(s)

    015-004-00-8

    aluminium phosphide

    244-088-0

    20859-73-8

    Water-react. 1

    H260

    GHS02

    H260

    EUH029

    M = 100

     

    Acute Tox. 2

    H300

    GHS06

    H300

    EUH032

     

    Acute Tox. 3

    H311

    GHS09

    H311

     

    Acute Tox. 1

    H330

    Dgr

    H330

     

    Aquatic Acute 1

    H400

     

    H400

     

    015-005-00-3

    magnesium phosphide;

    trimagnesium diphosphide

    235-023-7

    12057-74-8

    Water-react. 1

    H260

    GHS02

    H260

    EUH029

    M = 100

     

    Acute Tox. 2

    H300

    GHS06

    H300

    EUH032

     

    Acute Tox. 3

    H311

    GHS09

    H311

     

    Acute Tox. 1

    H330

    Dgr

    H330

     

    Aquatic Acute 1

    H400

     

    H400

     

    015-123-00-5

    fenamiphos (ISO);

    ethyl-4-methylthio-m-tolyl isopropyl phosphoramidate

    244-848-1

    22224-92-6

    Acute Tox. 2

    H300

    GHS06

    H300

     

    M = 100

    M = 100

     

    Acute Tox. 2

    H310

    GHS09

    H310

    Acute Tox. 2

    H330

    Dgr

    H330

    Eye Irrit. 2

    H319

     

    H319

    Aquatic Acute 1

    H400

     

     

    Aquatic Chronic 1

    H410

     

    H410

    030-012-00-1

    aluminium-magnesium-zinc-carbonate-hydroxide

    423-570-6

    169314-88-9

    Aquatic Chronic 4

    H413

     

    H413

     

     

     

    602-006-00-4

    chloroform;

    trichloromethane

    200-663-8

    67-66-3

    Carc. 2

    H351

    GHS06

    H351

     

     

     

    Repr. 2

    H361d

    GHS08

    H361d

    Acute Tox. 3

    H331

    Dgr

    H331

    Acute Tox. 4

    H302

     

    H302

    STOT RE 1

    H372

     

    H372

    Eye Irrit. 2

    H319

     

    H319

    Skin Irrit. 2

    H315

     

    H315

    603-097-00-3

    1,1’,1’-nitrilotripropan-2-ol;

    triisopropanolamine

    204-528-4

    122-20-3

    Eye Irrit. 2

    H319

    GHS07

    Wng

    H319

     

     

     

    605-008-00-3

    acrolein;

    prop-2-enal;

    acrylaldehyde

    203-453-4

    107-02-8

    Flam. Liq. 2

    H225

    GHS02

    H225

    EUH071

    Skin Corr. 1; H314: C ≥ 0,1 %

    D

    Acute Tox. 1

    H330

    GHS06

    H330

     

    Acute Tox. 2

    H300

    GHS05

    H300

     

    Acute Tox. 3

    H311

    GHS09

    H311

     

    Skin Corr. 1

    H314

    Dgr

    H314

     

    Aquatic Acute 1

    H400

     

     

     

    M = 100

    Aquatic Chronic 1

    H410

     

    H410

     

    M = 1

    607-023-00-0

    vinyl acetate

    203-545-4

    108-05-4

    Flam. Liq. 2

    H225

    GHS02

    H225

     

     

    D

    Carc. 2

    H351

    GHS08

    H351

     

     

    Acute Tox. 4

    H332

    GHS07

    H332

     

     

    STOT SE 3

    H335

    Dgr

    H335

     

     

    607-613-00-8

    reaction mass of:

     

    succinic acid

     

    monopersuccinic acid

     

    dipersuccinic acid

     

    monomethyl ester of succinic acid

     

    monomethyl ester of persuccinic acid

     

    dimethyl succinate glutaric acid

     

    monoperglutaric acid

     

    diperglutaric acid

     

    monomethyl ester of glutaric acid

     

    monomethyl ester of perglutaric acid

     

    dimethyl glutarate adipic acid

     

    monoperadipic acid

     

    diperadipic acid

     

    monomethyl ester of adipic acid

     

    monomethyl ester of peradipic acid

     

    dimethyl adipate

     

    hydrogen peroxide

     

    methanol

     

    water

    432-790-1

     

    Acute Tox. 4*

    H332

    GHS07

    H332

     

     

     

    Acute Tox. 4*

    H312

    GHS05

    H312

    Acute Tox. 4*

    H302

    GHS08

    H302

    Skin Corr. 1B

    H314

    Dgr

    H314

    STOT SE 2

    H371 (eyes)

     

    H371 (eyes)

    609-003-00-7

    nitrobenzene

    202-716-0

    98-95-3

    Carc. 2.

