(3)
|
Part 1 is amended as follows:
(a)
|
Table 6.2 is amended as follows:
(i)
|
The entry concerning code P202 is replaced by the following:
‘P202
|
Do not handle until all safety precautions have been read and understood.
|
Flammable gases (including chemically unstable gases) (Section 2.2)
|
A, B
(chemically unstable gases)
|
|
Germ cell mutagenicity (Section 3.5)
|
1A, 1B, 2
|
|
Carcinogenicity (Section 3.6)
|
1A, 1B, 2
|
|
Reproductive toxicity (Section 3.7)
|
1A, 1B, 2’
|
|
|
(ii)
|
The entry concerning code P220 is replaced by the following:
‘P220
|
Keep away from clothing and other combustible materials.
|
Oxidising gases (Section 2.4)
|
1
|
|
Oxidising liquids (Section 2.13)
|
1, 2, 3
|
Oxidising solids (Section 2.14)
|
1, 2, 3’
|
|
(iii)
|
The entry concerning code P221 is deleted.
|
(iv)
|
The entries concerning codes P222, P223, P230, P231 are replaced by the following:
‘P222
|
Do not allow contact with air.
|
Pyrophoric liquids (Section 2.9)
|
1
|
—
|
if emphasis of the hazard statement is deemed necessary
|
|
Pyrophoric solids (Section 2.10)
|
1
|
P223
|
Do not allow contact with water.
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2
|
—
|
if emphasis of the hazard statement is deemed necessary
|
|
P230
|
Keep wetted with …
|
Explosives (Section 2.1)
|
Divisions 1.1, 1.2, 1.3, 1.5
|
—
|
for substances and mixtures which are wetted, diluted, dissolved or suspended with a phlegmatiser in order to reduce or suppress their explosive properties (desensitised explosives)
|
… Manufacturer/supplier to specify appropriate material.
|
P231
|
Handle and store contents under inert gas/…
|
Pyrophoric liquids (Section 2.9)
|
1
|
… Manufacturer/supplier to specify appropriate liquid or gas if “inert gas” is not appropriate.
|
Pyrophoric solids (Section 2.10)
|
1
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2, 3
|
—
|
if the substance or mixture reacts readily with moisture in air.
|
… Manufacturer/supplier to specify appropriate liquid or gas if “inert gas” is not appropriate.’
|
|
(v)
|
The entries concerning codes P233, P234, P235, P240, P241, P242, P243 are replaced by the following:
‘P233
|
Keep container tightly closed.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
if the liquid is volatile and may generate an explosive atmosphere
|
|
Pyrophoric liquids (Section 2.9)
|
1
|
|
Pyrophoric solids (Section 2.10)
|
1
|
|
Acute toxicity — inhalation (Section 3.1)
|
1, 2, 3
|
—
|
if the chemical is volatile and may generate a hazardous atmosphere
|
|
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)
|
3
|
Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)
|
3
|
P234
|
Keep only in original packaging.
|
Explosives (Section 2.1)
|
Divisions 1.1, 1.2, 1.3, 1.4, 1.5
|
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A, B, C, D, E, F
|
Organic peroxides (Section 2.15)
|
Types A, B, C, D, E, F
|
Corrosive to metals (Section 2.16)
|
1
|
P235
|
Keep cool.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
for flammable liquids category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere
|
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A, B, C, D, E, F
|
—
|
may be omitted if P411 is given on the label
|
|
Self-heating substances and mixtures (Section 2.11)
|
1, 2
|
—
|
may be omitted if P413 is given on the label
|
|
Organic peroxides (Section 2.15)
|
Types A, B, C, D, E, F
|
—
|
may be omitted if P411 is given on the label
|
|
P240
|
Ground and bond container and receiving equipment.