    H351

    GHS06

    H351

     

     

     

    Repr. 1B

    H360F

    GHS08

    H360F

    Acute Tox. 3

    H301

    Dgr

    H301

    Acute Tox. 3

    H331

     

    H331

    Acute Tox. 3

    H311

     

    H311

    STOT RE 1

    H372 (blood)

     

    H372 (blood)

    Aquatic Chronic 3

    H412

     

    H412

    612-120-00-6

    aclonifen (ISO);

    2-chloro-6-nitro-3-phenoxyaniline

    277-704-1

    74070-46-5

    Carc. 2

    H351

    GHS08

    H351

     

    M = 100

    M = 10

     

    Skin Sens. 1A

    H317

    GHS07

    H317

     

    Aquatic Acute 1

    H400

    GHS09

     

     

    Aquatic Chronic 1

    H410

    Wng

    H410

     

    613-175-00-9

    epoxiconazole (ISO);

    (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[( 1H-1,2,4-triazol-1-yl)methyl]oxirane

    406-850-2

    133855-98-8

    Carc. 2

    H351

    GHS08

    H351

     

     

     

    Repr. 1B

    H360Df

    GHS09

    H360Df

    Aquatic Chronic 2

    H411

    Dgr

    H411

    616-200-00-1

    reaction mass of N,N’-ethane-1,2-diylbis(hexanamide) and 12-hydroxy-N-[2-[(1-oxyhexyl)amino]ethyl]octadecanamide and N,N’-ethane-1,2-diylbis(12-hydroxyoctadecan amide)

    432-430-3

     

    Aquatic Chronic 4

    H413

     

    H413

     

     

     

    648-055-00-5

    pitch, coal tar, high-temp.;

    [The residue from the distillation of high temperature coal tar. A black solid with an approximate softening point from 30 °C to 180 °C (86 °F to 356 °F). Composed primarily of a complex mixture of three or more membered condensed ring aromatic hydrocarbons.]

    266-028-2

    65996-93-2

    Carc. 1A

    H350

    GHS08

    H350

     

    M = 1000

    M = 1000

     

    Muta. 1B

    H340

    GHS09

    H340

     

    Repr. 1B

    H360FD

    Dgr

    H360FD

     

    Aquatic Acute 1

    H400

     

     

     

    Aquatic Chronic 1

    H410

     

    H410

     

    649-330-00-2

    naphtha (petroleum), hydrodesulphurized heavy;

    Low boiling point hydrogen treated naphtha;

    [A complex combination of hydrocarbons obtained from a catalytic hydrodesulfurization process. It consists of hydrocarbons having carbon numbers predominantly in the range of C7 through C12 and boiling in the range of approximately 90 °C to 230 °C (194 °F to 446 °F).]

    265-185-4

    64742-82-1

    Carc. 1B

    H350

    GHS08

    H350

     

     

    P

    Muta. 1B

    H340

    Dgr

    H340

    STOT RE 1

    H372 (central nervous system)

     

    H372 (central nervous system)

    Asp. Tox. 1

    H304

     

    H304

    649-345-00-4

    stoddard solvent;

    Low boiling point naphtha — unspecified;

    [A colourless, refined petroleum distillate that is free from rancid or objectionable odours and that boils in a range of approximately 148,8 °C to 204,4 °C (300 °F to 400 °F).]

    232-489-3

    8052-41-3

    Carc. 1B

    H350

    GHS08

    H350

     

     

    P

    Muta. 1B

    H340

    Dgr

    H340

    STOT RE 1

    H372 (central nervous system)

     

    H372 (central nervous system)

    Asp. Tox. 1

    H304

     

    H304

    649-405-00-X

    solvent naphtha (petroleum), medium aliph.;

    Straight run kerosine;

    [A complex combination of hydrocarbons obtained from the distillation of crude oil or natural gasoline. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly in the range of C9 through C12 and boiling in the range of approximately 140 °C to 220 °C (284 °F to 428 °F).]

    265-191-7

    64742-88-7

    STOT RE 1

    H372 (central nervous system)

    GHS08

    H372 (central nervous system)

     

     

     

    Asp. Tox. 1

    H304

    Dgr

    H304


    ANNEX III

    Index No

    International Chemical Identification

    EC No

    CAS No

    Classification

    Labelling

    Specific Conc. Limits,

    M — Factors

    Notes

    Hazard Class and Category Code(s)

    Hazard statement Code(s)

    Pictogram, Signal Word Code(s)

    Hazard statement Code(s)

    Suppl. Hazard statement Code(s)

    031-001-00-4

    gallium arsenide

    215-114-8

    1303-00-0

    Carc. 1B

    H350

    GHS08

    H350

     

     

     

    STOT RE 1

    H372 (respiratory and haematopoietic systems)