|
Explosives (Section 2.1)
|
Divisions 1.1, 1.2, 1.3, 1.4, 1.5
|
—
|
if the explosive is electrostatically sensitive
|
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
if the liquid is volatile and may generate an explosive atmosphere
|
|
Flammable solids (Section 2.7)
|
1, 2
|
—
|
if the solid is electrostatically sensitive
|
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A,B,C, D, E, F
|
—
|
if electrostatically sensitive and able to generate an explosive atmosphere
|
|
Organic peroxides (Section 2.15)
|
P241
|
Use explosion-proof [electrical/ventilating/lighting/…] equipment.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
if the liquid is volatile and may generate an explosive atmosphere.
|
—
|
text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate.
|
|
Flammable solids (Section 2.7)
|
1, 2
|
—
|
if dust clouds can occur.
|
—
|
text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate.
|
|
P242
|
Use non-sparking tools.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the ignition energy is < 0,1 mJ, e.g. carbon disulphide).
|
|
P243
|
Take action to prevent static discharges.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
if the liquid is volatile and may generate an explosive atmosphere.’
|
|
|
(vi)
|
The entry concerning code P250 is replaced by the following:
‘P250
|
Do not subject to grinding/shock/friction …
|
Explosives (Section 2.1)
|
Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5
|
—
|
if the explosive is mechanically sensitive
|
… Manufacturer/supplier to specify applicable rough handling.’
|
|
(vii)
|
The entry concerning code P261 is replaced as follows:
‘P261
|
Avoid breathing dust/fume/gas/mist/vapours/spray.
|
Acute toxicity — inhalation (Section 3.1)
|
3, 4
|
—
|
may be omitted if P260 is given on the label
|
Manufacturer/supplier to specify applicable conditions.’
|
Respiratory sensitisation (Section 3.4)
|
1, 1A, 1B
|
Skin sensitisation (Section 3.4)
|
1, 1A, 1B
|
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)
|
3
|
Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)
|
3
|
|
(viii)
|
The entry concerning code P263 is replaced by the following:
‘P263
|
Avoid contact during pregnancy and while nursing.
|
Reproductive toxicity — effects on or via lactation (Section 3.7)
|
Additional category’
|
|
|
(ix)
|
The entries concerning codes P280, P282, P283, P284, P231 + P232 are replaced by the following:
‘P280
|
Wear protective gloves/protective clothing/eye protection/face protection.
|
Explosives (Section 2.1)
|
Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5
|
Manufacturer/supplier to specify the appropriate type of equipment.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
Flammable solids (Section 2.7)
|
1, 2
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A, B, C, D, E, F
|
Pyrophoric liquids (Section 2.9)
|
1
|
Pyrophoric solids (Section 2.10)
|
1
|
Self-heating substances and mixtures (Section 2.11)
|
1, 2
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2, 3
|
Oxidising liquids (Section 2.13)
|
1, 2, 3
|
Oxidising solids (Section 2.14)
|
1, 2, 3
|
Organic peroxides (Section 2.15)
|
Types A, B, C, D, E, F
|
Acute toxicity — dermal (Section 3.1)
|
1, 2, 3, 4
|
—
|
Specify protective gloves/clothing
|
Manufacturer/supplier may further specify type of equipment where appropriate.
|
Skin corrosion (Section 3.2)
|
1, 1A, 1B, 1C
|
—
|
Specific protective gloves/clothing and eye/face protection
|
Manufacturer/supplier may further specify type of equipment where appropriate.
|
|
|
Skin irritation (Section 3.2)
|
2
|
—
|
Specify protective gloves.
|
Manufacturer/supplier may further specify type of equipment where appropriate.
|
Skin sensitisation (Section 3.4)
|
1, 1A, 1B
|
Serious eye damage (Section 3.3)
|
1
|
—
|
Specify eye/face protection.
|
Manufacturer/supplier may further specify type of equipment where appropriate.
|
Eye irritation (Section 3.3)
|
2
|
|
|
Germ cell mutagenicity (Section 3.5)
|
1A, 1B, 2
|
Manufacturer/ supplier to specify the appropriate type of equipment.
|
|
|
Carcinogenicity (Section 3.6)
|
1A, 1B, 2
|
|
|
Reproductive toxicity (Section 3.7)
|
1A, 1B, 2
|
P282
|
Wear cold insulating gloves and either face shield or eye protection.
|
Gases under pressure (Section 2.5)
|
Refrigerated liquefied gas
|
|
P283
|
Wear fire resistant or flame retardant clothing.
|
Oxidising liquids (Section 2.13)
|
1
|
|
Oxidising solids (Section 2.14)
|
1
|
|
P284
|
[In case of inadequate ventilation] wear respiratory protection.
|
Acute toxicity — inhalation (Section 3.1)
|
1, 2
|
—
|
text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use.
|
Manufacturer/supplier to specify equipment.
|
Respiratory sensitisation (Section 3.4)
|
1, 1A, 1B
|
P231 + P232
|
Handle and store contents under inert gas/…
Protect from moisture.
|
Pyrophoric liquids (Section 2.9)
|
1
|
… Manufacturer/supplier to specify the appropriate liquid or gas if “inert gas” is not appropriate.
|
Pyrophoric solids (Section 2.10)
|
1
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2, 3
|
—
|
if the substance or mixture reacts readily with moisture in air.
|
… Manufacturer/supplier to specify appropriate liquid or gas if “inert gas” is not appropriate.’
|
|
(x)
|
The entry concerning code P235 + P410 is deleted.
|
|
(b)
|
Table 6.3 is amended as follows:
(i)
|
The entry concerning code P302 is replaced by the following:
‘P302
|
IF ON SKIN:
|
Pyrophoric liquids (Section 2.9)
|
1
|
|
Pyrophoric solids (Section 2.10)
|
1
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2
|
Acute Toxicity, dermal (Section 3.1)
|
1, 2, 3, 4
|
|
|
Skin irritation (Section 3.2)
|
2
|
|
|
|
Skin sensitisation (Section 3.4)
|
1, 1A, 1B’
|
|
|
(ii)
|
The entry concerning code P312 is replaced by the following:
‘P312
|
Call a POISON CENTRE/doctor/… if you feel unwell.
|
Acute toxicity — oral (Section 3.1)
|
4
|
… Manufacturer/supplier to specify the appropriate source of emergency medical advice.’
|
Acute toxicity — dermal (Section 3.1)
|
3, 4
|
Acute toxicity — inhalation (Section 3.1)
|
4
|
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)
|
3
|
Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)
|
3
|
|
(iii)
|
The entries concerning codes P320 and P321 are replaced by the following:
‘P320
|
Specific treatment is urgent (see … on this label).
|
Acute toxicity — inhalation (Section 3.1)
|
1, 2
|
—
|
if immediate administration of antidote is required.
|
… Reference to supplemental first aid instruction.
|
P321
|
Specific treatment (see … on this label).
|
Acute toxicity — oral (Section 3.1)
|
1, 2, 3
|
—
|
if immediate administration of antidote is required.
|
… Reference to supplemental first aid instruction.
|
Acute toxicity, dermal (Section 3.1)
|
1, 2, 3, 4
|
—
|
if immediate measures such as specific cleansing agent are advised.
|
… Reference to supplemental first aid instruction.
|
Acute toxicity — inhalation (Section 3.1)
|
3
|
—
|
if immediate specific measures are required.
|
… Reference to supplemental first aid instruction.
|
Skin corrosion (Section 3.2)
|
1, 1A, 1B, 1C
|
… Reference to supplemental first aid instruction.