    Dgr

    H372 (respiratory and haematopoietic systems)

    050-025-00-6

    trichloromethylstannane

    213-608-8

    993-16-8

    Repr. 2

    H361d

    GHS08

    Wng

    H361d

     

     

     

    050-026-00-1

    2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-methyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate

    260-828-5

    57583-34-3

    Repr. 2

    H361d

    GHS08

    Wng

    H361d

     

     

     

    050-027-00-7

    2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate

    239-622-4

    15571-58-1

    Repr. 1B

    H360D

    GHS08

    Dgr

    H360D

     

     

     

    601-087-00-3

    2,4,4-trimethylpentene

    246-690-9

    25167-70-8

    Flam. Liq. 2

    H225

    GHS02

    H225

     

     

    D

    Asp. Tox. 1

    H304

    GHS07

    H304

    STOT SE 3

    H336

    GHS08

    Dgr

    H336

    606-145-00-1

    sulcotrione (ISO);

    2-[2-chloro-4-(methylsulfonyl)benzoyl]cyclohexane-1,3-dione

     

    99105-77-8

    Repr. 2

    H361d

    GHS08

    H361d

     

    M = 1

    M = 10

     

    STOT RE 2

    H373 (kidneys)

    GHS07

    H373 (kidneys)

    Skin Sens. 1A

    H317

    GHS09

    H317

    Aquatic Acute 1

    H400

    Wng

     

    Aquatic Chronic 1

    H410

     

    H410

    607-699-00-7

    bifenthrin (ISO);

    (2-methylbiphenyl-3-yl)methyl rel-(1R,3R)-3-[(1Z)-2-chloro-3,3,3-trifluoroprop-1-en-1-yl]-2,2-dimethylcyclopropanecarboxylate

     

    82657-04-3

    Carc. 2

    H351

    GHS06

    H351

     

    M = 10 000

    M = 100 000

     

    Acute Tox. 3

    H331

    GHS08

    H331

    Acute Tox. 2

    H300

    GHS09

    H300

    STOT RE 1

    H372 (nervous system)

    Dgr

    H372 (nervous system)

    Skin Sens. 1B

    H317

     

    H317

    Aquatic Acute 1

    H400

     

     

    Aquatic Chronic 1

    H410

     

    H410

    607-700-00-0

    indoxacarb (ISO);

    methyl (4aS)-7-chloro-2-{(methoxycarbonyl)[4-(trifluoromethoxy)phenyl]carbamoyl}-2,5-dihydroindeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate [1]

     

    173584-44-6 [1]

    Acute Tox. 3

    H301

    GHS06

    H301

     

    M = 1

    M = 1

     

    Acute Tox. 4

    H332

    GHS08

    H332

    STOT RE 1

    H372 (blood, nervous system, heart)

    GHS09

    H372 (blood, nervous system, heart)

    Skin Sens. 1B

    H317

    Dgr

    H317

    Aquatic Acute 1

    H400

     

     

    Aquatic Chronic 1

    H410

     

    H410

    reaction mass of (S)- Indoxacarb and (R)- Indoxacarb 75:25;

    methyl 7-chloro-2-{(methoxycarbonyl)[4-(trifluoromethoxy)phenyl]carbamoyl}-2,5-dihydroindeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate [2]

    144171-61-9 [2]

     

     

     

     

    607-702-00-1

    dihexyl phthalate

    201-559-5

    84-75-3

    Repr. 1B

    H360FD

    GHS08

    Dgr

    H360FD

     

     

     

    607-703-00-7

    ammoniumpentadeca- fluorooctanoate

    223-320-4

    3825-26-1

    Carc. 2

    H351

    GHS08

    H351

     

     

     

    Repr. 1B

    H360D

    GHS07

    H360D

    Lact.

    H362

    GHS05

    H362

    Acute Tox. 4

    H332

    Dgr

    H332

    Acute Tox. 4

    H302

     

    H302

    STOT RE 1

    H372 (liver)

     

    H372 (liver)

    Eye Dam.1

    H318

     

    H318

    607-704-00-2

    perfluorooctanoic acid

    206-397-9

    335-67-1

    Carc. 2

    H351

    GHS08

    H351

     

     

     

    Repr. 1B

    H360D

    GHS07

    H360D

    Lact.