Manufacturer/supplier may specify a cleansing agent if appropriate.
|
Skin irritation (Section 3.2)
|
2
|
Skin sensitisation (Section 3.4)
|
1, 1A, 1B
|
Specific target organ toxicity — single exposure (Section 3.8)
|
1
|
—
|
if immediate measures are required.
|
… Reference to supplemental first aid instruction.’
|
|
(iv)
|
The entry concerning code P334 is replaced by the following:
‘P334
|
Immerse in cool water [or wrap in wet bandages].
|
Pyrophoric liquids (Section 2.9)
|
1
|
—
|
text in square brackets to be used for pyrophoric liquids and solids
|
|
Pyrophoric solids (Section 2.10)
|
1
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2
|
Use only “immerse in cool water.” Text in square brackets should not be used.’
|
|
(v)
|
The entry concerning code P353 is replaced by the following:
‘P353
|
Rinse skin with water [or shower].
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.’
|
|
Skin corrosion (Section 3.2)
|
1, 1A, 1B, 1C
|
|
(vi)
|
The entry concerning code P370 is replaced by the following:
‘P370
|
In case of fire:
|
Explosives (Section 2.1)
|
Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5
|
|
Oxidising gases (Section 2.4)
|
1
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
Flammable solids (Section 2.7)
|
1, 2
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A, B, C, D, E, F
|
Pyrophoric liquids (Section 2.9)
|
1
|
Pyrophoric solids (Section 2.10)
|
1
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2, 3
|
Oxidising liquids (Section 2.13)
|
1, 2, 3
|
Oxidising solids (Section 2.14)
|
1, 2, 3
|
Organic Peroxides (Section 2.15)
|
Types A, B, C, D, E, F’
|
|
(vii)
|
The entries concerning codes P372 and P373 are replaced by the following:
‘P372
|
Explosion risk.
|
Explosives (Section 2.1)
|
Unstable explosives and Divisions 1.1, 1.2, 1.3, and 1.5
|
|
Division 1.4
|
—
|
except for explosives of division 1.4 (compatibility group S) in transport packaging.
|
|
Self-reactive substances and mixtures (Section 2.8)
|
Type A
|
|
Organic peroxides (Section 2.15)
|
Type A
|
P373
|
DO NOT fight fire when fire reaches explosives.
|
Explosives (Section 2.1)
|
Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.5
|
|
Division 1.4
|
—
|
except for explosives of division 1.4 (compatibility group S) in transport packaging.
|
|
Self-reactive substances and mixtures (Section 2.8)
|
Type A
|
|
Organic peroxides (Section 2.15)
|
Type A’
|
|
(viii)
|
The entry concerning code P374 is deleted.
|
(ix)
|
The entry concerning code P375 is replaced by the following:
‘P375
|
Fight fire remotely due to the risk of explosion.
|
Explosives (Section 2.1)
|
Division 1.4
|
—
|
for explosives of division 1.4 (compatibility group S) in transport packaging.’
|
|
Self-reactive substances and mixtures (Section 2.8)
|
Type B
|
|
Oxidising liquids (Section 2.13)
|
1
|
Oxidising solids (Section 2.14)
|
1
|
Organic peroxides (Section 2.15)
|
Type B
|
|
(x)
|
The entries concerning codes P378, P380, P381 are replaced by the following:
‘P378
|
Use … to extinguish.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
if water increases risk
|
… Manufacturer/supplier to specify appropriate media
|
Flammable solids (Section 2.7)
|
1, 2
|
Self-reactive substances and mixtures (Section 2.8)
|
Types B, C, D, E, F
|
Pyrophoric liquids (Section 2.9)
|
1
|
Pyrophoric solids (Section 2.10)
|
1
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2, 3
|
Oxidising liquids (Section 2.13)
|
1, 2, 3
|
Oxidising solids (Section 2.14)
|
1, 2, 3
|
Organic peroxides (Section 2.15)
|
Types B, C, D, E, F
|
P380
|
Evacuate area.