    H362

    GHS05

    H362

    Acute Tox. 4

    H332

    Dgr

    H332

    Acute Tox. 4

    H302

     

    H302

    STOT RE 1

    H372 (liver)

     

    H372 (liver)

    Eye Dam. 1

    H318

     

    H318

    612-282-00-8

    octadecylamine

    204-695-3

    124-30-1

    Asp. Tox. 1

    H304

    GHS05

    H304

     

    M = 10

    M = 10

     

    STOT RE 2

    H373 (gastro-intestinal tract, liver, immune system)

    GHS08

    H373 (gastro-intestinal tract, liver, immune system)

    Skin Irrit. 2

    H315

    GHS09

    H315

    Eye Dam. 1

    H318

    Dgr

    H318

    Aquatic Acute 1

    H400

     

     

    Aquatic Chronic 1

    H410

     

    H410

    612-283-00-3

    (Z)-octadec-9-enylamine

    204-015-5

    112-90-3

    Acute Tox. 4

    H302

    GHS05

    H302

     

    M = 10

    M = 10

     

    Asp Tox. 1

    H304

    GHS07

    H304

    STOT SE 3

    H335

    GHS08

    H335

    STOT RE 2

    H373 (gastro-intestinal tract, liver, immune system)

    GHS09

    H373 (gastro-intestinal tract, liver, immune system)

    Skin Corr. 1B

    H314

    Dgr

    H314

    Aquatic Acute 1

    H400

     

     

    Aquatic Chronic 1

    H410

     

    H410

    612-284-00-9

    amines, hydrogenated tallow alkyl

    262-976-6

    61788-45-2

    Asp Tox. 1

    H304

    GHS08

    H304

     

    M = 10

    M = 10

     

    STOT RE 2

    H373 (gastro-intestinal tract, liver, immune system)

    GHS05

    H373 (gastro-intestinal tract, liver, immune system)

    Skin Irrit. 2

    H315

    GHS09

    H315

    Eye Dam. 1

    H318

    Dgr

    H318

    Aquatic Acute 1

    H400

     

     

    Aquatic Chronic 1

    H410

     

    H410

    612-285-00-4

    amines, coco alkyl

    262-977-1

    61788-46-3

    Acute Tox. 4

    H302

    GHS05

    H302

     

    M = 10

    M = 10

     

    Asp. Tox. 1

    H304

    GHS07

    H304

    STOT SE 3

    H335

    GHS08

    H335

    STOT RE 2

    H373 (gastro-intestinal tract, liver, immune system)

    GHS09

    H373 (gastro-intestinal tract, liver, immune system)

    Skin Corr. 1B

    H314

    Dgr

    H314

    Aquatic Acute 1

    H400

     

     

    Aquatic Chronic 1

    H410

     

    H410

    612-286-00-X

    amines, tallow alkyl

    263-125-1

    61790-33-8

    Acute Tox. 4

    H302

    GHS05

    H302

     

    M = 10

    M = 10

     

    Asp. Tox. 1

    H304

    GHS07

    H304

    STOT RE 2

    H373 (gastro-intestinal tract, liver, immune system)

    GHS08

    H373 (gastro-intestinal tract, liver, immune system)

    Skin Corr. 1B

    H314

    GHS09

    H314

    Aquatic Acute 1

    H400

    Dgr

     

    Aquatic Chronic 1

    H410

     

    H410

    616-206-00-4

    flufenoxuron (ISO);

    1-(4-(2-cloro-α,α,α-p-trifluorotolyloxy)-2-fluorophenyl)-3-(2,6-difluorobenzolyl)urea

    417-680-3

    101463-69-8

    Lact.

    H362

    GHS09

    H362

     

    M = 10 000

    M = 10 000

     

    Aquatic Acute 1

    H400

    Wng

     

    Aquatic Chronic 1

    H410

     

    H410

    616-207-00-X

    polyhexamethylene biguanide hydrochloride

     

    27083-27-8 or 32289-58-0

    Carc. 2

    H351

    GHS05

    H351

     

    M = 10

    M = 10

     

    Acute Tox. 4

    H302

    GHS07

    H302

    STOT RE 1

    H372 (respiratory tract) (inhalation)

    GHS08

    H372 (respiratory tract) (inhalation)

    Eye Dam. 1

    H318

    GHS09

    H318

    Skin Sens. 1B

    H317

    Dgr

    H317

    Aquatic Acute 1

    H400

     

     

    Aquatic Chronic 1

    H410

     

    H410

    616-208-00-5

    N-ethyl-2-pyrrolidone;

    1-ethylpyrrolidin-2-one

    220-250-6

    2687-91-4

    Repr. 1B

    H360D

    GHS08

    Dgr

    H360D

     

     

     

    616-209-00-0

    amidosulfuron (ISO);

    3-(4,6-dimethoxypyrimidin-2-yl)-1-((N-methyl-N-methylsulfonylamino)sulfonyl)urea

    407-380-0

    120923-37-7

    Aquatic Acute 1

    H400

    GHS09

     

     

    M = 100

    M = 100

     

    Aquatic Chronic 1

    H410

    Wng

    H410

    616-210-00-6

    tebufenpyrad (ISO);