|
Explosives (Section 2.1)
|
Unstable explosives,
Divisions 1.1, 1.2, 1.3, 1.4, 1.5
|
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A, B
|
Oxidising liquids (Section 2.13)
|
1
|
Oxidising solids (Section 2.14)
|
1
|
Organic peroxides (Section 2.15)
|
Types A, B
|
P381
|
In case of leakage, eliminate all ignition sources.
|
Flammable gases (Section 2.2)
|
1, 2’
|
|
|
(xi)
|
The entry concerning code P301 + P312 is replaced by the following:
‘P301 + P312
|
IF SWALLOWED: Call a POISON CENTRE/doctor/… if you feel unwell.
|
Acute toxicity — oral (Section 3.1)
|
4
|
… Manufacturer/supplier to specify the appropriate source of emergency medical advice.’
|
|
(xii)
|
The entry concerning code P301 + P330 + P331 is deleted.
|
(xiii)
|
The entry concerning code P302 + P334 is replaced by the following:
‘P302 + P334
|
IF ON SKIN: Immerse in cool water or wrap in wet bandages.
|
Pyrophoric liquids (Section 2.9)
|
1’
|
|
|
(xiv)
|
The entry concerning code P303 + P361 + P353 is deleted.
|
(xv)
|
The entry concerning code P305 + P351 + P338 is deleted.
|
(xvi)
|
The entry concerning code P332 + P313 is replaced by the following:
‘P332 + P313
|
If skin irritation occurs: Get medical advice/attention.
|
Skin irritation (Section 3.2)
|
2
|
—
|
may be omitted when P333 + P313 is given on the label.’
|
|
|
(xvii)
|
The following new entry concerning code P336 + P315 is inserted after entry concerning code P333 + P313:
‘P336 + P315
|
Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention.
|
Gases under pressure (Section 2.5)
|
Refrigerated liquefied gas’
|
|
|
(xviii)
|
The entry concerning code P335 + P334 is deleted.
|
(xix)
|
The entry concerning code P370 + P378 is replaced by the following:
‘P370 + P378
|
In case of fire: Use … to extinguish.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
if water increases risk.
|
… Manufacturer/sup-plier to specify appropriate media.’
|
Flammable solids (Section 2.7)
|
1, 2
|
Self-reactive substances and mixtures (Section 2.8)
|
Types C, D, E, F
|
Pyrophoric liquids (Section 2.9)
|
1
|
Pyrophoric solids (Section 2.10)
|
1
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2, 3
|
Oxidising liquids (Section 2.13)
|
1, 2, 3
|
Oxidising solids (Section 2.14)
|
1, 2, 3
|
Organic peroxides (Section 2.15)
|
Types C, D, E, F
|
|
(xx)
|
The following new entries concerning codes P301 + P330 + P331, P302 + P335 + P334, P303 + P361 + P353 and P305 + P351 + P338 are inserted after the entry concerning code P370 + P378:
‘P301 + P330 + P331
|
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
|
Skin corrosion (Section 3.2)
|
1, 1A, 1B, 1C
|
|
P302 + P335 + P334
|
IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].
|
Pyrophoric solids (Section 2.10)
|
1
|
—
|
text in square brackets to be used for pyrophoric solids
|
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2
|
—
|
use only “Immerse in cold water”. Text in square brackets should not be used.
|
|
P303 + P361 + P353
|
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical.
|
|
Skin corrosion (Section 3.2)
|
1, 1A, 1B, 1C
|
P305 + P351 + P338
|
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
|
Skin corrosion (Section 3.2)
|
1, 1A, 1B, 1C
|
|
Serious eye damage/eye irritation (Section 3.3)
|
1
|
|
Eye irritation (Section 3.3)
|
2’
|
|
|
(xxi)
|
The entry concerning code P370 + P380 is deleted.