    N-(4-tertbutylbenzyl)-4-chloro-3-ethyl-1-methyl-1Hpyrazole-5- carboxamide

     

    119168-77-3

    Acute Tox. 3

    H301

    GHS06

    H301

     

    M = 10

    M = 10

     

    Acute Tox. 4

    H332

    GHS08

    H332

    STOT RE 2

    H373 (gastro-intestinal tract) (Oral)

    GHS09

    H373 (gastro-intestinal tract) (Oral)

    Skin Sens. 1B

    H317

    Dgr

    H317

    Aquatic Acute 1

    H400

     

     

    Aquatic Chronic 1

    H410

     

    H410

    616-211-00-1

    proquinazid (ISO);

    6-iodo-2-propoxy-3-propylquinazolin-4(3H)-one

     

    189278-12-4

    Carc. 2

    H351

    GHS08

    H351

     

    M = 1

    M = 10

     

    Aquatic Acute 1

    H400

    GHS09

     

    Aquatic Chronic 1

    H410

    Wng

    H410


    ANNEX IV

    Index No

    International Chemical Identification

    EC No

    CAS No

    Classification

    Labelling

    Concentration Limits

    Notes

    015-004-00-8

    aluminium phosphide

    244-088-0

    20859-73-8

    F; R15/29

    T+; R26/28

    Xn; R21

    R32

    N; R50

    F; T+; N

    R: 15/29-21-26/28-32-50

    S: (1/2-)3/9/14/49-8-22-30-36/37-43-45-60-61

    N; R50: C ≥ 0,25 %

     

    015-005-00-3

    magnesium phosphide;

    trimagnesium diphosphide

    235-023-7

    12057-74-8

    F; R15/29

    T+; R26/28

    Xn; R21

    R32

    N; R50

    F; T+; N

    R: 15/29-21-26/28-32-50

    S: (1/2-)3/9/14/49-8-22-30-36/37-43-45-60-61

    N; R50: C ≥ 0,25 %

     

    015-123-00-5

    fenamiphos (ISO);

    ethyl-4-methylthio-m-tolyl isopropyl phosphoramidate

    244-848-1

    22224-92-6

    T+; R26/28

    T; R24

    Xi; R36

    N; R50-53

    T+; N

    R: 24-26/28-36-50/53

    S: (1/2-)23-26-28-35-36/37-45-60-61

    N; R50-53: C ≥ 0,25 %

    N; R51-53: 0,025 % ≤ C < 0,25 %

    R52-53: 0,0025 % ≤ C < 0,025 %

     

    030-012-00-1

    aluminium-magnesium-zinc-carbonate-hydroxide

    423-570-6

    169314-88-9

    R53

    R: 53

    S: 61

     

     

    602-006-00-4

    chloroform;

    trichloromethane

    200-663-8

    67-66-3

    Carc. Cat. 3; R40

    Repr. Cat. 3; R63

    Xn; R20/22-48/20

    Xi; R36/38

    Xn

    R: 20/22-36/38-40-48/20-63

    S: (2-)36/37

     

     

    603-097-00-3

    1,1′,1′′-nitrilotripropan-2-ol;

    triisopropanolamine

    204-528-4

    122-20-3

    Xi; R36

    Xi

    R: 36

    S: (2-)26

     

     

    605-008-00-3

    acrolein;

    prop-2-enal;

    acrylaldehyde

    203-453-4

    107-02-8

    F; R11

    T+; R26/28

    T; R24

    C; R34

    N; R50

    F; T+; N

    R: 11-24-26/28-34-50

    S: (1/2-)23-26-28-36/37/39-45-61

    C; R34: C ≥ 0,1 %

    N; R50: C ≥ 0,25 %

    D

    607-023-00-0

    vinyl acetate

    203-545-4

    108-05-4

    F; R11

    Carc. Cat. 3; R40

    Xn; R20

    Xi; R37

    F; Xn

    R: 11-20-37-40

    S: 9-16-33-36/37

     

    D

    607-613-00-8

    reaction mass of:

     

    succinic acid

     

    monopersuccinic acid

     

    dipersuccinic acid

     

    monomethyl ester of succinic acid

     

    monomethyl ester of persuccinic acid

     

    dimethyl succinate

     

    glutaric acid

     

    monoperglutaric acid

     

    diperglutaric acid

     

    monomethyl ester of glutaric acid

     

    monomethyl ester of perglutaric acid

     

    dimethyl glutarate

     

    adipic acid

     

    monoperadipic acid

     

    diperadipic acid

     

    monomethyl ester of adipic acid

     

    monomethyl ester of peradipic acid

     

    dimethyl adipate

     

    hydrogen peroxide

     

    methanol

     

    water

    432-790-1

     