|
(xxii)
|
The entry concerning code P370 + P380 + P375 is replaced by the following:
‘P370 + P380 + P375
|
In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
|
Explosives (Section 2.1)
|
Division 1.4
|
—
|
for explosives of division 1.4 (compatibility group S) in transport packaging’
|
|
|
(xxiii)
|
The following new entries concerning codes P370 + P372 + P380 + P373 and P370 + P380 + P375 + [P378] are inserted after the entry concerning code P371 + P380 + P375:
‘P370 + P372 + P380 + P373
|
In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives
|
Explosives (Section 2.1)
|
Unstable explosives and divisions 1.1, 1.2, 1.3, 1.5
|
|
Division 1.4
|
—
|
except for explosives of division 1.4 (compatibility group S) in transport packaging.
|
|
Self-reactive substances and mixtures (Section 2.8)
|
Type A
|
|
Organic peroxides (Section 2.15)
|
Type A
|
|
P370 + P380 + P375 + [P378]
|
In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish].
|
Self-reactive substances and mixtures (Section 2.8)
|
Type B
|
—
|
text in square brackets to be used if water increases risk.
|
… Manufacturer/supplier to specify appropriate media.’
|
Organic peroxides (Section 2.15)
|
Type B
|
|
|
(c)
|
Table 6.4 is amended as follows:
(i)
|
The entry concerning code P401 is replaced by the following:
‘P401
|
Store in accordance with …
|
Explosives (Section 2.1)
|
Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5
|
… Manufacturer/ supplier to specify local/regional/ national/international regulations as applicable.’
|
|
(ii)
|
The entry concerning code P403 is replaced by the following:
‘P403
|
Store in a well-ventilated place.
|
Flammable gases (Section 2.2)
|
1, 2
|
|
Oxidising gases (Section 2.4)
|
1
|
|
Gases under pressure (Section 2.5)
|
Compressed gas
|
|
Liquefied gas
|
|
Refrigerated Liquefied gas
|
|
Dissolved gas
|
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere.
|
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A, B, C, D, E, F
|
—
|
except for temperature controlled self-reactive substances and mixtures or organic peroxides because condensation and consequent freezing may take place.
|
|
Organic peroxides (Section 2.15)
|
Acute toxicity — inhalation (Section 3.1)
|
1, 2, 3
|
—
|
if the substance or mixture is volatile and may generate a hazardous atmosphere.
|
|
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)
|
3
|
Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)
|
3’
|
|
(iii)
|
The entry concerning code P406 is replaced by the following:
‘P406
|
Store in a corrosion-resistant/… container with a resistant inner liner.
|
Corrosive to metals (Section 2.16)
|
1
|
—
|
may be omitted if P234 is given on the label
|
… Manufacturer/supplier to specify other compatible materials.’
|
|
(iv)
|
The entry concerning code P407 is replaced by the following:
‘P407
|
Maintain air gap between stacks or pallets.
|
Self-heating substances and mixtures (Section 2.11)
|
1, 2’
|
|
|
(v)
|
The entries concerning codes P411, P412, P413, P420 are replaced by the following:
‘P411
|
Store at temperatures not exceeding … °C/… °F.
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A, B, C, D, E, F
|
—
|
if temperature control is required (according to Annex I, Section 2.8.2.4 or 2.15.2.3) or if otherwise deemed necessary.
|
… Manufacturer/supplier to specify temperature using the applicable temperature scale.
|
Organic peroxides (Section 2.15)
|
Types A, B, C, D, E, F
|
P412
|
Do not expose to temperatures exceeding 50 °C/ 122 °F.
|
Aerosols (Section 2.3)
|
1, 2, 3
|
Manufacturer/supplier to use applicable temperature scale.
|
P413
|
Store bulk masses greater than … kg/… lbs at temperatures not exceeding … °C/… °F.
|
Self-heating substances and mixtures (Section 2.11)
|
1, 2
|
… Manufacturer/supplier to specify mass and temperature using applicable scale.
|
P420
|
Store separately.