    C; R34

    Xn; R20/21/22-68/20/21/22

    C

    R: 20/21/22-34-68/20/21/22

    S: (1/2-)26-28-36/37/39-45

     

     

    609-003-00-7

    nitrobenzene

    202-716-0

    98-95-3

    Carc. Cat. 3; R40

    Repr. Cat. 2; R60

    T; R23/24/25-48/23/24/25

    R52-53

    T

    R: 23/24/25-48/23/24/25-40-60-52/53

    S: 45-53

     

     

    612-120-00-6

    aclonifen (ISO);

    2-chloro-6-nitro-3-phenoxyaniline

    277-704-1

    74070-46-5

    Carc. Cat. 3; R40

    R43

    N; R50-53

    Xn; N

    R: 40-43-50/53

    S: (2-)36/37-60-61

    R43: C ≥ 0,1 %

    N; R50-53: C ≥ 0,25 %

    N; R51-53: 0,025 % ≤ C < 0,25 %

    R52-53: 0,0025 % ≤ C < 0,025 %

     

    613-175-00-9

    epoxiconazole (ISO);

    (2RS,3SR)-3-(2-chlorophenyl)-2-(4-fluorophenyl)-[(1H-1,2,4-triazol-1-yl)methyl]oxirane

    406-850-2

    133855-98-8

    Carc. Cat. 3; R40

    Repr. Cat. 2; R61

    Repr. Cat. 3; R62

    N; R51-53

    T; N

    R: 61-40-62-51/53

    S: 45-53-61

     

     

    616-200-00-1

    reaction mass of N,N’-ethane-1,2-diylbis(hexanamide) and 12-hydroxy-N-[2-[(1-oxyhexyl)amino]ethyl]octadecanamide and N,N’-ethane-1,2-diylbis(12-hydroxyoctadecan amide)

    432-430-3

     

    R53

    R: 53

    S: 61

     

     

    648-055-00-5

    pitch, coal tar, high-temp.;

    [The residue from the distillation of high temperature coal tar. A black solid with an approximate softening point from 30 °C to 180 °C (86 °F to 356 °F). Composed primarily of a complex mixture of three or more membered condensed ring aromatic hydrocarbons.]

    266-028-2

    65996-93-2

    Carc. Cat. 1; R45

    Muta. Cat. 2; R46

    Repr. Cat. 2; R60-61

    N; R50-53

    T; N

    R: 45-46-60-61-50/53

    S: 45-53-60-61

    N; R50-53: C ≥ 0,025 %

    N; R51-53: 0,0025 % ≤ C <

    0,025  %

    R52-53: 0,00025 % ≤ C <

    0,0025  %

     

    649-330-00-2

    naphtha (petroleum), hydrodesulphurized heavy;

    Low boiling point hydrogen treated naphtha;

    [A complex combination of hydrocarbons obtained from a catalytic hydrodesulfurization process. It consists of hydrocarbons having carbon numbers predominantly in the range of C7 through C12 and boiling in the range of approximately 90 °C to 230 °C (194 °F to 446 °F).]

    265-185-4

    64742-82-1

    Carc. Cat. 2; R45

    Muta. Cat. 2; R46

    Xn; R48/20-65

    T

    R: 45-46-48/20-65

    S: 45-53

     

    P

    649-345-00-4

    stoddard solvent;

    Low boiling point naphtha — unspecified;

    [A colourless, refined petroleum distillate that is free from rancid or objectionable odours and that boils in a range of approximately 148,8 °C to 204,4 °C (300 °F to 400 °F).]

    232-489-3

    8052-41-3

    Carc. Cat. 2; R45

    Muta. Cat. 2; R46

    Xn; R48/20-65

    T

    R: 45-46-48/20-65

    S: 45-53

     

    P

    649-405-00-X

    solvent naphtha (petroleum), medium aliph.;

    Straight run kerosine;

    [A complex combination of hydrocarbons obtained from the distillation of crude oil or natural gasoline. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly in the range of C9 through C12 and boiling in the range of approximately 140 °C to 220 °C (284 °F to 428 °F).]

    265-191-7

    64742-88-7

    Xn; R48/20-65

    Xn

    R: 48/20-65

    S: (2-)23-24-62

     

     


    ANNEX V

    Index No

    International Chemical Identification

    EC No

    CAS No

    Classification

    Labelling

    Concentration Limits

    Notes

    031-001-00-4

    gallium arsenide

    215-114-8

    1303-00-0

    Carc. Cat. 2; R45

    T; R48/23

    T

    R: 45-48/23

    S: 45-53

     

    E

    050-025-00-6

    trichloromethylstannane

    213-608-8

    993-16-8

    Repr. Cat. 3; R63

    Xn

    R: 63

    S: (2-)22-36/37

     

     

    050-026-00-1

    2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-methyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate

    260-828-5

    57583-34-3

    Repr. Cat. 3; R63

    Xn

    R: 63

    S: (2-)22-36/37

     

     

    050-027-00-7

    2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate

    239-622-4

    15571-58-1

    Repr. Cat. 2; R61

    T

    R: 61

    S: 45-53

     

     

    601-087-00-3

    2,4,4-trimethylpentene

    246-690-9

    25167-70-8

    F; R11

    Xn; R65

    R67

    F; Xn

    R: 11-65-67

    S: 9-16-33-62

     

    D

    606-145-00-1

    sulcotrione (ISO);

    2-[2-chloro-4-(methylsulfonyl)benzoyl]cyclohexane-1,3-dione

     

    99105-77-8

    Repr. Cat. 3; R63

    Xn; R48/22

    R43

    N; R50-53

    Xn; N

    R: 43-48/22-63-50/53

    S: (2-)22-36/37-60-61

    N; R50-53: C ≥ 25 %

    N; R51-53: 2,5 % ≤ C < 25 %

    R52-53: 0,25 % ≤ C< 2,5 %

    R43: C ≥ 0,1 %

     

    607-699-00-7

    bifenthrin (ISO);

    (2-methylbiphenyl-3-yl)methyl rel-(1R,3R)-3-[(1Z)-2-chloro-3,3,3-trifluoroprop-1-en-1-yl]-2,2-dimethylcyclopropanecarboxylate

     

    82657-04-3

    Carc. Cat 3; R40

    T; R23/25

    Xn; R48/22

    R43

    N; R50-53

    T; N

    R: 23/25-40-43-48/22-50/53

    S: (1/2-)23-24-36/37-38- 45-60-61

    N; R50-53: C ≥ 0,0025 %

    N; R51-53: 0,00025 % ≤ C< 0,0025 %

    R52-53: 0,000025 % ≤ C < 0,00025 %

     

    607-700-00-0

    indoxacarb (ISO);

    methyl (4aS)-7-chloro-2-{(methoxycarbonyl)[4-(trifluoromethoxy)phenyl]carbamoyl}-2,5-dihydroindeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate

     

    173584-44-6

    T; R25-48/25

    Xn; R20

    R43

    N; R50-53

    T; N

    R: 20-25-43-48/25-50/53

    S: (1/2-)24-37-45-60-61

    N; R50-53: C ≥ 25 %

    N; R51-53: 2,5 % ≤ C < 25 %

    R52-53: 0,25 % ≤ C < 2,5 %

     

    607-701-00-6

    reaction mass of (S)- Indoxacarb and (R)- Indoxacarb 75:25;

    methyl 7-chloro-2-{(methoxycarbonyl)[4-(trifluoromethoxy)phenyl]carbamoyl}-2,5-dihydroindeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylate

     

    144171-61-9

    T; R48/25

    Xn; R20/22

    R43

    N; R50-53

    T; N

    R: 20/22-43-48/25-50/53

    S: (1/2-)24-37-45-60-61

    N; R50-53: C ≥ 25 %

    N; R51-53: 2,5 % ≤ C < 25 %

    R52-53: 0,25 % ≤ C < 2,5 %

     

    607-702-00-1

    dihexyl phthalate

    201-559-5

    84-75-3

    Repr. Cat. 2; R60-61

    T

    R: 60-61

    S: 45-53

     

     

    607-703-00-7

    ammoniumpentade-cafluorooctanoate

    223-320-4

    3825-26-1

    Carc. Cat. 3; R40

    Repr. Cat. 2; R61

    R64

    T; R48/23

    Xn; R20/22-48/21/22

    Xi; R41

    T

    R: 61-20/22-40-41- 48/23-48/21/22-64

    S: 45-53

     

     

    607-704-00-2

    perfluorooctanoic acid

    206-397-9

    335-67-1

    Carc. Cat. 3; R40

    Repr. Cat. 2; R61

    R64

    T; R48/23

    Xn; R20/22-48/21/22

    Xi; R41

    T

    R: 61-20/22-40-41-48/23-48/21/22-64

    S: 45-53

     

     

    612-282-00-8

    octadecylamine

    204-695-3

    124-30-1

    Xn; R48/22-65

    Xi; R38-41

    N; R50-53

    Xn; N

    R: 38-41-48/22-65-50/53

    S: (2-)26-36/37/39-60-61-62

    N; R50-53: C ≥ 2,5 %

    N; R51-53: 0,25 % ≤ C < 2,5 %

    R52-53: 0,025 % ≤ C < 0,25 %

     