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A, B, C, D, E, F
|
|
Self-heating substances and mixtures (Section 2.11)
|
1,2
|
Oxidising liquids (Section 2.13)
|
1
|
Oxidising solids (Section 2.14)
|
1
|
Organic peroxides (Section 2.15)
|
Types A,B,C,D,E,F’
|
|
(vi)
|
The entry concerning code P422 is deleted.
|
(vii)
|
The entries concerning codes P403 + P233, P403 + P235, P410 + P403, P410 + 412 are replaced by the following:
‘P403 + P233
|
Store in a well-ventilated place. Keep container tightly closed.
|
Acute toxicity — inhalation (Section 3.1)
|
1, 2, 3
|
—
|
if the substance or mixture is volatile and may generate a hazardous atmosphere.
|
|
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)
|
3
|
Specific target organ toxicity — single exposure; narcosis (Section 3.8)
|
3
|
P403 + P235
|
Store in a well-ventilated place. Keep cool.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
—
|
for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere.
|
|
P410 + P403
|
Protect from sunlight. Store in a well-ventilated place.
|
Gases under pressure (Section 2.5)
|
Compressed gas
|
—
|
P410 may be omitted for gases filled in transportable gas cylinders in accordance with packing instruction P200 of the UN RTDG, unless those gases are subject to (slow) decomposition or polymerisation.
|
|
Liquefied gas
|
Dissolved gas
|
P410 + P412
|
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
|
Aerosols (Section 2.3)
|
1, 2, 3
|
Manufacturer/ supplier to use applicable temperature scale.’
|
|
(viii)
|
The entry concerning code P411 + P235 is deleted.
|
|
(d)
|
Table 6.5 is amended as follows:
The entries concerning codes P501 and P502 are replaced by the following:
‘P501
|
Dispose of contents/container to …
|
Explosives (Section 2.1)
|
Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5
|
… in accordance with local/regional/ national/international regulation (to be specified).
Manufacturer/supplier to specify whether disposal requirements apply to contents, container or both.
|
Flammable liquids (Section 2.6)
|
1, 2, 3
|
Self-reactive substances and mixtures (Section 2.8)
|
Types A, B, C, D, E, F
|
Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12)
|
1, 2, 3
|
Oxidising liquids (Section 2.13)
|
1, 2, 3
|
Oxidising solids (Section 2.14)
|
1, 2, 3
|
Organic peroxides (Section 2.15)
|
Types A, B, C, D, E, F
|
Acute toxicity — oral (Section 3.1)
|
1, 2, 3, 4
|
Acute toxicity — dermal (Section 3.1)
|
1, 2, 3, 4
|
Acute toxicity — inhalation (Section 3.1)
|
1, 2
|
Skin corrosion (Section 3.2)
|
1, 1A, 1B, 1C
|
Respiratory sensitisation (Section 3.4)
|
1, 1A, 1B
|
Skin sensitisation (Section 3.4)
|
1, 1A, 1B
|
Germ cell mutagenicity (Section 3.5)
|
1A, 1B, 2
|
Carcinogenicity (Section 3.6)
|
1A, 1B, 2
|
Reproductive toxicity (Section 3.7)
|
1A, 1B, 2
|
Specific target organ toxicity — single exposure (Section 3.8)
|
1, 2
|
Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8)
|
3
|
Specific target organ toxicity — single exposure; narcotic effects (Section 3.8)
|
3
|
Specific target organ toxicity — repeated exposure (Section 3.9)
|
1, 2
|
Aspiration hazard (Section 3.10)
|
1
|
Hazardous to the aquatic environment — acute aquatic hazard (Section 4.1)
|
1
|
Hazardous to the aquatic environment — chronic aquatic hazard (Section 4.1)
|
1, 2, 3, 4
|
P502
|
Refer to manufacturer or supplier for information on recovery or recycling
|
Hazardous to the ozone layer (Section 5.1)
|
1’
|
|
|
|