    612-283-00-3

    (Z)-octadec-9-enylamine

    204-015-5

    112-90-3

    Xn; R22-48/22-65

    C; R34

    N; R50-53

    C; N

    R: 22-34-48/22-65-50/53

    S: (1/2-)23-26-36/37/39-45-60-61-62

    C; R34: C ≥ 10 %

    Xi; R36/37/38: 5 % ≤ C < 10 %

    N; R50-53: C ≥ 2,5 %

    N; R51-53: 0,25 % ≤ C < 2,5 %

    R52-53: 0,025 % ≤ C < 0,25 %

     

    612-284-00-9

    amines, hydrogenated tallow alkyl

    262-976-6

    61788-45-2

    Xn; R48/22-65

    Xi; R38-41

    N; R50-53

    Xn; N

    R: 38-41-48/22-65-50/53

    S: (2-)26-36/37/39-60-61-62

    N; R50-53: C ≥ 2,5 %

    N; R51-53: 0,25 % ≤ C < 2,5 %

    R52-53: 0,025 % ≤ C < 0,25 %

     

    612-285-00-4

    amines, coco alkyl

    262-977-1

    61788-46-3

    Xn; R22-48/22-65

    C; R35

    N; R50-53

    C; N

    R: 22-35-48/22-65-50/53

    S: (1/2-)23-26-36/37/39-45-60-61-62

    C; R35: C ≥ 10 %

    C; R34: 5 % ≤ C < 10 %

    Xi; R36/37/38: 1 % ≤ C < 5 %

    N; R50-53: C ≥ 2,5 %

    N; R51-53: 0,25 % ≤ C < 2,5 %

    R52-53: 0,025 % ≤ C < 0,25 %

     

    612-286-00-X

    amines, tallow alkyl

    263-125-1

    61790-33-8

    Xn; R22-48/22-65

    C; R35

    N; 50-53

    C; N

    R: 22-35-48/22-65-50/53

    S: (1/2-)26-36/37/39-45-60-61-62

    N; R50-53: C ≥ 2,5 %

    N; R51-53: 0,25 % ≤ C < 2,5 %

    R52-53: 0,025 % ≤ C < 0,25 %

     

    616-206-00-4

    flufenoxuron (ISO);

    1-(4-(2-cloro-α,α,α-p-trifluorotolyloxy)-2-fluorophenyl)-3-(2,6-difluorobenzolyl)urea

    417-680-3

    101463-69-8

    R64

    R33

    N; R50-53

    N

    R: 33-64-50/53

    S: (2-)22-36/37-46-60-61

    N; R50-53 C ≥ 0,0025 %

    N; R51-53 0,00025 % ≤ C < 0,0025 %

    R52-53 0,000025 % ≤ C < 0,00025 %

     

    616-207-00-X

    polyhexamethylene biguanide hydrochloride

     

    27083-27-8 or 32289-58-0

    Carc. Cat 3; R40

    Xn; R22

    T; R48/23

    Xi; R41

    R43

    N; R50-53

    T; N

    R: 22-40-41-43-48/23-50/53

    S: (1/2-)22-36/37/39-45-60-61

    N; R50-53: C ≥ 2,5 %

    N; R51-53: 0,25 % ≤ C < 2,5 %

    R52-53: 0,025 % ≤ C < 0,25 %

     

    616-208-00-5

    N-ethyl-2-pyrrolidone;

    1-ethylpyrrolidin-2-one

    220-250-6

    2687-91-4

    Repr. Cat. 2; R61

    T

    R: 61

    S: 45-53

     

     

    616-209-00-0

    amidosulfuron (ISO);

    3-(4,6-dimethoxypyrimidin-2-yl)-1-((N-methyl-N-methylsulfonylamino)sulfonyl)urea

    407-380-0

    120923-37-7

    N; R50-53

    N

    R: 50/53

    S: 60-61

    N; R50-53: C ≥ 0,25 %

    N; R51-53: 0,025 % ≤ C < 0,25 %

    R52-53: 0,0025 % ≤ C < 0,025 %

     

    616-210-00-6

    tebufenpyrad (ISO);

    N-(4-tertbutylbenzyl)-4-chloro-3-ethyl-1-methyl-1Hpyrazole-5-carboxamide

     

    119168-77-3

    Xn; R20/22

    R43

    N; R50-53

    Xn; N

    R: 20/22-43-50/53

    S: (2-)24-37-46-60-61

    N; R50-53: C ≥ 2,5 %

    N; R51-53: 0,25 % ≤ C < 2,5 %

    R52-53: 0,025 % ≤ C < 0,25 %

     

    616-211-00-1

    proquinazid (ISO);

    6-iodo-2-propoxy-3-propylquinazolin-4(3H)-one

     

    189278-12-4

    Carc. Cat. 3; R40

    N; R50-53

    Xn; N

    R: 40-50/53

    S: (2-)36/37-46-60-61

     

     


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